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CrossRef Open Access 2018
КЛАСТЕРНАЯ САМООРГАНИЗАЦИЯ ИНТЕРМЕТАЛЛИЧЕСКИХ СИСТЕМ: МЕТАЛЛОКЛАСТЕРЫ Cs И Cs И МЕТАЛЛООКСИДНЫЙ КЛАСТЕР CsO ДЛЯ САМОСБОРКИ КРИСТАЛЛИЧЕСКОЙ СТРУКТУРЫ (Cs)(Cs)(CsO), "Физика и химия стекла"

В. Я. Шевченко, В.А. Блатов, Г.Д. Илюшин

Проведен геометрический и топологический анализ металлооксида с минимальным известным содержанием кислорода CsO, образующегося из кислородсодержащего расплава металлического Cs. Для определения кластеров-прекурсоров кристаллических структур использованы специальные алгоритмы разложения структурных графов на кластерные субструктуры (пакет программ ToposPro). Определены участвующие в самосборке кристаллических структур кластеры-прекурсоры: трехоктаэдрические кластеры CsO, октаэдрические кластеры Cs, тетраэдрические кластеры Cs. Реконструированы симметрийный и топологический коды процессов самосборки кристаллических структур из кластеров-прекурсоров в виде: первичная цепь микрослой микрокаркас.

CrossRef Open Access 2007
Surface transient effects in ultralow‐energy Cs <sup>+</sup> sputtering of Si

A. R. Chanbasha, A. T. S. Wee

Abstract This study examines the dependence of the sputter rate and the transient width ( z tr ) as a function of Cs + primary ion energy (impact energy ( E p ) = 320 eV, 500 eV and 1 keV) and incident angles between 0 and 70° . The instrument used was the ATOMIKA 4500 SIMS depth profiler and the sample was Si with ten delta layers of Si 0.7 Ge 0.3 . We observed the narrowest transient widths of between 1.4 and 2.0 nm apparent depth. This was achieved at incident angles (θ) of 30–50° . An extended transient effect was observed when profiled at θ > 50° . Below this incident angle, the transient width is less than twice the penetration depth ( z tr < 2 R norm ). At minimum z tr , z tr ≈ R norm . The detection sensitivity is best achieved at θ ≈ 30° for all energies investigated. The sputter rate is lowest at normal incidence, rising gradually to a maximum at θ ≈ 50–60° . This is similar to that observed with ultralow‐energy O 2 + primary ion beams. At ultralow energies, reducing E p does not have a significant effect in reducing z tr . We conclude that for E p < 1 keV, the optimum condition to achieve minimum z tr while maintaining good sensitivity and high sputter rate is at θ ≈ 30° . Copyright © 2007 John Wiley & Sons, Ltd.

CrossRef 2021
Synthesis and structure of the <i>λ</i> <sup>6</sup>Si-silicate [Cs(18-crown-6)]<sub>2</sub>[Si(OSO<sub>2</sub>CH<sub>3</sub>)<sub>6</sub>]

Isabelle Georg, Michael Bolte, Matthias Wagner et al.

Abstract The λ 6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6] (1) was synthesized by treatment of Si2Cl6 with Cs[OSO2CH3] in the presence of 18-crown-6. Compound 1 is the first example of a λ 6Si-silicate with a methanesulfonate ligand. It was characterized by NMR spectroscopy and by single-crystal X-ray diffraction. The solid-state structure of 1 consists of discrete [Si(OSO2CH3)6]2– anions and two [Cs(18-crown-6)]+ cations (triclinic space group, P 1 ¯ $P\overline{1}$ , Z = 1).

CrossRef 1977
Depth profile detection limit of 3×1015 atom cm−3 for As in Si using Cs+ bombardment negative secondary ion mass spectrometry

Peter Williams, Charles A. Evans

Depth profiles of As-implanted silicon samples have been determined by secondary ion mass spectrometry in order to establish a practical detection limit for As in Si. By monitoring the AsSi− species, produced in high yield by Cs+ ion bombardment, it is shown that As is detectable down to a background count limit of ∼3×1015 atom cm−3 (50 ppb) during a depth profile of a 250-μm square area.

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