Bookmark Saya

CrossRef 2021 2 sitasi

Synthesis and structure of the <i>λ</i> <sup>6</sup>Si-silicate [Cs(18-crown-6)]<sub>2</sub>[Si(OSO<sub>2</sub>CH<sub>3</sub>)<sub>6</sub>]

Isabelle Georg Michael Bolte Matthias Wagner Hans-Wolfram Lerner
Lihat Sumber DOI

Abstrak

Abstract The λ 6Si-silicate [Cs(18-crown-6)]2[Si(OSO2CH3)6] (1) was synthesized by treatment of Si2Cl6 with Cs[OSO2CH3] in the presence of 18-crown-6. Compound 1 is the first example of a λ 6Si-silicate with a methanesulfonate ligand. It was characterized by NMR spectroscopy and by single-crystal X-ray diffraction. The solid-state structure of 1 consists of discrete [Si(OSO2CH3)6]2– anions and two [Cs(18-crown-6)]+ cations (triclinic space group, P 1 ¯ $P\overline{1}$ , Z = 1).

Penulis (4)

I

Isabelle Georg

M

Michael Bolte

M

Matthias Wagner

H

Hans-Wolfram Lerner

Format Sitasi

APA MLA BibTeX
Georg, I., Bolte, M., Wagner, M., Lerner, H. (2021). Synthesis and structure of the <i>λ</i> <sup>6</sup>Si-silicate [Cs(18-crown-6)]<sub>2</sub>[Si(OSO<sub>2</sub>CH<sub>3</sub>)<sub>6</sub>]. https://doi.org/10.1515/znb-2021-0068

Akses Cepat

PDF tidak tersedia langsung

Cek di sumber asli →
Lihat di Sumber doi.org/10.1515/znb-2021-0068
Informasi Jurnal
Tahun Terbit
2021
Bahasa
en
Total Sitasi
2×
Sumber Database
CrossRef
DOI
10.1515/znb-2021-0068
Akses
Terbatas