Hasil untuk "physics.space-ph"

Jin-Zhi Du, Xiao-Jiao Du, Chengqiong Mao et al.

G. Hofmann, J. Smith, K. Johnson et al.

The effect of Ocean Acidification (OA) on marine biota is quasi-predictable at best. While perturbation studies, in the form of incubations under elevated pCO2, reveal sensitivities and responses of individual species, one missing link in the OA story results from a chronic lack of pH data specific to a given species' natural habitat. Here, we present a compilation of continuous, high-resolution time series of upper ocean pH, collected using autonomous sensors, over a variety of ecosystems ranging from polar to tropical, open-ocean to coastal, kelp forest to coral reef. These observations reveal a continuum of month-long pH variability with standard deviations from 0.004 to 0.277 and ranges spanning 0.024 to 1.430 pH units. The nature of the observed variability was also highly site-dependent, with characteristic diel, semi-diurnal, and stochastic patterns of varying amplitudes. These biome-specific pH signatures disclose current levels of exposure to both high and low dissolved CO2, often demonstrating that resident organisms are already experiencing pH regimes that are not predicted until 2100. Our data provide a first step toward crystallizing the biophysical link between environmental history of pH exposure and physiological resilience of marine organisms to fluctuations in seawater CO2. Knowledge of this spatial and temporal variation in seawater chemistry allows us to improve the design of OA experiments: we can test organisms with a priori expectations of their tolerance guardrails, based on their natural range of exposure. Such hypothesis-testing will provide a deeper understanding of the effects of OA. Both intuitively simple to understand and powerfully informative, these and similar comparative time series can help guide management efforts to identify areas of marine habitat that can serve as refugia to acidification as well as areas that are particularly vulnerable to future ocean change.

T. A. Krulwich, G. Sachs, E. Padan

S. Bian, Imali A. Mudunkotuwa, T. Rupasinghe et al.

S. Ohkuma, B. Poole

J. Koufman

I. Tannock, D. Rotin

P. Bullough, F. Hughson, J. Skehel et al.

D. Houben, Laurent Evrard, P. Sonnet

R. V. Benjaminsen, Maria A Mattebjerg, J. Henriksen et al.

Polycations such as polyethylenimine (PEI) are used in many novel nonviral vector designs and there are continuous efforts to increase our mechanistic understanding of their interactions with cells. Even so, the mechanism of polyplex escape from the endosomal/lysosomal pathway after internalization is still elusive. The "proton sponge " hypothesis remains the most generally accepted mechanism, although it is heavily debated. This hypothesis is associated with the large buffering capacity of PEI and other polycations, which has been interpreted to cause an increase in lysosomal pH even though no conclusive proof has been provided. In the present study, we have used a nanoparticle pH sensor that was developed for pH measurements in the endosomal/lysosomal pathway. We have carried out quantitative measurements of lysosomal pH as a function of PEI content and correlate the results to the "proton sponge " hypothesis. Our measurements show that PEI does not induce change in lysosomal pH as previously suggested and quantification of PEI concentrations in lysosomes makes it uncertain that the "proton sponge " effect is the dominant mechanism of polyplex escape.

Kun Wang, Jun Yin, D. Shen et al.

Hongyu Guo, Lu Xu, A. Bougiatioti et al.

Abstract. Particle water and pH are predicted using meteorological observations (relative humidity (RH), temperature (T)), gas/particle composition, and thermodynamic modeling (ISORROPIA-II). A comprehensive uncertainty analysis is included, and the model is validated. We investigate mass concentrations of particle water and related particle pH for ambient fine-mode aerosols sampled in a relatively remote Alabama forest during the Southern Oxidant and Aerosol Study (SOAS) in summer and at various sites in the southeastern US during different seasons, as part of the Southeastern Center for Air Pollution and Epidemiology (SCAPE) study. Particle water and pH are closely linked; pH is a measure of the particle H+ aqueous concentration and depends on both the presence of ions and amount of particle liquid water. Levels of particle water, in turn, are determined through water uptake by both the ionic species and organic compounds. Thermodynamic calculations based on measured ion concentrations can predict both pH and liquid water but may be biased since contributions of organic species to liquid water are not considered. In this study, contributions of both the inorganic and organic fractions to aerosol liquid water were considered, and predictions were in good agreement with measured liquid water based on differences in ambient and dry light scattering coefficients (prediction vs. measurement: slope = 0.91, intercept = 0.5 μg m−3, R2 = 0.75). ISORROPIA-II predictions were confirmed by good agreement between predicted and measured ammonia concentrations (slope = 1.07, intercept = −0.12 μg m−3, R2 = 0.76). Based on this study, organic species on average contributed 35% to the total water, with a substantially higher contribution (50%) at night. However, not including contributions of organic water had a minor effect on pH (changes pH by 0.15 to 0.23 units), suggesting that predicted pH without consideration of organic water could be sufficient for the purposes of aqueous secondary organic aerosol (SOA) chemistry. The mean pH predicted in the Alabama forest (SOAS) was 0.94 ± 0.59 (median 0.93). pH diurnal trends followed liquid water and were driven mainly by variability in RH; during SOAS nighttime pH was near 1.5, while daytime pH was near 0.5. pH ranged from 0.5 to 2 in summer and 1 to 3 in the winter at other sites. The systematically low pH levels in the southeast may have important ramifications, such as significantly influencing acid-catalyzed reactions, gas–aerosol partitioning, and mobilization of redox metals and minerals. Particle ion balances or molar ratios, often used to infer pH, do not consider the dissociation state of individual ions or particle liquid water levels and do not correlate with particle pH.

P. Swietach, R. Vaughan-Jones, A. Harris et al.

Katherine M. Strickler, A. Fremier, C. Goldberg

Boris Zhilyaev, Vladimir Petukhov, Sergey Pokhvala

We use high-tech observations of Unidentified Aerial Phenomena (UAP) class objects to evaluate their characteristics. We present data in three cases. (1) Multi-side daytime observations of UAPs over Kiev. (2) Night observations of a group of objects in the vicinity of the Moon. (3) UAP observations in the combat zone in Ukraine. Dark UAPs in the visible wavelength range are observed only during the day. At night they can only be seen in the infrared wavelength range. We note large sizes of UAPs, from three to six kilometers.They exhibit large velocities, from 2.5 Mach and much larger. They have low albedo, from three percent and below, that is, they actually exhibit features of a completely black body.

V. B. Maciel, C. Yoshida, T. Franco

A polyelectrolyte complex (PEC) matrix formed between chitosan and pectin was developed to entrap a bioactive compound (anthocyanin), obtaining an useful pH indicator device. Polysaccharides of opposite charges such as chitosan and pectin can have a very strong intermolecular interaction. The innovation lies in obtaining a new system based on natural and biodegradable compounds, which is simple to manufacture, to indicate variation in pH by visual changes in colour. This device has potential applications in food packaging. The PEC was studied using chitosan and pectin solutions at different pHs values (3.0, 4.0, 5.0 and 5.5) and pectin/chitosan molar ratios (1.0 to 10/1.0 to 5.0). PEC films were homogeneous and showed the highest yield (60.0%) at pH 5.5. Diffusion tests indicated efficient bioactive compound entrapment in the PEC matrix. Thermogravimetric analysis (TGA), scanning electron microscopy (SEM) and Fourier transform infrared (FTIR) spectroscopy indicate the compatibility between the polymers and bioactive compound.

Yuri V. Khotyaintsev, Daniel B. Graham, Andreas Johlander

We use multi-spacecraft Magnetospheric Multiscale (MMS) observations to investigate electric fields and ion reflection at a non-stationary collisionless perpendicular plasma shock. We identify sub-proton scale (5-10 electron inertial lengths) large-amplitude normal electric fields, balanced by the Hall term ($\mathbf{J} \times \mathbf{B}/ne$), as a transient feature of the shock ramp related to non-stationarity (rippling). The associated electrostatic potential, comparable to the energy of the incident solar wind protons, decelerates incident ions and reflects a significant fraction of protons, resulting in more efficient shock-drift acceleration than a stationary planar shock.

L. Richard, L. Sorriso-Valvo, E. Yordanova et al.

We investigate turbulence in magnetic reconnection jets in the Earth's magnetotail using data from the Magnetospheric Multiscale spacecraft. We show that signatures of a limited inertial range are observed in many reconnection jets. The observed turbulence develops on the time scale of a few ion gyroperiods, resulting in intermittent multifractal energy cascade from the characteristic scale of the jet down to the ion scales. We show that at sub-ion scales, the fluctuations are close to mono-fractal and predominantly kinetic Alfvén waves. The observed energy transfer rate across the inertial range is $\sim 10^8~\mathrm{J}~\mathrm{kg}^{-1}~\mathrm{s}^{-1}$, which is the largest reported for space plasmas so far.

Philip Lubin, Alexander N. Cohen, Jacob Erlikhman

Relativistic spacecraft, like those proposed by the NASA Starlight program and the Breakthrough Starshot Initiative, will have to survive radiation production that is unique when compared to that experienced by conventional spacecraft. In a relativistic interstellar spacecraft's reference frame, the interstellar medium (ISM) will look like a nearly mono-energetic beam of charged particles which impinges upon the leading edge of the spacecraft. Upon impact, ISM protons and electrons will travel characteristic lengths through the spacecraft shield and come to a stop via electronic and nuclear stopping mechanisms. As a result, bremsstrahlung photons will be produced within the spacecraft shield. In this work, we discuss the interstellar environment and its implications for radiation damage on relativistic spacecraft. We also explore expected radiation doses in terms of on-board device radiation tolerance.

Ningning Zhai, Tong Zhang, Dong-xue Yin et al.