Hasil untuk "Chemical industries"

Rania Al-Tohamy, S. Ali, Fang-Chun Li et al.

The synthetic dyes used in the textile industry pollute a large amount of water. Textile dyes do not bind tightly to the fabric and are discharged as effluent into the aquatic environment. As a result, the continuous discharge of wastewater from a large number of textile industries without prior treatment has significant negative consequences on the environment and human health. Textile dyes contaminate aquatic habitats and have the potential to be toxic to aquatic organisms, which may enter the food chain. This review will discuss the effects of textile dyes on water bodies, aquatic flora, and human health. Textile dyes degrade the esthetic quality of bodies of water by increasing biochemical and chemical oxygen demand, impairing photosynthesis, inhibiting plant growth, entering the food chain, providing recalcitrance and bioaccumulation, and potentially promoting toxicity, mutagenicity, and carcinogenicity. Therefore, dye-containing wastewater should be effectively treated using eco-friendly technologies to avoid negative effects on the environment, human health, and natural water resources. This review compares the most recent technologies which are commonly used to remove dye from textile wastewater, with a focus on the advantages and drawbacks of these various approaches. This review is expected to spark great interest among the research community who wish to combat the widespread risk of toxic organic pollutants generated by the textile industries.

Leilei Zhang, Maoxiang Zhou, Aiqin Wang et al.

Selective catalytic hydrogenation has wide applications in both petrochemical and fine chemical industries, however, it remains challenging when two or multiple functional groups coexist in the substrate. To tackle this challenge, the "active site isolation" strategy has been proved effective, and various approaches to the site isolation have been developed. In this review, we have summarized these approaches, including adsorption/grafting of N/S-containing organic molecules on the metal surface, partial covering of active metal surface by metal oxides either via doping or through strong metal-support interaction, confinement of active metal nanoparticles in micro- or mesopores of the supports, formation of bimetallic alloys or intermetallics or core@shell structures with a relatively inert metal (IB and IIB) or nonmetal element (B, C, S, etc.), and construction of single-atom catalysts on reducible oxides or inert metals. Both advantages and disadvantages of each approach toward the site isolation have been discussed for three types of chemoselective hydrogenation reactions, including alkynes/dienes to monoenes, α,β-unsaturated aldehydes/ketones to the unsaturated alcohols, and substituted nitroarenes to the corresponding anilines. The key factors affecting the catalytic activity/selectivity, in particular, the geometric and electronic structure of the active sites, are discussed with the aim to extract fundamental principles for the development of efficient and selective catalysts in hydrogenation as well as other transformations.

R. Rinaldi, R. Jastrzebski, Matthew T Clough et al.

Abstract Lignin is an abundant biopolymer with a high carbon content and high aromaticity. Despite its potential as a raw material for the fuel and chemical industries, lignin remains the most poorly utilised of the lignocellulosic biopolymers. Effective valorisation of lignin requires careful fine‐tuning of multiple “upstream” (i.e., lignin bioengineering, lignin isolation and “early‐stage catalytic conversion of lignin”) and “downstream” (i.e., lignin depolymerisation and upgrading) process stages, demanding input and understanding from a broad array of scientific disciplines. This review provides a “beginning‐to‐end” analysis of the recent advances reported in lignin valorisation. Particular emphasis is placed on the improved understanding of lignin's biosynthesis and structure, differences in structure and chemical bonding between native and technical lignins, emerging catalytic valorisation strategies, and the relationships between lignin structure and catalyst performance.

M. Kamal, S. Razzak, Mohammad. M. Hossain

J. Azmir, I. Zaidul, Md. Mokhlesur Rahman et al.

L. Christenson, R. Sims

G. Guillen, Yinjin Pan, Minghua Li et al.

Jiuyang Lin, Wenyuan Ye, Ming Xie et al.

A. Fakhru’l-Razi, A. Pendashteh, L. Abdullah et al.

K. Chaieb, H. Hajlaoui, Tarek Zmantar et al.

T. Robinson, G. McMullan, R. Marchant et al.

D. Neu, Hussein A. Warsame, K. Pedwell

D. Johnson, K. Hallberg

I. Kapdan, F. Kargı

S. Finkelstein, D. Hambrick

R. Baan, Y. Grosse, K. Straif et al.

B. Das, S. Prakash, P. Reddy et al.

K. Eshun, Qian He

Heng Zhang, Jibin Zhou, Feiyang Xu et al.

The development of chemical engineering technology is a multi-stage process that encompasses laboratory research, scaling up, and industrial deployment. This process demands interdisciplinary col laboration and typically incurs significant time and economic costs. To tackle these challenges, we have developed a system based on ChemELLM in this work. This system enables users to interact freely with the chem ical engineering model, establishing a new paradigm for AI-driven in novation and accelerating technological advancements in the chemical sector.If you would like to experience our system, please visit our official website at: https://chemindustry.iflytek.com/chat.

Pranay Jaiswal, Ivar S. Haugerud, Hidde D. Vuijk et al.

Life relies on a sophisticated metabolic molecular machinery that turns over high-energy molecules to evolve complex macromolecules and assemblies. At the molecular origin of life, such machinery was absent, implying the need for simple yet robust physical mechanisms to harvest energy from the environment and perform chemical work or produce chemical power. However, the mechanisms involved in harvesting energy from a macroscopic cyclic environment to drive chemical processes on the molecular scale remain elusive. In this work, we propose a theory that describes the kinetics of chemical reactions in a system subject to a cyclic reservoir with varying properties. We compare cycles of solvent (wet-dry cycles), with cycles of a component participating in a chemical reaction (reactant cycle). We find that for both wet-dry and reactant cycles, resonance frequencies exist at which the chemical power is maximal. We identify which cycle type is more beneficial in harvesting chemical power for different molecular interactions. Our findings of harvest efficiencies around ten percent suggest that the cyclic environment could have played a key role in catalyzing the metabolic molecular machinery at the molecular origin of life.