Science and technology of ammonia combustion
Hideaki Kobayashi, A. Hayakawa, K.D. Kunkuma . A. Somarathne
et al.
Abstract This paper focuses on the potential use of ammonia as a carbon-free fuel, and covers recent advances in the development of ammonia combustion technology and its underlying chemistry. Fulfilling the COP21 Paris Agreement requires the de-carbonization of energy generation, through utilization of carbon-neutral and overall carbon-free fuels produced from renewable sources. Hydrogen is one of such fuels, which is a potential energy carrier for reducing greenhouse-gas emissions. However, its shipment for long distances and storage for long times present challenges. Ammonia on the other hand, comprises 17.8% of hydrogen by mass and can be produced from renewable hydrogen and nitrogen separated from air. Furthermore, thermal properties of ammonia are similar to those of propane in terms of boiling temperature and condensation pressure, making it attractive as a hydrogen and energy carrier. Ammonia has been produced and utilized for the past 100 years as a fertilizer, chemical raw material, and refrigerant. Ammonia can be used as a fuel but there are several challenges in ammonia combustion, such as low flammability, high NOx emission, and low radiation intensity. Overcoming these challenges requires further research into ammonia flame dynamics and chemistry. This paper discusses recent successful applications of ammonia fuel, in gas turbines, co-fired with pulverize coal, and in industrial furnaces. These applications have been implemented under the Japanese ‘Cross-ministerial Strategic Innovation Promotion Program (SIP): Energy Carriers’. In addition, fundamental aspects of ammonia combustion are discussed including characteristics of laminar premixed flames, counterflow twin-flames, and turbulent premixed flames stabilized by a nozzle burner at high pressure. Furthermore, this paper discusses details of the chemistry of ammonia combustion related to NOx production, processes for reducing NOx, and validation of several ammonia oxidation kinetics models. Finally, LES results for a gas-turbine-like swirl-burner are presented, for the purpose of developing low-NOx single-fuelled ammonia gas turbine combustors.
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S. Fortunato, Carl T. Bergstrom, K. Börner
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Sociology, Medicine
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M. Munafo, Brian A. Nosek, D. Bishop
et al.
Improving the reliability and efficiency of scientific research will increase the credibility of the published scientific literature and accelerate discovery. Here we argue for the adoption of measures to optimize key elements of the scientific process: methods, reporting and dissemination, reproducibility, evaluation and incentives. There is some evidence from both simulations and empirical studies supporting the likely effectiveness of these measures, but their broad adoption by researchers, institutions, funders and journals will require iterative evaluation and improvement. We discuss the goals of these measures, and how they can be implemented, in the hope that this will facilitate action toward improving the transparency, reproducibility and efficiency of scientific research.
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Ziv Epstein, Aaron Hertzmann, L. Herman
et al.
Understanding shifts in creative work will help guide AI’s impact on the media ecosystem The capabilities of a new class of tools, colloquially known as generative artificial intelligence (AI), is a topic of much debate. One prominent application thus far is the production of high-quality artistic media for visual arts, concept art, music, and literature, as well as video and animation. For example, diffusion models can synthesize high-quality images (1), and large language models (LLMs) can produce sensible-sounding and impressive prose and verse in a wide range of contexts (2). The generative capabilities of these tools are likely to fundamentally alter the creative processes by which creators formulate ideas and put them into production. As creativity is reimagined, so too may be many sectors of society. Understanding the impact of generative AI—and making policy decisions around it—requires new interdisciplinary scientific inquiry into culture, economics, law, algorithms, and the interaction of technology and creativity.
538 sitasi
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Computer Science, Medicine
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Exaptation—a Missing Term in the Science of Form
S. Gould, E. Vrba
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P. Johnson-Laird
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C. Brinker
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Advances in the science and technology of carbon nanotubes and their composites: a review
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N. Kaplan, R. Merton, N. Storer
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J. Bond, D. Humphrey, K. Paton
et al.
3537 sitasi
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Political Science