Harper R. Grimsley, Daniel Claudino, S. Economou
et al.
The variational quantum eigensolver (VQE) has emerged as one of the most promising near-term quantum algorithms that can be used to simulate many-body systems such as molecular electronic structures. Serving as an attractive ansatz in the VQE algorithm, unitary coupled cluster (UCC) theory has seen a renewed interest in recent literature. However, unlike the original classical UCC theory, implementation on a quantum computer requires a finite-order Suzuki-Trotter decomposition to separate the exponentials of the large sum of Pauli operators. While previous literature has recognized the non-uniqueness of different orderings of the operators in the Trotterized form of UCC methods, the question of whether or not different orderings matter at the chemical scale has not been addressed. In this letter, we explore the effect of operator ordering on the Trotterized UCCSD ansatz, as well as the much more compact k-UpCCGSD ansatz recently proposed by Lee et al [J. Chem. Theory Comput., 2019, 15, 311; arXiv, 2019, quant-ph:1909.09114]. We observe a significant, system-dependent variation in the energies of Trotterizations with different operator orderings. The energy variations occur on a chemical scale, sometimes on the order of hundreds of kcal/mol. This letter establishes the need to define not only the operators present in the ansatz, but also the order in which they appear. This is necessary for adhering to the quantum chemical notion of a "model chemistry", in addition to the general importance of scientific reproducibility. As a final note, we suggest a useful strategy to select out of the combinatorial number of possibilities, a single well-defined and effective ordering of the operators.
The radiation pressure-like coupling between magnons and phonons in magnets can modify the phonon frequency (magnomechanical spring effect) and decay rate (magnomechanical decay) via dynamical backaction. Such effects have been recently observed by coupling the uniform magnon mode of a magnetic sphere (the Kittel mode) to a microwave cavity. In particular, the ability to evade backaction effects was demonstrated [C.A. Potts et al., arXiv:2211.13766 [quant-ph] (2022)], a requisite for applications such as magnomechanical based thermometry. However, deviations were observed from the predicted magnomechanical decay rate within the standard theoretical model. In this work, we account for these deviations by considering corrections due to (i) magnetic Kerr nonlinearities and (ii) the coupling of phonons to additional magnon modes. Provided that such additional modes couple weakly to the driven cavity, our model yields a correction proportional to the average Kittel magnon mode occupation. We focus our results on magnetic spheres, where we show that the magnetostatic Walker modes couple to the relevant mechanical modes as efficiently as the Kittel mode. Our model yields excellent agreement with the experimental data.
In this paper, we prove a lower bound on the soundness of quantum locally testable codes under the distance balancing construction of Evra et al. arXiv:2004.07935 [quant-ph]. Our technical contribution is that the new soundness of the quantum code is at least the old soundness divided by the classical code length (up to a constant factor). This allows us to use any classical code with independent checks when distance balancing, where previously only the repetition code had been considered for qLTCs. By using a good classical LDPC code, we are able to grow the dimension of the hypersphere product codes arXiv:1608.05089 [quant-ph] and the hemicubic codes arXiv:1911.03069 [quant-ph] while maintaining their distance and locality, but at the expense of soundness. From this, and also by distance balancing a chain complex of Cross et al. arXiv:2209.11405 [cs.IT], we obtain quantum locally testable codes of new parameters.
We discuss critical remarks raised by Horodecki (2023 arXiv:2301.07802 [quant-ph]) toward our work on the connection between superluminal extension of special relativity and fundamental aspects of quantum theory.
We show that Bell correlations may arise as a special sort of selection artefact, produced by ordinary control of the initial state of the experiments concerned. This accounts for nonlocality, without recourse to any direct spacelike causality or influence. The argument improves an earlier proposal in (arXiv:2101.05370v4 [quant-ph], arXiv:2212.06986 [quant-ph]) in two main respects: (i) in demonstrating its application in a real Bell experiment; and (ii) in avoiding the need for a postulate of retrocausality. This version includes an Appendix, discussing the relation of the proposal to the conclusions of Wood and Spekkens (arXiv:1208.4119 [quant-ph]).
We experimentally demonstrate that a squeezed probe optical field can improve the sensitivity of the magnetic field measurements based on nonlinear magneto-optical rotation (NMOR) with an amplitude-modulated pump when compared to a coherent probe field under identical conditions. To realize an all-atomic magnetometer prototype, we utilize a nonlinear atomic interaction, known as polarization self-rotation(PSR), to produce a squeezed probe field. An independent pump field, amplitude-modulated at the Larmor frequency of the bias magnetic field, allows us to extend the range of most sensitive NMOR measurements to sub-Gauss magnetic fields. While the overall sensitivity of the magnetometer is rather low ($>250\mathrm{pT}/\sqrt{\mathrm{Hz}}$, we clearly observe a $15\%$ sensitivity improvement when the squeezed probe is used. Our observations confirm the recently reported quantum enhancement in a modulated atomic magnetometer arXiv:2108.01519 [quant-ph].
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The following protocol is intended for the quantification of double-stranded DNA using Quant-iT™PicoGreen® dsDNA Assay Kit (ThermoFisher). This protocol is a simplified and condensed version of the full protocol from the manufacturer. The procedure described here is for 96 reactions. If samples are run in duplicates, then this should allow quantifying 40 samples.
In this paper, I try once again to cause some good-natured trouble. The issue remains, when will we ever stop burdening the taxpayer with conferences devoted to the quantum foundations? The suspicion is expressed that no end will be in sight until a means is found to reduce quantum theory to two or three statements of crisp physical (rather than abstract, axiomatic) significance. In this regard, no tool appears better calibrated for a direct assault than quantum information theory. Far from a strained application of the latest fad to a time-honored problem, this method holds promise precisely because a large part--but not all--of the structure of quantum theory has always concerned information. It is just that the physics community needs reminding. This paper, though taking quant-ph/0106166 as its core, corrects one mistake and offers several observations beyond the previous version. In particular, I identify one element of quantum mechanics that I would not label a subjective term in the theory--it is the integer parameter D traditionally ascribed to a quantum system via its Hilbert-space dimension.
Every clock is a physical system and thereby ultimately quantum. A naturally arising question is thus how to describe time evolution relative to quantum clocks and, specifically, how the dynamics relative to different quantum clocks are related. This is a particularly pressing issue in view of the multiple choice facet of the problem of time in quantum gravity, which posits that there is no distinguished choice of internal clock in generic general relativistic systems and that different choices lead to inequivalent quantum theories. Exploiting a recent unifying approach to switching quantum reference systems [Vanrietvelde et al 2020 Quantum 4 225; Vanrietvelde et al 2018 arXiv:1809.05093[quant-ph])], we exhibit a systematic method for switching between different clock choices in the quantum theory. We illustrate it by means of the parametrized particle, which, like gravity, features a Hamiltonian constraint. We explicitly switch between the quantum evolution relative to the non-relativistic time variable and that relative to the particle’s position, which requires carefully regularizing the zero-modes in the so-called time-of-arrival observable. While this toy model is simple, our approach is general and, in particular, directly amenable to quantum cosmology. It proceeds by systematically linking the reduced quantum theories relative to different clock choices via the clock-choice-neutral Dirac quantized theory, in analogy to coordinate changes on a manifold. This method suggests a new perspective on the multiple choice problem, indicating that it is rather a multiple choice feature of the complete relational quantum theory, taken as the conjunction of Dirac quantized and quantum deparametrized theories. Precisely this conjunction permits one to consistently switch between different temporal reference systems, which is a prerequisite for a quantum notion of general covariance. Finally, we show that quantum uncertainties generically lead to a discontinuity in the relational dynamics when switching clocks, in contrast to the classical case.
The following protocol is intended for the quantification of RNA using Quant-iT™ RiboGreen™ RNA Assay Kit (ThermoFisher). This protocol is a simplified and condensed version of the full protocol from the manufacturer. The procedure described here is for 96 reactions. If samples are run in duplicates, then this should allow quantifying 40 samples.
Recently, the basic concept of quantum coherence (or superposition) has gained a lot of renewed attention, after Baumgratz et al. (Phys. Rev. Lett. 113, 140401. (doi:10.1103/PhysRevLett.113.140401)), following Åberg (http://arxiv.org/abs/quant-ph/0612146), have proposed a resource theoretic approach to quantify it. This has resulted in a large number of papers and preprints exploring various coherence monotones, and debating possible forms for the resource theory. Here, we take the view that the operational foundation of coherence in a state, be it quantum or otherwise wave mechanical, lies in the observation of interference effects. Our approach here is to consider an idealized multi-path interferometer, with a suitable detector, in such a way that the visibility of the interference pattern provides a quantitative expression of the amount of coherence in a given probe state. We present a general framework of deriving coherence measures from visibility, and demonstrate it by analysing several concrete visibility parameters, recovering some known coherence measures and obtaining some new ones.
A recent paper [Z. Yu and S. Prasad, "Quantum limited superresolution of an incoherent source pair in three dimensions," arXiv:1805.09227v2 [quant-ph] (2018)] considered the problem of quantum limited estimation of the separation vector for a pair of incoherent point sources in all three dimensions. Here we extend our analysis to treat the problem of simultaneously estimating the location of the centroid and the separation of the source pair, which is equivalent to localizing both sources simultaneously. We first calculate the quantum Fisher information for simultaneous pair centroid-separation estimation and then discuss the fundamental, estimation-theoretic trade-offs between the two tasks, which we confirm using simulations.
We explore the multiparticle transition probabilities in Gaussian unitaries effected by a two-mode Bogoliubov bosonic transformation on the mode annihilation and creation operators. We show that the transition probabilities can be characterized by remarkably simple, yet unsuspected recurrence equations involving a linear combination of probabilities. The recurrence exhibits an interferometric suppression term - a negative probability - which generalizes the seminal Hong-Ou-Mandel effect to more than two indistinguishable photons impinging on a beam splitter of rational transmittance. Unexpectedly, interferences thus originate in this description from the cancellation of probabilities instead of amplitudes. Our framework, which builds on the generating function of the non-Gaussian matrix elements of Gaussian unitaries in Fock basis, is illustrated here for the most common passive and active linear coupling between two optical modes driven by a beam splitter or a parametric amplifier. Hence, it also allows us to predict unsuspected multiphoton interference effects in an optical amplifier of rational gain. In particular, we confirm the newly found two-photon interferometric suppression effect in an amplifier of gain 2 originating from timelike indistinguishability (arXiv:2012.15165 [quant-ph]). Overall, going beyond standard two-mode optical components, we expect our method will prove valuable for describing general quantum circuits involving Bogoliubov bosonic transformations.
The following protocol is intended for the quantification of RNA using Quant-iT™ RiboGreen™ RNA Assay Kit (ThermoFisher). This protocol is a simplified and condensed version of the full protocol from the manufacturer. The procedure described here is for 96 reactions. If samples are run in duplicates, then this should allow quantifying 40 samples.
This invited chapter in the Handbook of Quantum Logic and Quantum Structures consists of two parts: 1. A substantially updated version of quant-ph/0402130 by the same authors, which initiated the area of categorical quantum mechanics, but had not yet been published in full length; 2. An overview of the progress which has been made since then in this area.