Recent Advances in Carbon Dioxide Hydrogenation to Methanol via Heterogeneous Catalysis.
Xiao Jiang, X. Nie, Xinwen Guo
et al.
The utilization of fossil fuels has enabled an unprecedented era of prosperity and advancement of well-being for human society. However, the associated increase in anthropogenic carbon dioxide (CO2) emissions can negatively affect global temperatures and ocean acidity. Moreover, fossil fuels are a limited resource and their depletion will ultimately force one to seek alternative carbon sources to maintain a sustainable economy. Converting CO2 into value-added chemicals and fuels, using renewable energy, is one of the promising approaches in this regard. Major advances in energy-efficient CO2 conversion can potentially alleviate CO2 emissions, reduce the dependence on nonrenewable resources, and minimize the environmental impacts from the portions of fossil fuels displaced. Methanol (CH3OH) is an important chemical feedstock and can be used as a fuel for internal combustion engines and fuel cells, as well as a platform molecule for the production of chemicals and fuels. As one of the promising approaches, thermocatalytic CO2 hydrogenation to CH3OH via heterogeneous catalysis has attracted great attention in the past decades. Major progress has been made in the development of various catalysts including metals, metal oxides, and intermetallic compounds. In addition, efforts are also put forth to define catalyst structures in nanoscale by taking advantage of nanostructured materials, which enables the tuning of the catalyst composition and modulation of surface structures and potentially endows more promising catalytic performance in comparison to the bulk materials prepared by traditional methods. Despite these achievements, significant challenges still exist in developing robust catalysts with good catalytic performance and long-term stability. In this review, we will provide a comprehensive overview of the recent advances in this area, especially focusing on structure-activity relationship, as well as the importance of combining catalytic measurements, in situ characterization, and theoretical studies in understanding reaction mechanisms and identifying key descriptors for designing improved catalysts.
1128 sitasi
en
Chemistry, Medicine
Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
H. Chung, D. Cullen, Drew C. Higgins
et al.
1366 sitasi
en
Chemistry, Medicine
The molten salt reactor (MSR) in generation IV: Overview and perspectives
J. Serp, M. Allibert, O. Bene
et al.
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption.
D. Strmčnik, M. Uchimura, Chao Wang
et al.
1151 sitasi
en
Medicine, Chemistry
Accident tolerant fuels for LWRs: A perspective
S. Zinkle, K. Terrani, J. Gehin
et al.
962 sitasi
en
Materials Science
Recycling of carbon dioxide to methanol and derived products - closing the loop.
Alain Goeppert, M. Czaun, John-Paul Jones
et al.
946 sitasi
en
Chemistry, Medicine
Microbial engineering for the production of advanced biofuels
Pamela Peralta-Yahya, Fuzhong Zhang, S. D. Cardayré
et al.
1048 sitasi
en
Business, Medicine
Kinetic modeling of gasoline surrogate components and mixtures under engine conditions
M. Mehl, W. Pitz, C. Westbrook
et al.
Review of hydrogen storage techniques for on board vehicle applications
D. J. Durbin, C. Malardier-Jugroot
High-Flux Solar-Driven Thermochemical Dissociation of CO2 and H2O Using Nonstoichiometric Ceria
W. Chueh, C. Falter, M. Abbott
et al.
1388 sitasi
en
Medicine, Chemistry
Nanostructured Materials for Electrochemical Energy Conversion and Storage Devices
Yu‐Guo Guo, Jinsong Hu, L. Wan
2121 sitasi
en
Materials Science, Chemistry
Vehicle Propulsion Systems: Introduction to Modeling and Optimization
L. Guzzella, A. Sciarretta
1062 sitasi
en
Engineering
Energy production from biomass (Part 3): Gasification technologies.
P. McKendry
1223 sitasi
en
Engineering, Medicine
Changing the activity of electrocatalysts for oxygen reduction by tuning the surface electronic structure.
V. Stamenković, B. Mun, K. Mayrhofer
et al.
1988 sitasi
en
Chemistry, Medicine
Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and Oxygen
A. Bard, M. Fox
Inexpensive renewable electricity enables Saudi Arabia's fuel price reforms
Walid Matar
Saudi Arabia is currently implementing fuel price reforms. The reforms are being executed in phases, where the ultimate goal is to have fuel prices approach their market equivalent values. Using the KAPSARC Energy Model, this analysis shows that such reforms would be more costly for Saudi Arabia without the availability and cost reductions of renewable electricity technologies. Solar photovoltaic technologies, in particular, have made enacting fuel price reforms more tenable. As the use of oil products for power generation and industrial processes cease due to price reforms, renewable technologies mitigate the scarcity of natural gas. For instance, lower natural gas use by the electricity sector would result in a market-clearing (meaning, demand equals supply) natural gas price of 3–4 $/mmBtu in 2040 with the deployment of renewable technologies. The projected rise in Saudi natural gas supply and these prices are sufficient to accommodate nearly 50 GW of renewable electricity capacity. Comparatively, this natural gas price would be above 7 $/mmBtu without renewable electricity. The advent of inexpensive renewable electricity lowers fuel costs for all natural gas users in industry and utilities. Moreover, the marginal electricity generation cost with renewable electricity drops by 30 %, on average. While renewable electricity reduces energy system costs, the magnitude of these benefits is highly dependent on the exogenously-defined domestic gas availability and the global LNG price. These findings suggest aligning fuel price regulations with renewable electricity deployment to minimize cost shocks and reduce oil use in industrial and utility sectors.
Energy industries. Energy policy. Fuel trade
Mass transfer and water management in proton exchange membrane fuel cells with a composite foam-rib flow field
Wei Gao, Qifeng Li, Kai Sun
et al.
Mass transfer capability of reactants and hydrothermal management is important for the performance and durability of proton exchange membrane fuel cells. In the conventional rib flow field, the oxygen transport is affected by the accumulation of under-rib liquid water which causes excessive concentration loss and limits cell performance. To improve the cell performance, a composite foam-rib flow field structure is proposed by combining the metal foam flow field and the conventional rib flow field. The proposed design is simulated by using a three-dimensional homogeneous non-isothermal numerical model. The results show that the composite foam-rib flow field, by improving the oxygen transfer and water removal capabilities under the ribs, can improve the oxygen concentration and current density without increasing the pumping power, thus improving the cell performance under different conditions. The key parameters of the composite foam-rib flow field are optimized. With the optimal metal foam filling ratio of 0.75 and porosity of 0.85, the peak power density and the limiting current density for the composite foam-rib flow field are higher than the conventional rib flow field by 5.20% and 22.68%.
en
physics.flu-dyn, physics.app-ph
Monitoring of Fluid Transport in Low Temperature Water Electrolyzers and Fuel Cells: Emerging Technologies and Future Prospects
Zehua Dou, Laura Tropf, Tobias Lappan
et al.
Low temperature water electrolyzers (LTWEs) and low temperature hydrogen fuel cells (LTFCs) present a promising technological strategy for the productions and usages of green hydrogen energy towards a net-zero world. However, the interactions of gas/liquid (fluid) transport and the intrinsic reaction kinetics in LTWEs/LTFCs present one of the key hurdles hindering high production rate and high energy conversion efficiency. Addressing these limitations requires analytical tools that are capable of resolving fluid transport across the heterogeneous, multiscale structures of operating LTWE and LTFC systems. This review provides a comprehensive overview of recent advancements in measurement technologies for investigating fluid transport. We first outline the technical requirements of such analytical systems, and assess the capabilities and limitations of established optical, X-rays and neutrons based imaging systems. We emphasis on emerging strategies that utilize integrated miniaturized sensors, ultrasound, and other alternative physical principles to achieve operando, high-resolution, and scalable measurements towards applications at device and system levels. Finally, we outline future directions in this highly interdisciplinary field, emphasizing the importance of next-generation sensing concepts to overcome the fluid transport hurdle, towards accelerating the deployment of green hydrogen technologies.
Multi-Machine Scaling Laws for Fuel and Impurity Puffing Rates Sufficient for Detachment Access: a Systematic Review of Magnetic Confinement Fusion Devices
M. Moscheni, A. Herrmann, R. Kembleton
et al.
An open-source database of 457 experimental and numerical entries representing 32 machines$-$including tokamaks, stellarators, and linear plasma devices$-$is assembled. From this dataset, we derive multi-machine scaling laws that predict the fuel and impurity puffing rates sufficient to edge plasma detachment$-$the leading reactor-relevant solution to the challenge of plasma-wall interaction. Validation against up to 40 L- and H-mode plasmas shows agreement within a factor of 1.5 in about 50\% of cases, and within a factor of 2 on average. Divertor volume alone is found to strongly correlate with the fuelling rate. Inclusion of plasma opaqueness leads to $Γ_{\text{D}} \propto [n_{\text{sep}}\, a\, (S_{\text{div}}/V_{\text{div}})^{-1.5}]^{1.05}$, valid across all toroidal devices. Its H-mode simplification, $Γ_{\text{D}}^{\text{HDL}} \propto 0.43\, a^{1.58}\, λ_q^{-0.89}$, avoids explicit dependence on $n_{\text{sep}}$ and carries intrinsic physical meaning through the H/L density limit and the power fall-off length. The impurity seeding rate is captured by a general non-linear law, from which the Greenwald-Eich-Scarabosio simplification, $Γ_{\text{Z}}^{\text{GES}} \propto a^{1.51}\, λ_q^{-0.27}$, is obtained. Similar relationships are defined for stellarators, consistent with tokamak trends but still awaiting validation$-$an opportunity for further study. These results have immediate relevance for reactor fuel-cycle design and edge plasma modelling. More broadly, they demonstrate that physics-based 0D laws can reliably link detachment access to engineering actuators, offering practical tools for reactor design. Our laws represent macroscopic patterns across machines rather than microscopic variations within an individual device$-$providing the basis for our forthcoming studies aimed at extending this framework to machine-specific behaviour.
Amplifying microwave pulses with a single qubit engine fueled by quantum measurements
Rémy Dassonneville, Cyril Elouard, Romain Cazali
et al.
Recent progress in manipulating individual quantum systems enables the exploration of engines exploiting non-classical resources. One of the most appealing is the energy provided by the inherent backaction of quantum measurements. While a handful of experiments have investigated the inner dynamics of engines fueled by measurement backaction, powering a task by such an engine is missing. Here we demonstrate the amplification of microwave signals by an engine fueled by repeated quantum measurements of a superconducting transmon qubit. Using feedback, the engine acts as a quantum Maxwell demon operating without a hot thermal source. Measuring the gain of this amplification constitutes a direct probing of the work output of the engine, in contrast with inferring the work by measuring the qubit state along its evolution. Observing a good agreement between both work estimation methods, our experiment validates the accuracy of the indirect method. We characterize the long-term stability of the engine as well as its robustness to transmon decoherence, loss and drifts. Our experiment exemplifies the use of energy brought by quantum measurement backaction.
en
quant-ph, cond-mat.mes-hall