The growing global demand for clean and sustainable energy has reignited interest in nuclear power as a carbon-free alternative to fossil fuels, driving an increase in uranium mining. However, uranium extraction releases radioactive elements along with toxic and heavy metals, posing serious environmental risks. A combined narrative and systematic review was employed to evaluate remediation mechanisms, performance trends, sustainability, and emerging technological advancements. The results indicate that phytoremediation remains the most extensively studied and field-applicable technique, while phycoremediation offers rapid uptake in aqueous systems and mycoremediation demonstrates higher tolerance to extreme conditions. However, limitations such as slow remediation rates, site-specific performance, and scalability challenges restrict their widespread implementation. This study also highlights the emerging role of artificial intelligence and machine learning in optimizing remediation processes, although their application remains limited, particularly in fungal systems. Furthermore, the integration of nature-based solutions into nuclear waste management frameworks, aligned with international safety standards, presents a promising pathway for sustainable remediation. Future research should focus on developing hybrid remediation strategies, establishing performance thresholds under high contamination conditions, and advancing AI-driven, site-specific optimization models to enhance efficiency and scalability.
Antonio Conversano, Samuele Alemanno, Davide Sogni
et al.
The REPowerEU plan is aimed at a target of 35 bcm of biomethane annually by 2030, up from 4 bcm in 2023, requiring about EUR 37 billion in investment. Food waste is identified as a key feedstock, characterized by discrete homogeneity, although its availability may vary seasonally. In Italy, the Emilia-Romagna region generates approximately 450 kt/y of industrial waste from the food and beverage sector, primarily originating from meat processing (NACE 10.1), fruit and vegetable processing (NACE 10.3), and the manufacture of vegetable and animal oils and fats (NACE 10.4). Of this amount, food and beverage processing waste (EWC 02) accounts for about 302 kt from NACE 10 (food, year 2019) and 14 kt from NACE 11 (beverage, year 2019). This study provides a comprehensive screening of waste streams generated by the local food and beverage industry in Emilia-Romagna, evaluating the number of enterprises, their value added, and recorded waste production. The screening led to the identification of suitable streams for further valorization strategies: a total of ~93 kt/y was selected for the preliminary conceptual design of an integrated process combining anaerobic digestion with hydrothermal treatment, aimed at supporting national biomethane production targets while maximizing material recovery through hydrochar production. Preliminary estimations indicate that the proposed process may achieve a biochemical methane potential of approximately 0.23 Nm<sup>3</sup>/kg<sub>VS</sub>, along with a hydrochar yield of about 130 kg/t<sub>waste</sub>.
The utilization of Solid Waste Compost (SWC) as an organic fertilizer (OF) in agriculture has garnered significant attention in recent years due to growing concerns about worsening waste management issues. This empirical study investigates paddy farmers’ perceptions of SWC under Sri Lanka’s organic farming policy and uniquely addresses its underexploited potential as an organic fertilizer. Data were collected from 254 respondents in the Attanagalla Divisional Secretariat Division via a structured questionnaire. Nine key performance indicators were established to evaluate SWC against other organic fertilizers considered for the study. Findings revealed that meeting the ‘required quantity’ OF was the most challenging aspect (91%) for organic paddy cultivation, while only 14.2% of paddy farmers were able to utilize SWC for paddy fields due to limited availability. Farmers appreciated SWC as the most effective in balancing pest–predator interactions, even surpassing straw; however, its availability lagged compared to alternatives such as straw. Farmers expressed a higher likelihood of adopting SWC if it met government certification standards. The findings conclude that, while increasing production of SWC could enhance its role as an organic fertilizer in paddy farming, achieving its quality standards for paddy farming through government standard certification is crucial for successful implementation.
Agricultural waste poses significant environmental, economic, and social challenges globally, with estimates indicating that 10–50% of agricultural products are discarded annually as waste. This review explores strategies for managing agricultural waste to mitigate its adverse impacts and promote sustainable development. Agricultural residues, such as those from sugarcane, rice, and wheat, contribute to pollution when improperly disposed of through burning or burying, contaminating soil, water, and air. However, these residues also represent untapped resources for bioenergy production, composting, mulching, and the creation of value-added products like biochar, bioplastics, single-cell protein and biobased building blocks. The paper highlights various solutions, including integrating agricultural waste into livestock feed formulations to reduce competition for human food crops, producing biofuels like ethanol and biodiesel from lignocellulosic materials, and adopting circular economy practices to upcycle waste into high-value products. Technologies such as anaerobic digestion for biogas production and gasification for synthesis gas offer renewable energy alternatives and ample feedstocks for gas fermentation while addressing waste management issues. Composting and vermicomposting enhance soil fertility, while mulching improves moisture retention and reduces erosion. Moreover, the review emphasizes the importance of policy frameworks, public-private partnerships, and farmer education in promoting effective waste management practices. By implementing these strategies, agricultural waste can be transformed into a resource, contributing to food security, environmental conservation, and economic growth.
Pretreatment of lignocellulosic biomass remains the primary obstacle to the profitable use of this type of biomass in biorefineries. The challenge lies in the recalcitrance of the lignin-carbohydrate complex to pretreatment, especially the difficulty in removing the lignin to access the carbohydrates (cellulose and hemicellulose). This study had two objectives: (i) to investigate the effect of reactive extrusion on lignocellulosic biomass in terms of delignification percentage and the structural characteristics of the resulting extrudates, and (ii) to propose a novel pretreatment approach involving extrusion technology based on the results of the first objective. Two types of biomasses were used: agricultural residue (corn stover) and forest residue (black spruce chips). By optimizing the extrusion conditions via response surface analysis (RSA), the delignification percentages were significantly improved. For corn stover, the delignification yield increased from 2.3% to 27.4%, while increasing from 1% to 25.3% for black spruce chips. The highest percentages were achieved without the use of sodium hydroxide and for temperatures below 65 °C. Furthermore, the optimized extrudates exhibited important structural changes without any formation of p-cresol, furfural, and 5-hydroxymethylfurfural (HMF) (enzymes and microbial growth-inhibiting compounds). Acetic acid however was detected in corn stover extrudate. The structural changes included the disorganization of the most recalcitrant functional groups, reduction of particle sizes, increase of specific surface areas, and the appearance of microscopic roughness on the particles. Analyzing all the data led to propose a new promising approach to the pretreatment of lignocellulosic biomasses. This approach involves combining extrusion and biodelignification with white rot fungi to improve the enzymatic hydrolysis of carbohydrates.
Souphaphone Soudachanh, Alessio Campitelli, Stefan Salhofer
One of the largest issues facing countries, particularly emerging nations with high population, production, and consumption growth, is an inadequate waste management system (WMS). This paper analyzes the development of the waste management systems of nine capital cities in the Association of Southeast Asian Nations (ASEAN) region by using a recently developed approach, the Waste Management System–Development Stage Concept. This concept comprises five development stages and various components, including Collection and Transport, Waste Disposal, Energy Recovery, Waste Recycling, and Waste Prevention and Reuse. The findings indicate that in terms of waste collection, waste disposal, and energy recovery, Singapore is at a higher development stage (Stage 5) and is more advanced than other ASEAN cities. For most of the components, Bangkok, Jakarta, Kuala Lumpur, and Manila fall into stages 2 to 4, whereas the early development stages 1 to 3 are present in Bandar Seri Begawan, Hanoi, Phnom Penh, and Vientiane. The results will be used to determine the next steps in developing the WMSs, including the introduction of separate collection for recycling or the installation of a waste-to-energy plant. The environmental impact of each measure will be later assessed using the LCA approach, and the most effective measures shall be identified in future studies.
Sergey M. Frolov, Anton S. Silantiev, Ilias A. Sadykov
et al.
Reported in the article is further progress in the development of the novel pulsed detonation gun (PDG) technology for the conversion of organic wastes into syngas in a two-component gasifying agent (GA) containing ultra-superheated steam and carbon dioxide obtained by pulsed detonations of a natural gas–oxygen mixture at a frequency of 1 Hz. Experimental studies were carried out on a waste converter with a 40 dm<sup>3</sup> flow reactor and two PDGs with a total volume of 2.4 or 3.2 dm<sup>3</sup>, which is approximately a factor of 6 and 4.5 less than in previous studies, respectively. The objective of the research was to find the design and operation parameters of the waste converter that provide a minimum amount of CO<sub>2</sub> in the gasification products. Waste machine oil was used as a feedstock. It is shown that, compared with the earlier experiments with a higher average temperature of the reactor wall and with a PDG of a much larger volume, the contents of H<sub>2</sub>, CO, CH<sub>4</sub>, and CO<sub>2</sub> in the syngas remained virtually unchanged, whereas the efficiency of the gasification process increased significantly: the use of 1 g of natural gas made it possible to gasify up to 4 g of the feedstock. It is also shown that the determining role in the gasification process of liquid feedstock is played by the feedstock residence time in the PDG rather than in the reactor. The minimum ratio between the flow rates of the GA and liquid feedstock, the minimum ratio between the flow rates of combustible gas and liquid feedstock, as well as the actual GA consumption in the gasification process are determined experimentally.
The construction industry is among the most prominent contributors to global resource consumption, waste production, and greenhouse gas emissions. A pivotal step toward mitigating these sectoral impacts lies in the adoption of a circular production and consumption system. The use of alternative waste materials can mitigate landfill accumulation and the associated detrimental environmental effects. To highlight unconventional materials, this study began with a bibliometric assessment via a bibliography analyzis software called “Bibliometrix” (version 4.1.3). The outputs from the analyzis can assist in identifying research trends, gaps in literature and benchmark research performance. The search engine used for sourcing publications was Scopus, using the main criteria as “Waste materials used in building and construction”. The time-period analysed was from 2013 to 2023. The results included publications obtained in journal articles, book chapters and conference proceedings. The assessment reviewed 6238 documents from 1482 sources. The results revealed an array of waste materials; however, rubber, textiles, and ceramics had a significant reduction in research attention. Rubber waste presents promising opportunities in civil concrete construction methods. The preparatory steps of textile fibres in composite materials are frequently disregarded, resulting in structural issues for the end-product. Obstacles persist in ceramic technology due to the absence of transparency, primarily because industry entities closely safeguard proprietary information. While sustainability research often emphasizes emissions, practical trials commonly revolve around integrating materials into current systems. A more comprehensive approach, contemplating the complete lifecycle of materials, could provide deeper insights into fostering sustainable construction practices. Researchers can use these findings when determining trends, research gaps, and future research directions.
An option to reduce the exploitation and depletion of natural mineral resources is to repurpose current waste materials. Fillers are often added to polymers to improve the properties and lower the overall cost of the final product. Very few studies have assessed the use of waste brown eggshell powder (BESP) as filler in polylactic acid (PLA). The addition of mineral fillers in a polymer matrix can play an important role in the performance of a composite under load. Therefore, tailoring the amount of filler content can be a deciding factor as to which filler amount is best. The goal of this study was to investigate the effect of brown eggshells compared to conventional limestone (LS) powder on the mechanical properties of PLA composites. One-way analysis of variance (ANOVA) was used to carry out the statistical analysis on the average values of each composite mechanical property tested. Scanning electron microscopy (SEM) was used to view if there were any differences in the fractured surfaces. Overall, the LS performed marginally better than the BESP fillers. The highest ultimate tensile and ultimate flexural strengths for eggshell composites containing 32 µm fillers had values of 48 MPa (5–10 wt.% BESP) and 67 MPa (10 wt.%. BESP), respectively. Both the tensile and flexural modulus improved with filler contents and were highest at 20 wt.% with values of 4.5 GPa and 3.4 GPa, respectively. The Charpy impact strength decreased for all filler amounts. SEM micrographs identified changes in the fractured surfaces due to the additions of the filler materials. The ANOVA results showed statistically significant differences for the composite materials. After five weeks of soaking in distilled water, the composites containing 20 wt.% BESP fillers had the highest weight gain. The study demonstrated that waste brown eggshells in powdered form can be used as a filler in PLA composites.
Guilherme Peixoto, Gustavo Mockaitis, Wojtyla Kmiecik Moreira
et al.
Second-generation (2G) ethanol production has been increasingly evaluated, and the use of sugarcane bagasse as feedstock has enabled the integration of this process with first-generation (1G) ethanol production from sugarcane. The pretreatment of bagasse generates pentose liquor as a by-product, which can be anaerobically processed to recover energy and value-added chemicals. The potential to produce biohydrogen and organic acids from pentose liquor was assessed using a mesophilic (25 °C) upflow anaerobic packed-bed bioreactor in this study. An average organic loading rate of 11.1 g COD·L<sup>−1</sup>·d<sup>−1</sup> was applied in the reactor, resulting in a low biohydrogen production rate of 120 mL·L<sup>−1</sup> d<sup>−1</sup>. Meanwhile, high lactate (38.6 g·d<sup>−1</sup>), acetate (31.4 g·d<sup>−1</sup>), propionate (50.1 g·d<sup>−1</sup>), and butyrate (50.3 g·d<sup>−1</sup>) production rates were concomitantly obtained. Preliminary analyses indicated that the full-scale application of this anaerobic acidogenic technology for hydrogen production in a medium-sized 2G ethanol distillery would have the potential to completely fuel 56 hydrogen-powered vehicles per day. An increase of 24.3% was estimated over the economic potential by means of chemical production, whereas an 8.1% increase was calculated if organic acids were converted into methane for cogeneration (806.73 MWh). In addition, 62.7 and 74.7% of excess organic matter from the 2G ethanol waste stream could be removed with the extraction of organic acid as chemical commodities or their utilization as a substrate for biomethane generation, respectively.
Magdalena Lech, Oliwia Gala, Karolina Helińska
et al.
Nowadays, electroplating plants are factories that use huge amounts of water in the coating process of anti-corrosion layers. They are required to decrease the heavy metal content to very low values before releasing the post-process water into the aquatic environment. They very often decrease their content using coagulation combined with flocculation. However, these processes are often not effective enough, and the concentration of a given metal does not reach a satisfactory low level. The use of membrane techniques to purify this type of wastewater leads to a reduction in the content of heavy metals, including nickel, to zero values. This allows for not only reducing the negative impact on the aquatic environment but also a step toward more conscious management of water resources—namely, the reuse of water in the electroplating process. The following review not only describes the membrane methods used to treat the wastewater considered, e.g., nanofiltration, ultrafiltration, or electrodialysis, but also shows the directions of development of these processes.
Portia Adade Williams, Satyanarayana Narra, Edward Antwi
et al.
Issues of rising waste generation are calling for proper management and the sustainable control of waste. This study examines waste- and energy-relevant policies and strategies in Ghana and the stakeholders’ perceptions on such policies and strategies. It explores the gaps and challenges in national policy documents to guide the implementation of waste-to-energy projects in Ghana. The approach adopted includes a comprehensive review of relevant policy documents and key informant interviews with selected key stakeholders. Factors such as limited funding, inadequate logistics, expertise and infrastructure, growing population and negative attitudes of general public towards the environment, amongst others, are the concerns identified. Findings from the policy review revealed that capacity to harness energy from waste could be improved through appropriate technologies suitable for Ghana. Adequate institutional framework, stakeholders and mechanisms to explore opportunities to coordinate implementation of various policy strategies and interventions have been established. Streamlining strategies to constitute components to improve governance on waste management, improving financing to ensure sustainable investment in waste-to-energy projects, improving research on waste-to-energy technologies as well as enhancing public interest and education on proper waste management could enhance the implementation of national waste and energy policies for feasible up-scaling of waste-to-energy technologies in Ghana.
Dye-containing effluent generated in textile industries is polluting and complex wastewater. It should be managed adequately before its final destination. The up-flow anaerobic blanket (UASB) reactor application is an ecofriendly and cost-competitive treatment. The present study briefly reviews the UASB application for dye-containing wastewater valorization. Bioenergy and clean-water production potential during dye-containing wastewater treatment are emphasized to promote resource recovery in textile industries. Hydraulic retention time (HRT), organic loading rate (OLR), pH, temperature, and hydraulic mixing influence sludge granulation, microbial activity, and dye removal. HRT and OLR ranges of 6–24 h and 1–12 kg m<sup>−3</sup> d<sup>−1</sup> of chemical oxygen demand (COD) at a mesophilic temperature (30–40 °C) are recommended for efficient treatment. In these conditions, efficiencies of color and COD of 50–97% and 60–90% are reported in bench-scale UASB studies. Complex dye structures can hinder biomineralization. Pretreatment may be necessary to reduce dye concentration. Carbon-source and redox mediators are added to the UASB reactor to expedite kinetic reactions. A biogas yield of 1.48–2.70 L d<sup>−1</sup> in UASB, which treats dye-containing effluents, is documented. Cotreatment of dye wastewater and locally available substrate could increase biogas productivity in UASB reactors. Organic waste generated in the textile industry, such as dye sludge, cotton, and starch, is recommended to make cotreatment cost competitive. Bioenergy production and water reuse allow environmental and economic benefits. Studies on combined systems integrating UASB and membrane processes, such as ultrafiltration and nanofiltration, for the production of reusable water and pretreatment of wastewater and sludge for improvements in biogas production might realize the complete potential for resource recovery of UASB technology. UASB bioenergy usage for integrated treatment trains can reduce operating costs and assist process sustainability in the textile industry.
Zarifeh Raji, Ahasanul Karim, Antoine Karam
et al.
Heavy metal contamination in wastewater is a significant concern for human health and the environment, prompting increased efforts to develop efficient and sustainable removal methods. Despite significant efforts in the last few decades, further research initiatives remain vital to comprehensively address the long-term performance and practical scalability of various adsorption methods and adsorbents for heavy metal remediation. This article aims to provide an overview of the mechanisms, kinetics, and applications of diverse adsorbents in remediating heavy metal-contaminated effluents. Physical and chemical processes, including ion exchange, complexation, electrostatic attraction, and surface precipitation, play essential roles in heavy metal adsorption. The kinetics of adsorption, influenced by factors such as contact time, temperature, and concentration, directly impact the rate and effectiveness of metal removal. This review presents an exhaustive analysis of the various adsorbents, categorized as activated carbon, biological adsorbents, agricultural waste-based materials, and nanomaterials, which possess distinct advantages and disadvantages that are linked to their surface area, porosity, surface chemistry, and metal ion concentration. To overcome challenges posed by heavy metal contamination, additional research is necessary to optimize adsorbent performance, explore novel materials, and devise cost-effective and sustainable solutions. This comprehensive overview of adsorption mechanisms, kinetics, and diverse adsorbents lays the foundation for further research and innovation in designing optimized adsorption systems and discovering new materials for sustainable heavy metal remediation in wastewater.
This study characterises materials that belong to the group of refuse-derived fuels (RDF). This group of materials regarded as an alternative fuel is derived from industrial, municipal solid and commercial wastes. The aim of this study is to evaluate the quality of waste composition, demonstrate statistically different values and the energy efficiency of the fuel derived from waste. Data on incinerated waste were collected from two different sources. The basic physical and chemical parameters of waste include density and water content. The lower heating value (LHV) of waste, chlorine concentration and ash content of two groups of incinerated waste were also evaluated and compared for a given period of time (one year, with monthly breakdown). Statistical analysis indicated the differences in the combustion of waste groups, visualized by box plots and other diagrams to show the distribution of the results. An analysis of exhaust gas parameters was carried out, both in terms of chemical composition and energy parameters. The RDF combustion process was presented through simulations for the adopted conditions of heat recovery. It was found that for each kilogram of RDF, about 3.85 kWh (13,860 kJ) of heat can be obtained. The combustion process was simulated using Aspen Plus software.
This research examines the challenges of everyday waste minimization of ‘zero waste’ practitioners in Chinese cities. Drawing on 45 in-depth interviews and virtual ethnography of a zero-waste community, this article details the processes during which different types of waste were ‘inevitably’ produced in everyday practices, such as those related to shopping and gifting, food provisioning and eating, binning and composting. Using theories of social practice, this article turns away from focusing on individual awareness, behavior, and choice, and instead seeks to explain how practices that people come to perform can be reproduced and reinforced despite individuals’ commitments to change. The findings illuminate how waste generation is subject to culturally and collectively constructed norms and rules, key social relations of love and care, and is embedded in the material arrangements that make up everyday life. The research sheds light on the importance of paying attention to both the more routinized and reflexive aspects of everyday life, and the power of diverse actors in affecting and shaping daily activities of consumption and waste.
Municipal refuse. Solid wastes, Standardization. Simplification. Waste
R. Tiburcio, M. M. Junior, Juliana Tofano. C. Leite
et al.
Abstract The recycling of materials found in municipal solid waste (MSW) is preferable to energy recovery; however, parts of the residues are rejected and sent to landfills. Rejects can be processed and used as refuse-derived fuel (RDF); nevertheless, an assessment of the fuel properties is relevant. This work evaluated the fuel potential of rejected MSW by manually sorting recyclable products, dominated by discarded recyclable solid waste (DRSW), aiming at recovery using it as RDF in thermochemical processes. The methodologies employed contemplated the physicochemical and thermophysical characterization of samples from five different fractions (non-chlorinated plastics, paper/cardboard, textiles, Tetra Pak® packaging, and wastes in natura) and processed RDF from DRSW. The results showed that these wastes present important energetic potential (lower heating value of 19.86 MJ/kg, 79.70% of volatile matter, and 8.87% of fixed carbon), with a low chlorine content in the bottom ash (11.43%). The samples tested in this work had moisture, ash, and combustible matter percentages within the limits established by the Tanner diagram. Therefore, the use of DRSW as RDF is an alternative to waste treatment, promotes energy recovery, and reinforces the goals of the United Nations 2030 Agenda for Sustainable Development due to the socioenvironmental and economic benefits of using rejected waste.
The recycling of source separated polyolefins (POs) (e.g., light weight packaging waste) is already state of the art. Therefore, further plastic materials contained in mixed wastes have become more important due to increasing legal pressure. Mixed commercial and municipal solid wastes contain large quantities of POs. These mixed wastes would usually be treated in waste incinerators or processed to refuse-derived fuel for cement plants. Large-scale experiments were conducted to assess the potential of such POs from these waste streams for recycling processes. The potential and applicability of a dry-mechanical and subsequently wet-mechanical (Wet-mechanical) processing with the aim of generating a PO concentrate for chemical recycling purposes was assessed. These investigations’ focus was put on the centrifugal force separator technology as the core element of Wet-mechanical processing. In addition to the input material, all output materials and process water streams were chemically and physically characterized to estimate potential treatment or recycling paths. Results demonstrate that a two-stage purification is necessary to produce POs with sufficient purity out of both wastes. Chlorine and heavy metal levels are simultaneously reduced. The increased quantity of impurities only slightly changes the density of the process waters. Process water analyses show that wastewater treatment is necessary before discharge into a receiving water or sewage treatment plant. The sediment does not fulfil any hazard-relevant properties, and different thermal treatment options are possible.
As a result of the activities carried out by people to maintain their daily lives in different places such as homes, hospitals, hotels or workplaces, waste consisting of furniture, paint, batteries, food waste, sachets, bottles, fabrics, and fibers with the heterogeneous structure is called municipal solid waste. Secondary fuels with higher heating value, which are generated by recycling of non-recyclable and reusable wastes in municipal solid wastes, are called as refuse derived fuel (RDF). In this study, RDF1 (taken in December, winter season) and RDF2 (taken in June, summer season) samples obtained from different dates were used. The ultimate, proximate, calorific value, X-ray fluorescence, thermogravimetric analysis, and differential scanning calorimetry analysis were performed for these samples. Combustion characterization from RDF samples was investigated in the applied analyzes. The results of the content analysis made were examined separately and compared with the thermogravimetric analysis and differential thermal analysis combustion graph curves. It was revealed that the RDF1 sample had a better combustion compared to the RDF2 sample, as the ash amount and content obtained as a result of the combustion also supported other data. In addition, the results of the analysis show how different the RDF samples taken from the same region in two different months are different from each other.