Hasil untuk "Chemical engineering"

D. Bokov, A. Turki Jalil, S. Chupradit et al.

The sol-gel process is a more chemical method (wet chemical method) for the synthesis of various nanostructures, especially metal oxide nanoparticles. In this method, the molecular precursor (usually metal alkoxide) is dissolved in water or alcohol and converted to gel by heating and stirring by hydrolysis/alcoholysis. Since the gel obtained from the hydrolysis/alcoholysis process is wet or damp, it should be dried using appropriate methods depending on the desired properties and application of the gel. For example, if it is an alcoholic solution, the drying process is done by burning alcohol. After the drying stage, the produced gels are powdered and then calcined. The sol-gel method is a cost-effective method and due to the low reaction temperature there is good control over the chemical composition of the products. The sol-gel method can be used in the process of making ceramics as a molding material and can be used as an intermediate between thin films of metal oxides in various applications. The materials obtained from the sol-gel method are used in various optical, electronic, energy, surface engineering, biosensors, and pharmaceutical and separation technologies (such as chromatography). The sol-gel method is a conventional and industrial method for the synthesis of nanoparticles with different chemical composition. The basis of the sol-gel method is the production of a homogeneous sol from the precursors and its conversion into a gel. The solvent in the gel is then removed from the gel structure and the remaining gel is dried. The properties of the dried gel depend significantly on the drying method. In other words, the “removing solvent method” is selected according to the application in which the gel will be used. Dried gels in various ways are used in industries such as surface coating, building insulation, and the production of special clothing. It is worth mentioning that, by grinding the gel by special mills, it is possible to achieve nanoparticles.

Coralie Jehanno, Jill W. Alty, Martijn Roosen et al.

Aya Samir, F. Ashour, A. A. Hakim et al.

The interest in producing biodegradable polymers by chemical treatment, microorganisms and enzymes has increased to make it easier to dispose after the end of its use without harming the environment. Biodegradable polymers reported a set of issues on their way to becoming effective materials. In this article, biodegradable polymers, treatment, composites, blending and modeling are studied. Environmental fate and assessment of biodegradable polymers are discussed in detail. The forensic engineering of biodegradable polymers and understanding of the relationships between their structure, properties, and behavior before, during, and after practical applications are investigated.

M. Boles, D. Ling, T. Hyeon et al.

Jinchen Sun, H. Tan

Alginate is a natural polysaccharide exhibiting excellent biocompatibility and biodegradability, having many different applications in the field of biomedicine. Alginate is readily processable for applicable three-dimensional scaffolding materials such as hydrogels, microspheres, microcapsules, sponges, foams and fibers. Alginate-based biomaterials can be utilized as drug delivery systems and cell carriers for tissue engineering. Alginate can be easily modified via chemical and physical reactions to obtain derivatives having various structures, properties, functions and applications. Tuning the structure and properties such as biodegradability, mechanical strength, gelation property and cell affinity can be achieved through combination with other biomaterials, immobilization of specific ligands such as peptide and sugar molecules, and physical or chemical crosslinking. This review focuses on recent advances in the use of alginate and its derivatives in the field of biomedical applications, including wound healing, cartilage repair, bone regeneration and drug delivery, which have potential in tissue regeneration applications.

Ying Zhou, Jun Feng Zhang, Juyoung Yoon

Mahmoud Elsabahy, K. Wooley

K. Sivula, Florian Le Formal, M. Grätzel

S. Walling, J. Provis

This review examines the detailed chemical insights that have been generated through 150 years of work worldwide on magnesium-based inorganic cements, with a focus on both scientific and patent literature. Magnesium carbonate, phosphate, silicate-hydrate, and oxysalt (both chloride and sulfate) cements are all assessed. Many such cements are ideally suited to specialist applications in precast construction, road repair, and other fields including nuclear waste immobilization. The majority of MgO-based cements are more costly to produce than Portland cement because of the relatively high cost of reactive sources of MgO and do not have a sufficiently high internal pH to passivate mild steel reinforcing bars. This precludes MgO-based cements from providing a large-scale replacement for Portland cement in the production of steel-reinforced concretes for civil engineering applications, despite the potential for CO2 emissions reductions offered by some such systems. Nonetheless, in uses that do not require steel reinforcement, and in locations where the MgO can be sourced at a competitive price, a detailed understanding of these systems enables their specification, design, and selection as advanced engineering materials with a strongly defined chemical basis.

T. Kean, M. Thanou

M. C. Stuart, W. Huck, J. Genzer et al.

S. Perrault, C. Walkey, T. Jennings et al.

U. Gaya, A. Abdullah

Meggie Hakim, Y. Broza, O. Barash et al.

A. Augst, H. Kong, D. Mooney

N. Sahinidis

S. Kitagawa, R. Kitaura, S. Noro

David A. Fletcher, R. Mcmeeking, D. Parkin

M. Gavrilescu, Y. Chisti

Xiaohui Yan, Shiqing Liu, Yongjian Su et al.

Free radicals are a class of reactive substances produced during the operation of proton exchange membrane fuel cells (PEMFCs), which have a great impact on the durability of PEMFCs. Previous research on the fuel cell degradation mechanism mainly focused on the degradation of the membrane electrode assembly (MEA) in high Pt loading PEMFCs, especially the chemical degradation of proton exchange membrane (PEM). However, there are significant differences in the characteristics and performance of PEMFCs with low and high Pt loading especially under the high current density, which is mainly due to the oxygen transport process in cathode catalyst layers (CCLs). Currently, few relevant research has explored the impact of chemical degradation on oxygen transport in the cathode of low-Pt PEMFCs. Therefore, this work investigates the effects of free radical attack on the structure of ionomer films, the local oxygen transport process and the evolution of the ionomer coated Pt/C structure in CCLs through physicochemical characterizations, electrochemical measurements and molecular dynamic simulations. Our research found that free radical attacks decreased the electrochemical active area of CCLs, but it also temporarily improved the cell performance at high current densities. Furthermore, molecular dynamics simulations demonstrated that the ionomer exhibited higher oxygen self-diffusion and a more relaxed structure after degradation.