One of the methods of municipal solid waste (MSW) treatment is biodrying. The literature describes mainly the results obtained in a laboratory- and a pilot-scale reactor. The manuscript presents the results of MSW treatment in a full-scale bio-drying reactor (150 m3). The reactor is operated in one of the Polish installations specializing in mechanical-biological treatment (MBT). During the 14 day period of biodrying in the reactor, the parameters of MSW such as the moisture, temperature, loss on ignition (LOI), and net heating value (NHV) were examined. The temperature of the air in the reactor was also examined. The research also included changes in the above-mentioned parameters of MSW located in three parts of the reactor: the front, middle, and back. The test results showed that the moisture content of the waste decreased from the initial level of 55% to the level of 30%. This was accompanied by an increase in the NHV from 6.3 MJ kg−1 to 9.6 MJ kg−1. At the same time, the LOI decreased from 68% d.m. to 45% d.m. The LOI decrease is not favorable from the point of view of using MSW as refuse-derived fuel (RDF), as was expected in the final usage stage. The results have application value as the plant operator, having at their disposal the controlling of the reactor’s ventilation and the temperature inside the reactor, should select the speed of the moisture removal from MSW at such a level as to minimize the LOI decrease.
The calorific value of household refuse (HR) is greatly improved after classification, which includes the implementation of sufficient pyrolysis conditions. Therefore, a better pyrolysis effect can be achieved by co-pyrolysis with industrial solid waste (ISW) with high calorific value. In this work, HR and ISW were used as raw materials for co-pyrolysis experiments. The influence on the distribution of three-phase products after co-pyrolysis, the concentration of heavy metals and dioxins in the flue gas, and the distribution of PCDD/Fs isomers were studied. The results showed that, at a temperature of 600 °C and H/C = 1.3, of the formed material, the quantity of pyrolysis gas was approximately 27 wt.%, and the quantity of pyrolysis oil was approximately 40.75 wt.%, which mainly contained alkanes, olefins, and aromatic hydrocarbons. When S/C = 0.008, pyrolysis gas accounted for 25.95 wt.% of the formed material, and pyrolysis oil for 41.95 wt.% of the formed material. The ignition loss rate of pyrolysis coke was approximately 20%, and the maximal calorific value was 14,217 KJ/kg. According to the thermogravimetric experiment, the co-pyrolysis of HR and ISW can promote the positive reaction of pyrolysis, and the weight loss reached 62% at 550 °C. The emission of gaseous heavy metals was relatively stable, and the concentration of heavy metals slightly decreased. The main heavy metals in the ash were Cu, Fe, and Zn. The emission of dioxins could be effectively reduced by the pyrolysis of HR with ISW, and the produced dioxins were mainly synthesized from de novo synthesis. After pyrolysis, the toxic equivalent of dioxins in the flue gas was reduced from 0.69 to 0.29 ng I-TEQ/Nm3, and the distribution of dioxin isomers in the flue gas had little influence. The experimental results provide a theoretical basis for the application of co-pyrolysis technology with HR and ISW.
Abstract One of the issues faced by several cities in Indonesia is the management of their increasing generation of solid wastes. One of the largest waste generators include the commercial area, such as malls, restaurants, office buildings, motels, and others, which need to manage their wastes via more sustainable routes such as the application of these wastes as refuse derived fuel to mitigate the climate change causing by fossil fuel. This study aims to analyse the potential use of wastes generated from commercial areas such as refuse-derived fuel (RDF) in the cement industry for reducing CO2 emissions. Five variants of RDFs were developed on the basis of commercial solid waste compositions. Results revealed that RDF variation 3 comprising 20% paper and 80% plastics exhibits the highest energy of 6272 kcal/kg. As preliminary study, cement industry Y is investigated as an example. During the simulation of the clinker production, RDF variation 3 is combined with petroleum coke, coal, fuel oil, or natural gas. Compared to other fuels, the combination of petroleum coke and RDF variation 3 exhibits the best CO2 reduction of 2, 155.3 106 Kt CO2/year, with the total annual clinker production of 12.64 million tons. These findings should aid policy and decision makers of waste management service provision and industry to design financially viable management systems based on resource recovery options.