Precision spectroscopy of a trapped $^{173}$Yb$^+$ ion using a bath of ultracold atoms
Egor Kovlakov, Rene Gerritsma
We demonstrate precision laser spectroscopy of a trapped $^{173}$Yb$^+$ ion that is not directly laser cooled by coupling it to ultracold atoms. The atomic bath continuously cools the internal degrees of freedom of the ion to its hyperfine ground state via spin-exchange collisions. Successful laser excitation is detected via state-selective charge transfer and subsequent ion loss. We probe the $6^2S_{1/2}\rightarrow 6^2P_{3/2}$ transition at 329 nm and measure the magnetic and electric hyperfine interaction constants for the $6^2P_{3/2}$ state to be $A=-241(1)$ MHz and $B=1460(8)$ MHz, respectively. Our results are in agreement with a previous measurement obtained in a hollow-cathode discharge experiment but are a factor of 6-9 more precise. The techniques demonstrated in this work may be extended to perform precision spectroscopy on other ions with complex level structures.
en
physics.atom-ph, quant-ph
Effects of changes of pH on the contractile function of cardiac muscle.
C. Orchard, J. Kentish
666 sitasi
en
Chemistry, Medicine
Series of molecular-like doubly excited states of a quasi-three-body Coulomb system
Matthieu Génévriez, Maxence Jungers, Christian Rosen
et al.
We investigated resonant multiphoton excitation of high-angular-momentum planetary states of the strontium atom, a quasi-three-body Coulomb system, both experimentally and theoretically. A series of highly doubly excited electronic states converging to the double ionization threshold was identified and reproduced by first-principles calculations, which provided access to the two-electron wavefunctions of the resonances. In these states, the outer electron is dynamically localized at large distances by pendulum-like oscillations of the inner electron across the nucleus. A complementary simple molecular-like adiabatic model offers a clear interpretation of the correlated two-electron motion and suggests that the series is a general feature of highly doubly excited states of atoms and molecules.
en
physics.atom-ph, quant-ph
Tracking chirality in photoelectron circular dichroism
Marec W. Heger, Daniel M. Reich
In photoelectron circular dichroism (PECD) it is generally difficult to trace how and when the chirality of the molecule is imprinted onto the photoelectron. We present simulations of PECD in a simple model and employ chirality measures to establish a quantitative connection between the chirality of the potential, the electronic wave function's chirality, and the anisotropy of the photoelectron distribution. We show that these measures are suitable indicators for chirality, paving the way for tracking the chiral evolution from the nuclear scaffold to the final observable.
en
physics.atom-ph, quant-ph
Self-energy correction to energy levels of highly charged ions in a path integral formalism
Sreya Banerjee, Zoltán Harman
Self-energy corrections to the energy levels of bound electrons are calculated in the framework of path integrals. We arrive at the full fermion propagator, using methods of functional integrals, in the form of Schwinger-Dyson equation (SDE). From the full fermion SDE, the self-energy corrected propagator is identified and the energy shift is obtained from the poles of the spectral function. The numerical calculations are performed using complex contour integrals and the B-spline representation of basis functions. We identify ions with Lamb shifts observable via modern mass spectrometric methods.
en
physics.atom-ph, quant-ph
Probability distributions of atomic scattering lengths
John L. Bohn, Reuben R. W. Wang
The probability distribution of the real and imaginary parts of atomic scattering lengths $a$ are derived, in a two-channel model that allows for inelastic scattering to occur. While the real part of $a$ remains Cauchy-distributed, as predicted for single channel scattering in the classic work of Gribakin and Flambaum, the imaginary part of $a$ is seen to be strongly peaked near zero. Two-body inelastic scattering rates may therefore be smaller in general than a naive estimate would suggest.
en
physics.atom-ph, quant-ph
$\mathcal{O}\left(mα^2 (Zα)^6\right)$ contribution to Lamb shift from radiative corrections to the Wichmann-Kroll potential
Petr A. Krachkov, Roman N. Lee
We derive an analytical expression for the contribution of the order $mα^2 (Zα)^6$ to the hydrogen Lamb shift which comes from the diagrams for radiative corrections to the Wichmann-Kroll potential. We use modern methods of multiloop calculations, based on IBP reduction, DRA method and differential equations.
en
hep-ph, physics.atom-ph
Negative pH, efflorescent mineralogy, and consequences for environmental restoration at the Iron Mountain Superfund site, California.
D. Nordstrom, C. Alpers
497 sitasi
en
Chemistry, Medicine
Polymeric anticancer drugs with pH-controlled activation.
K. Ulbrich, V. Šubr
490 sitasi
en
Chemistry, Medicine
pH-responsive supramolecular nanovalves based on cucurbit[6]uril pseudorotaxanes.
S. Angelos, Yingwei Yang, K. Patel
et al.
420 sitasi
en
Medicine, Chemistry
Effect of pH and impurities on the surface charge of zinc oxide in aqueous solution
A. Degen, M. Kosec
Iron metabolism in anoxic environments at near neutral pH.
K. Straub, M. Benz, B. Schink
473 sitasi
en
Medicine, Biology
A ratiometric CdSe/ZnS nanocrystal pH sensor.
P. Snee, R. C. Somers, Gautham P Nair
et al.
460 sitasi
en
Chemistry, Medicine
Biomimetic pH Sensitive Polymersomes for Efficient DNA Encapsulation and Delivery
Hannah Lomas, I. Cantón, S. MacNeil
et al.
421 sitasi
en
Materials Science
Measurement of pH. Definition, standards, and procedures (IUPAC Recommendations 2002)
R. Buck, S. Rondinini, A. Covington
et al.
pH as a trigger of peptide beta-sheet self-assembly and reversible switching between nematic and isotropic phases.
A. Aggeli, M. Bell, L. Carrick
et al.
431 sitasi
en
Chemistry, Medicine
pH-operated nanopistons on the surfaces of mesoporous silica nanoparticles.
Yan-Li Zhao, Zongxi Li, Sanaz Kabehie
et al.
283 sitasi
en
Chemistry, Medicine
Association of urinary pH with body weight in nephrolithiasis.
N. Maalouf, K. Sakhaee, J. Parks
et al.
Effects of temperature, solid content and pH on the stability of black carrot anthocyanins
Ayşegül Kırca, M. Özkan, B. Cemeroǧlu
Sperm motility in fishes. I. Effects of temperature and pH: a review
S. M. Alavi, J. Cosson
396 sitasi
en
Biology, Medicine