The calorific value of household refuse (HR) is greatly improved after classification, which includes the implementation of sufficient pyrolysis conditions. Therefore, a better pyrolysis effect can be achieved by co-pyrolysis with industrial solid waste (ISW) with high calorific value. In this work, HR and ISW were used as raw materials for co-pyrolysis experiments. The influence on the distribution of three-phase products after co-pyrolysis, the concentration of heavy metals and dioxins in the flue gas, and the distribution of PCDD/Fs isomers were studied. The results showed that, at a temperature of 600 °C and H/C = 1.3, of the formed material, the quantity of pyrolysis gas was approximately 27 wt.%, and the quantity of pyrolysis oil was approximately 40.75 wt.%, which mainly contained alkanes, olefins, and aromatic hydrocarbons. When S/C = 0.008, pyrolysis gas accounted for 25.95 wt.% of the formed material, and pyrolysis oil for 41.95 wt.% of the formed material. The ignition loss rate of pyrolysis coke was approximately 20%, and the maximal calorific value was 14,217 KJ/kg. According to the thermogravimetric experiment, the co-pyrolysis of HR and ISW can promote the positive reaction of pyrolysis, and the weight loss reached 62% at 550 °C. The emission of gaseous heavy metals was relatively stable, and the concentration of heavy metals slightly decreased. The main heavy metals in the ash were Cu, Fe, and Zn. The emission of dioxins could be effectively reduced by the pyrolysis of HR with ISW, and the produced dioxins were mainly synthesized from de novo synthesis. After pyrolysis, the toxic equivalent of dioxins in the flue gas was reduced from 0.69 to 0.29 ng I-TEQ/Nm3, and the distribution of dioxin isomers in the flue gas had little influence. The experimental results provide a theoretical basis for the application of co-pyrolysis technology with HR and ISW.
Abstract One of the issues faced by several cities in Indonesia is the management of their increasing generation of solid wastes. One of the largest waste generators include the commercial area, such as malls, restaurants, office buildings, motels, and others, which need to manage their wastes via more sustainable routes such as the application of these wastes as refuse derived fuel to mitigate the climate change causing by fossil fuel. This study aims to analyse the potential use of wastes generated from commercial areas such as refuse-derived fuel (RDF) in the cement industry for reducing CO2 emissions. Five variants of RDFs were developed on the basis of commercial solid waste compositions. Results revealed that RDF variation 3 comprising 20% paper and 80% plastics exhibits the highest energy of 6272 kcal/kg. As preliminary study, cement industry Y is investigated as an example. During the simulation of the clinker production, RDF variation 3 is combined with petroleum coke, coal, fuel oil, or natural gas. Compared to other fuels, the combination of petroleum coke and RDF variation 3 exhibits the best CO2 reduction of 2, 155.3 106 Kt CO2/year, with the total annual clinker production of 12.64 million tons. These findings should aid policy and decision makers of waste management service provision and industry to design financially viable management systems based on resource recovery options.
We have been advancing the concept of carbonized refuse-derived fuel (CRDF) by refuse-derived fuel (RDF) torrefaction as improved recycling to synergistically address the world’s energy demand. The RDF is a combustible fraction of municipal solid waste (MSW). Many municipalities recover RDF for co-firing with conventional fuels. Torrefaction can further enhance fuel properties and valorize RDF. Energy demand for torrefaction is one of the key unknowns needed for scaling up CRDF production. To address this need, a pioneering model for optimizing site-specific energy demand for torrefaction of mixed RDF materials was developed. First, thermogravimetric and differential scanning calorimetry analyses were used to establish thermal properties for eight common RDF materials. Then, the model using the %RDF mix, empirical thermal properties, and torrefaction temperature was developed. The model results for individual RDF components fitted well (R2 ≥ 0.98) with experimental torrefaction data. Finally, the model was used to find an optimized RDF site-specific mixture with the lowest energy demand. The developed model could be a basis for estimating a net energy potential from the torrefaction of mixed RDF. Improved models could be useful to make plant-specific decisions to optimize RDF production based on the energy demand that depends on highly variable types of MSW and RDF streams.
The torrefaction of municipal solid waste is one of the solutions related to the Waste to Carbon concept, where high-quality fuel—carbonized refuse-derived fuel (CRDF)—is produced. An identified potential problem is the emission of volatile organic compounds (VOCs) during CRDF storage. Kinetic emission parameters have not yet been determined. It was also shown that CRDF can be pelletized for energy densification and reduced volume during storage and transportation. Thus, our working hypothesis was that structural modification (via pelletization) might mitigate VOC emissions and influence emission kinetics during CRDF storage. Two scenarios of CRDF structural modification on VOC emission kinetics were tested, (i) pelletization and (ii) pelletization with 10% binder addition and compared to ground (loose) CRDF (control). VOC emissions from simulated sealed CRDF storage were measured with headspace solid-phase microextraction and gas chromatography–mass spectrometry. It was found that total VOC emissions from stored CRDF follow the first-order kinetic model for both ground and pelletized material, while individual VOC emissions may deviate from this model. Pelletization significantly decreased (63%~86%) the maximum total VOC emission potential from stored CDRF. Research on improved sustainable CRDF storage is warranted. This could involve VOC emission mechanisms and environmental-risk management.