Jun Sakuma, Hisashi Asanuma, Naoto Takahata
et al.
Precise and accurate ages for asteroidal crusts are fundamental for reconstructing the timeline of magmatic, metamorphic, and impact events in the early Solar System. Zirconolite (CaZrTi2O7) is an accessory mineral found in a wide range of crustal rocks on both the Earth and Moon, and has proven to be a potentially useful U Pb chronometer. However, this mineral is rare in asteroidal meteorites, and its use for early Solar System chronology has been limited. We present the in situ occurrence, U Pb chronology, and chemistry of zirconolite in the andesitic meteorite Erg Chech 002, which represents a sample of the oldest known asteroidal crust. The zirconolite occurs as needle- and fiber-shaped, stubby crystals, with widths of 3 micrometers and lengths of up to 30 micrometers. Electron and ion microprobe analyses yielded concordant U Pb data with a weighted mean 207Pb 206Pb age of 4557.9 4.3 Ma 2sigma, rendering it the Solar System's oldest known zirconolite. Yet, this age is distinctly younger than reported high-precision 207Pb 206Pb ages varying from 4565.6 to 4566.2 Ma, which were obtained by acid leaching of pyroxene and whole rock samples of the meteorite. From its mineralogical and REE (U+Th) (Nb+Ta) characteristics, we argue that the zirconolite age represents the timing of a shock metamorphism of the parent asteroid's crust. Our results suggest that 207Pb 206Pb dating for acid-leached samples can be affected by including even a tiny amount of metamorphic zirconolite, calling for caution in interpreting the high-precision 207Pb 206Pb age data. On the basis of thermodynamic and geochemical considerations, we infer further occurrences of zirconolite in alkali-silica-rich asteroidal rocks that rapidly cooled from high temperatures.
Nanophase iron (npFe) plays a crucial role in controlling the optical, chemical, and physical evolution of lunar regolith grains. While in-situ formation of npFe via reduction of native Fe-bearing minerals has long been considered a dominant pathway, recent mineralogical evidence from X.Zeng et al. (2025) reveals that the source of a significant fraction of npFe may be delivered directly by exotic micrometeoroid impacts (exotic npFe). Yet the atomic-scale processes governing how exotic np-Fe forms and survives during hypervelocity impacts remain largely unknown. To quantitatively compare in-situ and exotic delivery and formation of npFe, we perform a series of innovative atomistic modeling of micrometeoroid impacts with distinct projectile target compositions: (1) SiO$_2$ projectiles on Fe$_2$SiO$_4$ targets (in-situ formation), (2) Fe$_2$SiO$_4$ projectiles on SiO$_2$ targets (exotic delivery). Our results reveal distinct mechanistic fingerprints: in-situ np-Fe forms diffusely and radially around the impact site, whereas exotic np-Fe is efficiently retained and concentrated in asymmetric, momentum-aligned clusters. These contrasting spatial signatures provide a potential diagnostic criterion for distinguishing exotic versus in-situ np-Fe in returned lunar soils. In agreement with Chang'e-5 observations, our simulations demonstrate that exotic np-Fe production can be substantial, particularly in Fe-poor terrains such as highland regions. These findings highlight the need to account for exotic np-Fe when interpreting space weathering processes and remote-sensing data for the Moon and other airless bodies.
Md. Shazzadur Rahman, Sharmin Sultana, Pradip Kumar Biswas
et al.
Introduction: This study assesses groundwater suitability for drinking and irrigation in central-west Bangladesh’s granary region. Using the entropy water quality index (EWQI) and conventional irrigation indices, it evaluates water quality essential for public health and sustainable agriculture. Materials and methods: Groundwater samples from multiple sites were analyzed for major physicochemical parameters. Drinking suitability was assessed using EWQI, while irrigation suitability was evaluated through USSL, Wilcox, and Doneen indices. Hydrochemical facies and geochemical processes were interpreted using Piper, Gibbs, and bivariate analyses. Results and discussion: Groundwater in the study area is neutral to alkaline in nature and is dominated by calcium (Ca2+) and bicarbonate (HCO3-), characterizing a Ca-Mg-HCO3 water type. This composition reflects calcite dissolution and ion-exchange processes. Gibbs plots and bivariate relationships indicate that rock weathering, particularly of calcite, dolomite, and silicate minerals, largely governs the groundwater chemistry. The EWQI and WQI results reveal that 96.67 % of the samples are unsuitable for drinking, with 76.67 % classified as poor quality. PCA results indicate that the dissolved constituents are primarily of geogenic origin, with minor anthropogenic influence. For irrigation purposes, the USSL diagram suggests low to medium alkali hazards, Wilcox ratings range from permissible to excellent, and Doneen’s classification places the samples in Class I, indicating high permeability. Conclusion: Groundwater is generally unsuitable for drinking but remains acceptable for irrigation. Regular monitoring and effective management are essential to prevent further degradation and ensure long-term water sustainability.
Jun Takeshita, Yuichiro Cho, Haruhisa Tabata
et al.
Saturn's ice-covered moon Enceladus may host a subsurface ocean with biologically relevant chemistry. Plumes released from this ocean preserve information on its chemical state, and previous analyses suggest weakly to strongly alkaline pH (approximately pH 8--12). Constraining the pH requires identification of pH-sensitive minerals in plume deposits. Several analytical techniques could provide such mineralogical information, but few are practical for deployment on planetary missions. Raman spectrometers, which have recently advanced for \textit{in situ} exploration and have been incorporated into flight instruments, offer a feasible approach for mineral identification on icy moons. However, their applicability to pH estimation from plume-derived minerals has not been investigated. In this study, we evaluate whether Raman measurements of plume particles deposited on the surface of Enceladus can be used to distinguish between weakly and strongly alkaline subsurface ocean models. Fluids with pH values of 9 and 11 were frozen under vacuum conditions analogous to those on Enceladus. The resulting salt deposits were then analyzed using a flight-like Raman spectrometer. The Raman spectra show pH-dependent carbonate precipitation: NaHCO$_3$ and Na$_2$CO$_3$ peaks were detected at pH 9, whereas only Na$_2$CO$_3$ peaks were detected at pH 11. These findings demonstrate that Raman spectroscopy can distinguish pH-dependent carbonate phases. This capability allows us to constrain whether the pH of the subsurface ocean is weakly alkaline or strongly alkaline, which is a key parameter for assessing its chemical evolution and potential habitability.
Abdessamad Mazzourh, Houria Dakak, Morad Taher
et al.
The mechanisms underlying groundwater salinization are diverse and complex, influenced by natural and anthropogenic factors. The natural salinization of water primarily depends on the geographical context (coastal, continental, etc.), geological characteristics (aquifer type, sediment mineralogy, etc.), and climatic conditions. On the other hand, anthropogenic salinization results from human activities and practices on the surface areas overlying vulnerable aquifers. In this study, we investigate the origins of salinization in the groundwater of the coastal Ghiss-Nekkour aquifer, which serves as the primary source of drinking water for Al Hoceima city and its surrounding areas. A comparative approach was employed, integrating geological (lithological and structural), hydrochemical, and statistical criteria to identify and analyze salinization mechanisms. The findings indicate that the salinity of the Ghiss-Nekkour aquifer is spatially variable. Most of the aquifer exhibits salinity values ranging from 1 to 3.2 PSU, with localized extreme values exceeding 3.2 PSU. These higher salinity levels are observed primarily in the eastern part near the Trougout fault and in the southwestern region of the aquifer. Such variations suggest the influence of both natural geological features and anthropogenic activities on the salinity distribution. To address this issue, it is essential to implement targeted solutions, including regular monitoring of groundwater quality, and controlling anthropogenic pollution sources. By addressing these challenges, the Ghiss-Nekkour aquifer can continue to serve as a reliable drinking water source for the region.
N.I. Ponomareva, L.P. Nikitina, V.N. Bocharov
et al.
This paper is dedicated to results of microscopic study of minerals from xenoliths of mantle spinel lherzolites in Cenozoic basaltoids of Zhokhov Island (New Siberian Islands, Russia) using microanalysis and Raman spectroscopy, as well as the assessment of formation conditions (T, P, fO2) of the olivine-spinel mineral assemblage. Olivine is one of the major minerals of spinel lherzolites of the Zhokhov Island. It contains numerous syngenetic and later mineral and fuid inclusions. The solid-phase inclusions include enstatite, diopside, spinel, apatite, sulfdes, and solid hydrocarbons identifed by Raman spectroscopy as kerogen and bitumen. Based on results of Raman spectroscopy, fuid inclusions contain CO2 and, locally, a mixture of CO2 (97.5 %) and CO (2.5 %). According to various geothermometers, the average temperature of co-existence of the olivine-spinel assemblage is 1010 K (737 °C) at a pressure of 1 GPa. Oxygen fugacity (lgfO2) for lherzolites of the Zhokhov Island ranges from –13.9 to –14.6.
Context.Spatially-resoved cicrumstellar disk spectrum and composition can provide valuable insights into the bulk composition of forming planets, as well as the mineralogical signatures that emerge during and after planet formation. Aims. We aim to systemically extract the RX~J1604.3-213010 (J1604 hereafter) protoplanetary disk in high-contrast imaging observations, and obtain its multi-band reflectance in visible to near-infrared wavelengths. Methods. We obtained coronagraphic observations of J1604 from the Keck Observatory's NIRC2 instrument, and archival data from the Very Large Telescope's SPHERE instrument. Using archival images to remove star light and speckles, we recovered the J1604 disk and obtained its surface brightness using forward modeling. Together with polarization data, we obtained the relative reflectance of the disk in $R$, $J$, $H$ ($H2$ and $H3$), $K$ ($K1$ and $K2$), and $L'$ bands spanning two years. Results. Relative to the J1604 star, the resolved disk has a reflectance of ${\sim}10^{-1}$~arcsec$^{-2}$ in $R$ through $H$ bands and ${\sim}10^{-2}$~arcsec$^{-2}$ in $K$ and $L'$ bands, showing a blue color. Together with other systems, we summarized the multi-band reflectance for 9 systems. We also identified varying disk geometry structure, and a shadow that vanished between June and August in 2015. Conclusions. Motivated by broad-band observations, the deployment of cutting-edge technologies could yield higher-resolution reflection spectra, thereby informing the dust composition of disks in scattered light in the future. With multi-epoch observations, variable shadows have the potential to deepen insights into the dynamic characteristics of inner disk regions.
Sanjeet S. Kaintura, Swati Thakur, Sarabjot Kaur
et al.
In this work, radioactivity investigations of soil samples from neutral and agricultural sites in Punjab/India have been carried out to study the impact of land use patterns. The analysis of radiological, mineralogical, physicochemical, and morphological attributes of soil samples has been performed employing state-of-the-art techniques. The mean activity concentration of 238U, 232Th, 40K, 235U, and 137Cs, measured using a carbon-loaded p-type HPGe detector, in neutral land was observed as 58.03, 83.95, 445.18, 2.83, and 1.16Bq kg-1, respectively. However, in vegetation land, it was found to be 40.07, 64.68, 596.74, 2.26 and 2.11Bq kg-1, respectively. In the detailed activity analysis, radium equivalent (Raeq) radioactivity is found to be in the safe prescribed limit of 370Bq kg-1 for all investigated soil samples. However, the dosimetric investigations revealed that the outdoor absorbed gamma dose rate (96.08nGy h-1) and consequent annual effective dose rate (0.12mSv y-1) for neutral land, and the gamma dose rate (82.46nGy h-1) and subsequent annual effective dose rate (0.10mSv y-1) for vegetation land marginally exceeded the global average. The surface morphology of neutral land favored more compactness, while agricultural land favored high porosity. Various heavy metals of health concern, namely As, Cd, Co, Cr, Cu, Hg, Pb, Se, and Zn, were also evaluated in all soil samples using Inductively Coupled Plasma-Mass Spectroscopy (ICP-MS). Pollution Load Index (PLI) and Ecological Risk Index (RI) revealed that vegetation land was more anthropogenically contaminated than neutral land, with maximum contamination from Hg and As.
Accretion processes in protoplanetary disks produce a diversity of small bodies that played a crucial role in multiple reshuffling events throughout the solar system and in both early and late accretion of planets. Application of thermo-chronometers to meteorites provides precise dating of the formation age of mineralogical components. Nucleosynthetic anomalies indicating a dichotomy between NC and C meteorites and precise parent body (PB) chronology can be combined with thermal evolution models to constrain the timescale of accretion and dynamical processes in the early solar system. Achondrite PBs are considered to have accreted early and mostly in the NC region, while late accretion in the C region produced mostly undifferentiated PBs, such as the CR chondrite PB that formed as late as 4 Ma after CAIs. However, presence of more evolved CR-related meteorites suggests also an earlier accretion timing. We present modeling evidence for a temporally distributed accretion of parent bodies of CR-related meteorite groups that originate from a C reservoir and range from aqueously altered chondrites to partially differentiated primitive achondrites. The PB formation times derived range from <1 Ma to ~4 Ma after solar system formation, with ~3.7 Ma, ~1.5-2.75 Ma, <~0.6 Ma, and <~0.7 Ma for CR, Flensburg, NWA 6704, and NWA 011. This implies that accretion processes in the C reservoir started as early as in the NC reservoir and produced differentiated PBs with carbonaceous compositions in addition to undifferentiated C chondritic PBs. The accretion times correlate inversely with the degree of the meteorites' alteration, metamorphism, or differentiation. Accretion times for CI/CM, Ryugu, and Tafassites PBs of ~3.75 Ma, ~1-3 Ma, and 1.1 Ma, respectively, fit well into this correlation in agreement with the thermal and alteration conditions suggested by the meteorites.
The research aims to study Sabkha mineralogy to determine the mineral types, the nature of the precipitation, and the patterns of salt crystallization. Two Sabkhas in Abu Ghraib, west of Baghdad, were studied. It was found that the Sabkhas were formed in flat ponds from saturated solutions in a semi-arid to arid climate. Halite predominates, followed by anhydrite and gypsum as evaporite minerals. As for the minerals of the Sabkha soil, it consisted of feldspar, calcite, quartz, and dolomite, in addition to the clay minerals represented by kaolinite, illite, and chlorite. Needle forms, hopper shapes, dendritic crystals, and polygon shapes are the main crystallization patterns dominantly found in the Sabkhas. All these types of crystallization occurre under normal temperatures.
<p>Geomorphic and sedimentologic data indicate that the climate of today's hyper-arid Atacama Desert (northern Chile) was more humid during the mid-Pliocene to Late Pliocene. The processes, however, leading to increased rainfall in this period are largely unknown. To uncover these processes we use both global and regional kilometre-scale model experiments for the mid-Pliocene (3.2 Ma). We found that the PMIP4–CMIP6 (Paleoclimate Modelling Intercomparison Project–Coupled Model Intercomparison Project) model CESM2 (Community Earth System Model 2) and the regional model WRF (Weather Research and Forecasting) used in our study simulate more rainfall in the Atacama Desert for the mid-Pliocene in accordance with proxy data, mainly due to stronger extreme rainfall events in winter. Case studies reveal that these extreme winter rainfall events during the mid-Pliocene are associated with strong moisture conveyor belts (MCBs) originating in the tropical eastern Pacific. For present-day conditions, in contrast, our simulations suggest that the moisture fluxes rather arise from the subtropical Pacific region and are much weaker. A clustering approach reveals systematic differences between the moisture fluxes in the
present-day and mid-Pliocene climates, both in strength and origins. The two mid-Pliocene clusters representing tropical MCBs and occurring less than 1 d annually on average produce more rainfall in the hyper-arid core of the Atacama Desert south of 20<span class="inline-formula"><sup>∘</sup></span> S than what is simulated for the entire present-day period. We thus conclude that MCBs are mainly responsible for enhanced rainfall during the mid-Pliocene. There is also a strong sea-surface temperature (SST) increase in the tropical eastern Pacific and along the Atacama coast for the mid-Pliocene. It suggests that a warmer ocean in combination with stronger mid-tropospheric troughs is beneficial for the development of MCBs leading to more extreme rainfall in a <span class="inline-formula">+</span>3 <span class="inline-formula"><sup>∘</sup></span>C warmer world like in the mid-Pliocene.</p>
Bayan Obo, located in the north margin of the Yinshan Block, North China Craton (NCC), contains the Archean to Paleoproterozoic basement rocks which may shed light on the early crustal evolution of the NCC. In this paper, to reveal the formation and modification of the basements, we report Hf isotope of zircons from the biotite plagiogneisses in Bayan Obo. Combined with the published U–Pb ages and Hf isotope compositions of the zircons from the Bayan Obo basement rocks, a comprehensive review was employed to provide new insights into the formation and modification of the basement in this area. The oldest formation age of the basement rocks was found to be approximately 2.6 Ga, with positive εHf(t) values indicating the contribution from the depleted mantle to the rocks. The age of ∼2.0 Ga marks the major formation period of the basement rocks. The varied εHf(t) values (−17.2 to +8.9) of the magmatic zircons suggest a mixture origin between the depleted mantle and crustal rocks for the gneiss. The basement went through extensive metamorphism during 1.95–1.9 Ga. In addition, zircon U–Pb–Hf isotope data of the Precambrian units in Guyang and Wuchuan, which are adjacent to Bayan Obo, were compiled for comparison. The comprehensive review on the data of the concordant magmatic zircons indicates the existence of 3.5 Ga crustal fragments in the Yinshan Block. The melting of the depleted mantle and the addition of juvenile materials into the crust at 2.6–2.9 Ga and 2.45–2.55 Ga were confirmed by the high positive εHf(t) values of the magmatic and inherited zircons. An increase in remelting of the crust at 2.0 Ga is deduced from the extremely unradiogenic Hf isotope of the magmatic zircons.
Understanding the structure and mineralogical composition of a region is an essential step in mining, both during exploration (before mining) and in the mining process. During exploration, sparse but high-quality data are gathered to assess the overall orebody. During the mining process, boundary positions and material properties are refined as the mine progresses. This refinement is facilitated through drilling, material logging, and chemical assaying. Material type logging suffers from a high degree of variability due to factors such as the diversity in mineralization and geology, the subjective nature of human measurement even by experts, and human error in manually recording results. While laboratory-based chemical assaying is much more precise, it is time-consuming and costly and does not always capture or correlate boundary positions between all material types. This leads to significant challenges and financial implications for the industry, as the accuracy of production blasthole logging and assaying processes is essential for resource evaluation, planning, and execution of mine plans. To overcome these challenges, this work reports on a pilot study to automate the process of material logging and chemical assaying. A machine learning approach has been trained on features extracted from measurement-while-drilling (MWD) data, logged from autonomous drilling systems (ADS). MWD data facilitate the construction of profiles of physical drilling parameters as a function of hole depth. A hypothesis is formed to link these drilling parameters to the underlying mineral composition. The results of the pilot study discussed in this paper demonstrate the feasibility of this process, with correlation coefficients of up to 0.92 for chemical assays and 93% accuracy for material detection, depending on the material or assay type and their generalization across the different spatial regions.
One of the main complications for the interpretation of reflectance spectra of airless planetary bodies is surface alteration by space weathering caused by irradiation by solar wind and micrometeoroid particles. We aim to evaluate the damage to the samples from H and laser irradiation and relate it to the observed alteration in the spectra. We used olivine (OL) and pyroxene (OPX) pellets irradiated by 5 keV H ions and individual fs laser pulses and measured their visible (VIS) and near-infrared (NIR) spectra. We observed the pellets with scanning and transmission electron microscopy. We studied structural, mineralogical, and chemical modifications in the samples and connected them to changes in the reflectance spectra. In both minerals, H irradiation induces partially amorphous sub-surface layers containing small vesicles. In OL pellets, these vesicles are more tightly packed than in OPX ones. Related spectral change is mainly in the VIS spectral slope. Changes due to laser irradiation are mostly dependent on material's melting temperature. Only the laser-irradiated OL contains nanophase Fe particles, which induce detectable spectral slope change throughout the measured spectral range. Our results suggest that spectral changes at VIS-NIR wavelengths are mainly dependent on thickness of (partially) amorphous sub-surface layers. Amorphisation smooths microroughness, increasing the contribution of volume scattering and absorption over surface scattering. Soon after exposure to the space environment, the appearance of partially amorphous sub-surface layers results in rapid changes in the VIS spectral slope. In later stages (onset of micrometeoroid bombardment), we expect an emergence of nanoparticles to also mildly affect the NIR spectral slope. An increase in dimensions of amorphous layers and vesicles in the more space-weathered material will only cause band-depth variation and darkening.
This study aims to contribute to improve the knowledge on the setting of the Irbiben granites, located south of the gold deposit of this locality (Tagragra d'Akka buttonhole, Anti-Atlas, Morocco). The petrographic characterization showed leucocratic porphyry rocks, with a mineralogy dominated by quartz and phenocrysts of plagioclase, alkali feldspars of sometimes centimetric size as well as very small sulphides of metallic luster. Two generations of quartz have been identified: a QIquartz with undulating extinction phenocrysts testifying to an episode of deformation orchestrated in this inlier, and a QII quartz with more rounded and limpid minerals indicating an intense silicification. Plagioclase and alkali feldspars are deeply altered to sericite and epidote. Geochemical characterization classifies these rocks as calc-alkaline series granites, rich in potassium, with a peraluminous character indicating their crustal origin. Their arc geochemical signature, Ba enrichment, and negative Nb, Ti, and P anomalies are characteristic of a subduction zone. This subduction could be associated with an episode of convergence between an oceanic lithosphere located in the north and the West African craton in the south, as shown by the proposed geodynamic model.
Lucie Riu, François Poulet, Jean-Pierre Bibring
et al.
A radiative transfer model was used to reproduce several millions of OMEGA (Observatoire pour la Minéralogie, l'Eau, les Glaces et l'Activité) spectra representative of igneous terrains of Mars. This task provided the modal composition and grain sizes at a planetary scale. The lithology can be summarized in five mineral maps at km-scale. We found that the low albedo equatorial regions of the Martian surface (from 60°S to 30°N) are globally dominated by plagioclase with average abundance ~50 vol% and pyroxenes with total averaged abundance close to 40 vol%. An evolution of the LCP/(LCP+HCP) ratio is observed with time at the global scale, suggesting an evolution of the degree of partial melting throughout the Martian eras. Olivine and Martian dust are minor components of the modelled terrains. The olivine distribution is quite different from the other minerals because it is found on localized areas with abundance reaching 20 vol%. A statistical approach, to classify the pixels of the abundances maps, using k-means clustering, highlighted seven distinct mineral assemblages on the surface. This classification illustrates that diverse mineralogical units are found in the Noachian and Hesperian terrains, which suggests the presence of various and complex magmatic processes at a global scale during the two oldest eras. The chemical composition was derived from the modal composition maps. The OMEGA-derived chemical composition is quite consistent with several distinctive geochemical characteristics previously considered as fingerprints of the Martian surface. A major discrepancy is in regards to the Fe content that is significantly smaller than soil and rock analyses from GRS and in situ measurements. The discrepancy could be partly explained by the assumptions used for the spectral modelling or could also indicate surface alteration rinds.
The Neoproterozoic Binggounan Formation mud shale in the Hongliugou Ⅰ section on the northwestern margin of the Altyn Tagh fault was deposited in a passive continental margin. They are shelf sediments about 60 m thick, interbedded with siliceous rocks, undergone a low temperature thermodynamic metamorphism, and had hydrocarbon generation potential. The tectonic background, provenance, weathering and sedimentary environment of the mud shale were discussed with regard to stratigraphic sections, mineralogy and geochemical analyses. The mud shale was mainly composed of silica-rich clay rock and mud-rich siliceous shale, followed by mud-silica mixed shale. They have simila-rities in Si, Mg, K, P, Sc, Y, Hf, Th Sc contents compared with the Post Archaean Australian shale (PAAS). The Ti, Mn, Fe, Ta contents and δEun, δCen, ΣREE values are higher, while the Al, Ca, Na, Nb and Zr contents are lower. The primitive sediment sources of the Binggounan mud shale were recycled sedimentary clasts, intermediate mafic and acid intrusive rocks, similar to a normal shale and arenites argillites and ensialic of continental upper crust in composition. The shale has undergone moderate chemical weathering in warm and humid conditions. The formation was divided into three sedimentary cycles from bottom to top, mainly anaerobic and anoxic, and occasionally oxidized. Hydrothermal alteration also occured in the lower section. The mud shale with a clay content of about 40% is rich in trace elements (REE) and organic matter, which was deposited in a suboxic to anoxic section on the shelf, showing a high productivity and hydrocarbon-generation potential.
در تحلیل و طراحی سازههای سنگی، تعیین پارامترهای ژئومکانیکی اهمیت فراوانی دارد. در تعیین این پارامترها، خصوصیات ناپیوستگی نقش مهمی را ایفا میکنند، اما عدم قطعیت موجود در ناپیوستگیها و ناهمگنی ذاتی تودهسنگ، اطمینان به پارامترهای تعیین شده را کاهش میدهد. در چنین شرایطی در نظر گرفتن دامنهای از پارامترها ممکن است اطمینان به نتایج را افزایش دهد. در این مقاله روشی کاربردی با استفاده از منطق فازی و شبیهسازی مونتکارلو برای در نظر گرفتن عدم قطعیت در تودهسنگ ارایه شده است. تابع عملگر استفاده شده در مطالعه، معیار هوک و براون است. برای انجام مطالعه موردی از دادههای معتبر موجود در مطالعات گذشته استفاده شده است. ابتدا با در نظر گرفتن عدم قطعیت در پارامترهای ورودی شامل شاخص مقاومت زمینشناسی، مقاومت فشاری سنگ بکر و فاکتور، مجموعه اعداد فازی برای ثوابت تودهسنگتعیین و سپس با استفاده از نتایج به دست آمده، پارامترهای ژئومکانیکی تودهسنگ به صورت مجموعه اعداد فازی محاسبه شده است. در نهایت با استفاده از شبیهسازی مونتکارلو، دادههای تصادفی، تولید شده و فاصله اطمینان برای هر پارامتر با سطح اطمینان %95 به دست آمده است. نتایج نشان میدهد، در مسایلی که پارامترهای آنها عدم قطعیت دارند، روش پیشنهادی قابلیت بالایی داشته و ممکن است ریسک حاصل از عدم قطعیت را کاهش دهد.
Celitement is a new type of cement that is based on hydraulic calcium-hydrosilicate (hCHS) that possesses a potential for minimizing the ratio C/S from above 3 in OPC down to 1, which significantly reduces the amount of CO$_2$ released during processing. The reaction kinetics of hCHS differs from that of classical clinker phases due to the presence of highly reactive silicate species, which involve silanol groups instead of pure calcium silicates and aluminates and aluminoferrites. In contrast to Portland cement, no calcium hydroxide is formed during hydration, which otherwise regulates the Ca concentration. Without the buffering role of Ca(OH)$_2$ the concentration of the dissolved species c(Ca$^{2+}$) and c(SiO$_4^{4-}$) and the corresponding pH must be controlled to ensure a reproducible reaction. Pure hCHS reacts isochemically with water, resulting in a C-S-H phase with the same chemical composition as a single hydration product, with a homogeneous distribution of the main elements Ca and Si throughout the sample. Here we study via nanoindentation the mechanical properties of two different types of hardened pastes made out of Celitement (C/S=1.28), with varying amounts of hCHS and variable water to cement ratio. We couple nanoindentation grids with Raman mappings to link the nanoscale mechanical properties to individual microstructural components, yielding in-depth insight into the mechanics of the mineralogical phases constituting the hardened cement paste. We show that we can identify in hardened Celitement paste both fresh C-S-H with varying density, and C-S-H from the raw material using their specific Raman spectra, while simultaneously measuring their mechanical properties. Albeit not suitable for phase identification, EDX measurements provide valuable information about the distribution of alkalis, thus further helping to understand the reaction pattern of hCHS.