Short-duration extreme rainfall is a major trigger of flash floods and urban inundation, yet its quantification remains a profound challenge due to the scarcity of high-resolution observations. This review synthesizes how three central paradigms of nonlinear science, multifractal cascade theory, self-organized criticality (SOC) and chaos theory, provide critical insights and practical methodologies for bridging this observational gap. We examine how multifractal temporal downscaling leverages scale-invariance to derive sub-hourly rainfall statistics from coarser data. The SOC paradigm is discussed for its ability to explain the power-law statistics of rainfall extremes and cluster properties, offering a physical basis for estimating rare events. The role of chaos theory and its modern evolution into complex network analysis is explored for diagnosing predictability and spatiotemporal organization. By comparing and integrating these perspectives plus recent developments in stochastic hydrology, this review highlights their collective potential to advance the estimation, understanding, and prediction of short-duration extreme rainfall, ultimately informing improved risk assessment and climate resilience strategies.
Abstract Significant efforts have been devoted to investigating the oxidation of MXenes in various environments. However, the underlying mechanism of MXene oxidation and its dependence on the electrode potential remain poorly understood. Here we show the oxidation behavior of MXenes under the working conditions of electrochemical processes in terms of kinetics and thermodynamics by using constant-potential ab initio simulations. The theoretical results indicate that the potential effects can be attributed to the nucleophilic attack of water molecules on metal atoms, similar to that taking place in the Oxygen Evolution Reaction. Building upon these findings, we deduced the oxidation potential of the common MXenes, and proposed antioxidant strategies for MXene. Finally, we demonstrated that MBenes, the boron analogs of MXenes, may undergo a similar nucleophilic attack in water and inferred that molecule-induced Walden inversion is widely present in material reconstructions. This work contributes to a fundamental understanding MXene stability at the atomic level, and promotes the transition in materials discovery from trial-and-error synthesis to rational design.
The thermodynamic evolution of Coronal Mass Ejections (CMEs) in the inner corona (≤1.5 Rsun) is not yet completely understood. In this work, we study the evolution of thermodynamic properties of a CME core observed in the inner corona on 20 July 2017, by combining the MLSO/K-Cor white-light and the MLSO/CoMP Fe XIII 10747 Å line spectroscopic data. We also estimate the emission measure weighted temperature (TEM) of the CME core by applying the Differential Emission Measure (DEM) inversion technique on the SDO/AIA six EUV channels data and compare it with the effective temperature (Teff) obtained using Fe XIII line width measurements. We find that the Teff and TEM of the CME core show similar variation and remain almost constant as the CME propagates from ∼1.05 to 1.35 Rsun. The temperature of the CME core is of the order of million-degree kelvin, indicating that it is not associated with a prominence. Further, we estimate the electron density of this CME core using K-Cor polarized brightness (pB) data and found it decreasing by a factor of ∼3.6 as the core evolves. An interesting finding is that the temperature of the CME core remains almost constant despite expected adiabatic cooling due to the expansion of the CME core, which suggests that the CME core plasma must be heated as it propagates. We conclude that the expansion of this CME core behaves more like an isothermal than an adiabatic process.
Akhmad Masykur Hadi Musthofa, Mindriany Syafila, Qomarudin Helmy
Up to 60–70% of the total textile dyes produced are azo dyes. An example of azo dye is methylene blue, which is commonly used in dyeing wool, silk, and cotton. This substance possessed harmful effects on the environment. Therefore, the removal process is mandatory. The adsorption process is a common method for dye removal in wastewater. One innovation to increase adsorption efficiency even further is by reducing adsorbent particle size. To understand the effect of adsorbent particle size on the adsorption process, in this study, granular activated carbon (GAC) was pulverized into powder (PAC) and superfine powder (SPAC). Adsorbent characterizations, isotherm, kinetics, and thermodynamics tests were conducted. Based on this study, surface area, pore volume, and adsorption capacity were increased for smaller adsorbent particle sizes. Isotherm and kinetic analysis showed that there was no difference in the isotherm and kinetic models that applied to each activated carbon, but there was an increase in the isotherm and kinetic coefficient values at smaller particle sizes. Meanwhile, based on the thermodynamic test, there were differences in the dominant adsorption mechanism for each activated carbon. In GAC and SPAC, the dominant adsorption mechanism was electrostatic interactions, while in PAC was van der Waals forces.
Alberto Sainz Dalda, Alberto Sainz Dalda, Bart De Pontieu
et al.
The flare activity of the Sun has been studied for decades, using both space- and ground-based telescopes. The former have mainly focused on the corona, while the latter have mostly been used to investigate the conditions in the chromosphere and photosphere. The Interface Region Imaging Spectrograph (IRIS) instrument has served as a gateway between these two cases, given its capability to observe quasi-simultaneously the corona, the transition region, and the chromosphere using different spectral lines in the near- and far-ultraviolet ranges. IRIS thus provides unique diagnostics to investigate the thermodynamics of flares in the solar atmosphere. In particular, the Mg II h&k and the Mg II UV triplet lines provide key information about the thermodynamics of low to upper chromosphere, while the C II 1334 & 1335 Å lines cover the upper-chromosphere and low transition region. The Mg II h&k and the Mg II UV triplet lines show a peculiar, pointy shape before and during the flare activity. The physical interpretation, i.e., the physical conditions in the chromosphere, that can explain these profiles has remained elusive. In this paper, we show the results of a non-LTE inversion of such peculiar profiles. To better constrain the atmospheric conditions, the Mg II h&k and the Mg II UV triplet lines are simultaneously inverted with the C II 1334 & 1335 Å lines. This combined inversion leads to more accurate derived thermodynamic parameters, especially the temperature and the turbulent motions (micro-turbulence velocity). We use an iterative process that looks for the best fit between the observed profile and a synthetic profile obtained by considering non-local thermodynamic equilibrium and partial frequency redistribution of the radiation due to scattered photons. This method is computationally rather expensive (≈6 CPU-hour/profile). Therefore, we use the k-means clustering technique to identify representative profiles and associated representative model atmospheres. By inverting the representative profiles with the most advanced inversion code (STiC), in addition to recover the main physical parameters, we are able to conclude that these unique, pointy profiles are associated with a large gradient in the line-of-sight velocity along the optical depth in the high chromosphere.
To mitigate environmental issues and implement energy management strategies, hydrogen is emerging as the most promising and sustainable energy source to help achieve decarbonization targets and meet world energy demands. However, hydrogen poses significant storage and transportation challenges due to its low volumetric and gravimetric density. Hence, ammonia is a potential candidate for a hydrogen storage medium because it contains 17.65% hydrogen by weight, and its volumetric hydrogen density is 45% higher than that of liquid hydrogen. In the maritime sector, these available fuels of ammonia and hydrogen are utilized via internal combustion engines, fuel cells, and gas turbines, which are employed on board ships. This study investigates the possibility of using ammonia and hydrogen as fuels for Solid Oxide Fuel Cells (SOFCs). A combined SOFC-Gas Turbine (GT) system was proposed to generate power for marine propulsion plants. This system was designed and modeled with support from Aspen HYSYS V.12.1. Thermodynamics performances of the proposed system were analyzed using the first and second laws of thermodynamics. The energy efficiencies of direct ammonia and hydrogen SOFCs were 60.96 and 64.46%, respectively. The energy efficiencies of the combined systems increased by 12.37 and 13.97% when using ammonia and hydrogen as fuels, respectively, compared with that of single SOFC systems. The exergy destruction of the primary components with each fuel was examined. Furthermore, a parametric study was performed to select the most suitable fuel utilization factor for the system. This analysis proved that ammonia has the potential as a hydrogen carrier and that waste heat recovery is an effective method to improve the thermodynamic performance of an SOFC system.
Hilfer fractional stochastic differential equations with delay are discussed in this paper. Firstly, the solutions to the corresponding equations are given using the Laplace transformation and its inverse. Afterwards, the Picard iteration technique and the contradiction method are brought up to demonstrate the existence and uniqueness of understanding, respectively. Further, finite-time stability is obtained using the generalized Grönwall–Bellman inequality. As verification, an example is provided to support the theoretical results.
Meenakshi Giridhar, B. C. Manjunath, B. S. Surendra
et al.
Abstract This present research aimed to investigate the novel applications of synthesized La doped CuFe2O4 nanomaterial (LCF NMs) using renewable bio-fuel (Aegle Marmelos extract) by combustion process. The sensor applications were accomplished by modified electrode using LCF NMs with graphite powder and examined its excellent sensing action towards heavy metal (Lead content) and drug chemical (Paracetamol) substances. The thermodynamics of redox potential and super-capacitor behavior of LCF NMs were investigated through Cyclic Voltametric (CV) and Electrochemical Impedance Spectral (EIS) methods under specific conditions at scan rate of 1 to 5 mV/s. The heterogeneous photo-catalytic process of prepared NMs on Fast orange Red (FOR) dye-decolouration was investigated and noted its excellent degradation (91.7%) at 90 min using 20 ppm of dye solution and 40 mg of synthesized samples under Sun-light irradiation. Further, the antibacterial activity of synthesized NMs is investigated against various strains of gram positive (Bacillus subtillis) and gram negative bacteria (Pseudomonas aeruginosa), which confirms that the LCF NMs have higher activity towards gram positive bacteria with an average inhibition zone of 19 mm. This synthesized LCF NMs is a multi-functional material with stable and eco-friendly materials.
Polymorphs of titanium dioxides have found extensive applications in energy fields such as photocatalytic hydrogen generation and batteries. Further research on the thermochemistry of titanium dioxides should be conducted to attain a more detailed understanding of correlations among the steps of synthesis-structure-properties-performance paradigm for achieving controlled functionality. In this review, we briefly highlight important developments in polymorph structures, experimental accesses, stabilities, and thermodynamic data for nano-phased TiO2. We emphasis the important roles of surface hydration and structural symmetry on the stability of TiO2 in the context of photocatalysis and lithium-ions batteries. Because analogues of TiO2 phases have many important applications, the relevant results summarized in this work may have broad implications for the prediction of functionalities from the viewpoint of thermochemistry.
Copper (Cu(Ⅱ)) pollution has a hazardous effect on human health. However, designing new adsorbents with prominent properties is a tremendous challenge in effectively removing Cu(Ⅱ) ions from the environment. In this study, new adsorbent—MnFe2O4/multi-wall carbon nanotubes (MMWCNTs), with excellent magnetic properties were synthesized and then systematically characterized. Introducing MnFe2O4 addressed the challenge of separating the nano-adsorbent from the liquid medium. Batch adsorption experiment results indicated that effective adsorption occurred in a relatively neutral range (pH=6–8). The adsorption behaviors were consistent with the pseudo-second-order model and the Freundlich model. The maximum adsorption capacity reached 46.41 mg/g at 308 K. The adsorption thermodynamics revealed the endothermic character of adsorption by MMWCNTs, and increasing the temperature benefitted the adsorption process. Furthermore, many surface functional groups of MMWCNTs facilitated adsorption performance. Compared with the MWCNTs before modified, the adsorbent had a nearly tenfold improvement from 3.4% to 34.8% in the removal efficiency of Cu(Ⅱ) ions. These results demonstrated that MMWCNTs are a suitable, efficient adsorbent that can be used in natural water bodies for adsorbing Cu(Ⅱ) ions.
Fluidic oscillators have proven their capabilities and advantages in terms of the generation of oscillating jets without moving parts for many years, mainly in experimental studies. In this paper, the design, development, and integration of fluidic atomizers into the liquid-fuel system of the dual-fuel low NO<sub>X</sub> Advanced Can Combustion (ACC) system of the MAN Gas Turbines (MGT) are presented. The two-stage system comprises a pressure-swirl nozzle as a pilot stage and an assembly of four main premixed nozzles, based on fluidic technology. The design and the features of the pilot nozzle are briefly presented, whereas the focus lies on the functionality and layout of the fluidic nozzles. The complete integration, validation, and verification of this innovative liquid-fuel injection unit are presented. The final system features fast fuel-switchovers, low complexity, high reliability, and dry low emissions in liquid-fuel operation.
Thermodynamics, Descriptive and experimental mechanics
Francisco M. Marquez, Pedro J. Zufiria, Luis J. Yebra
In this paper, we present the physical foundations and the development of the thermodynamic part of a Modelica library with the fundamental components for modeling thermofluid systems. We have chosen Modelica because it is an object-oriented modeling language that allows an elegant design of the library, with a top-down conception that starts from very general components where we model the thermodynamic properties common to all simple substances and descend by inheritance to model the properties of each particular substance. To model the behavior of each component, we have used: classical thermodynamics to define the equilibrium states, the local equilibrium hypothesis of Classical Irreversible Thermodynamics to model the changes of state, and the port-Hamiltonian approach to obtain the equations of the system dynamics. With this formulation, we implement the thermodynamic behavior of ideal gases (including monatomic gases as a particular case), the 2073 substances defined for the CEA (Chemical Equilibrium with Applications) NASA Glenn computer program, the IAPWS Formulation 1995 for the Thermodynamic Properties of Water Substance for General and Scientific Use, and the Syltherm 800 HTF (Heat Transfer Fluid). We also define graphical symbols for each library component that facilitate modeling complex systems with simple drag-and-drop manipulations, component connection, and parameter selection. These symbols are a slightly modified version of those used in bond graphs to facilitate their reading and the representation of the structure of complex systems. We also show the modeling, simulation, and comparison for accuracy, performance, and scalability of some thermodynamic systems implemented with the Modelica Standard Library (MSL) and the proposed library.
Permeability is one of the most fundamental reservoir rock properties required for modeling hydrocarbon production. However, shale permeability is not yet fully understood because of the high temperature of shale reservoirs. The third thermal stress that is caused by temperature change will decrease the permeability of shale. In this work, a theoretical model has been derived to describe the permeability of shale considering the third thermal stress; the principles of thermodynamics and the mechanics of elasticity have been employed to develop this model. The elastic modulus parameters of the shale were measured, along with Poisson’s ratio, as required. Lastly, the permeability of shale was tested by transient pulse-decay. Isothermal flow experiments were carried out at 303, 313, 323, and 333 K to assess the effects of shale expansion and deformation on shale permeability caused by the third thermal stress. The permeability of shale samples, as predicted by the model, was found to agree well with experimental observations. The model may provide useful descriptions of the gas flow in shale. The correction accuracy of the permeability was found to increase at lower permeability. However, the development of completely predictive models for shale permeability will require additional experimental data and further testing.
Abstract In this work interacting Umami Chaplygin gas has been studied in flat FRW model of universe in context of it’s thermodynamic and dynamical behaviour. In particular, considering Umami fluid as dark energy interacting with dark matter, irreversible thermodynamics has been studied both for apparent and event horizon as bounding horizon in two separate cases. Also the model has been investigated in purview of dynamical systems analysis by converting the cosmological evolution equations to an autonomous system of ordinary differential equations. With some restrictions on model parameter $$\omega $$ ω and coupling parameter $$\lambda $$ λ , some cosmologically interesting critical points describing late time accelerated evolution of the universe attracted by cosmological constant and accelerated scaling attractor in quintessence era have been found to alleviate coincidence problem.
Astrophysics, Nuclear and particle physics. Atomic energy. Radioactivity
Rafael Bardera, Ángel Rodríguez-Sevillano, Adelaida García-Magariño
A wind tunnel tests campaign has been conducted to investigate the aerodynamic flow around a wing morphing to be used in a micro air vehicle. Non-intrusive whole field measurements were obtained by using PIV, in order to compare the velocity and turbulence intensity maps for the modified and the original version of an adaptive wing designed to be used in a micro air vehicle. Four sections and six angles of attack have been tested. Due to the low aspect ratio of the wing and the low Reynold number tested of 6.4 × 10<sup>4</sup>, the influence of the 3D effects has been proved to be important. At high angles of attack, the modified model prevented the detachment of the stream, increased the lift of the wing and reduced the turbulence intensity level on the upper surface of the airfoil and in the wake.
Thermodynamics, Descriptive and experimental mechanics
In order to study the phase transition through thermodynamic geometry, we consider the charged AdS black hole with global monopole. We first introduce thermodynamics of charged AdS black hole with global monopole by discussing the dependence of Hawking temperature, specific heat and P−v curve on horizon radius and monopole parameter. By implementing various thermodynamic geometry methods, for instance, Weinhold, Ruppiner, Quevedo and HPEM formulations, we derive corresponding scalar curvatures for charged AdS black hole with a global monopole. Here, we observe that, in contrast to Weinhold and Ruppeiner methods, HPEM and Quevedo formulations provide more information about the phase transition of the charged AdS black hole with a global monopole. Keywords: Phase transition, AdS black hole, Monopole, Geometrodynamics
A theoretical quantum Brayton engine research has been carried out using a potential box system to increase its thermal efficiency. The method applied in this research is a classical thermodynamics system model in the form of a piston tube containing a monatomic ideal gas analogous to a quantum model in the form of a potential box containing one particle. The efficiency formulation of the quantum Brayton engine obtained from this study is following the classical version. However, the efficiency value obtained on a quantum Brayton engine is higher when compared to its classic. It happens because the value of the Laplace constant owned by the Brayton quantum version is 3, while the classic version is 5/3.