Hasil untuk "Plasma physics. Ionized gases"

A. Kazemi, McKayla J. Nicol, Sven G. Bilén et al.

Plasma medicine is an emerging field that applies the science and engineering of physical plasma to biomedical applications. Low-temperature plasma, also known as cold plasma, is generated via the ionization of atoms in a gas, generally via exposure to strong electric fields, and consists of ions, free radicals, and molecules at varying energy states. Plasmas generated at low temperatures (approximately room temperature) have been used for applications in dermatology, oncology, and anti-microbial strategies. Despite current and ongoing clinical use, the exact mechanisms of action and the full range of effects of cold plasma treatment on cells are only just beginning to be understood. Direct and indirect effects of plasma on immune cells have the potential to be utilized for various applications such as immunomodulation, anti-infective therapies, and regulating inflammation. In this review, we combine diverse expertise in the fields of plasma chemistry, device design, and immunobiology to cover the history and current state of plasma medicine, basic plasma chemistry and their implications, the effects of cold atmospheric plasma on host cells with their potential immunological consequences, future directions, and the outlook and recommendations for plasma medicine.

Nikolai N. Bogachev, Vyacheslav P. Stepin, Vsevolod I. Zhukov et al.

This study investigates the axial electron density distribution in two plasma antenna configurations excited by a surface wave microwave discharge and its influence on the radiation pattern of antennas. The axial plasma electron density profiles were characterized using two non-invasive diagnostic techniques: the resonant cavity measurements in the TM₁₁₀ mode and the waveguide transmission analysis. A linear decrease in the plasma electron density along the antenna was observed. The effective electrical length of the plasma antennas, accounting for this density distribution, is found to be approximately half the physical plasma column length. Numerical simulations employing COMSOL Multiphysics based on the Drude model revealed that a realistic nonuniform axial plasma electron density distribution markedly modifies the antenna radiation characteristics. For the wave-type plasma monopole antenna, this results in a shift in the emission maximum, a reduction in the main lobe amplitude, a nearly twofold broadening of the main lobe, and the disappearance of the side lobe. For the quarter-wave-type plasma asymmetric dipole antenna, there is a reduction in the main lobe amplitude without a shift in the maximum and a broadening of the main lobe due to an increase in the side-lobe level and its merging with the main lobe.

Alexander S. Metel, Marina A. Volosova, Enver S. Mustafaev et al.

To increase the wear resistance of a hollow ceramic product, it is necessary to apply wear-resistant coatings to all its surfaces, including the internal surfaces. Before the coating deposition, the surface must be processed with a beam of energetic particles to ensure its adhesion. In this study, a scheme for processing internal surfaces of hollow cylinders with fast argon atoms is proposed and tested. Simultaneous treatment of all surfaces of the rotating ceramic cylinder allowed for deposition of a uniform TiB₂ coating on both sides of the cylinder and a decrease in the abrasion wear by several times.

Takaki Miyamoto, Jeanielle Amurao, Eiji Minami et al.

Lignin is a natural aromatic macromolecule present in wood and an abundant resource on Earth, yet it is hardly used. In this study, an aqueous solution plasma treatment was investigated for the catalyst-free production of valuable chemicals from lignin. To elucidate the decomposition mechanism, the aqueous solution plasma treatment was applied to the fundamental lignin aromatic model compounds—phenol, guaiacol, and syringol. The results showed that the decomposition rate followed the order syringol > guaiacol > phenol, indicating that electron-donating methoxy groups enhance reactivity. These aromatic model compounds underwent hydroxylation at the ortho and para positions, oxidative ring cleavage, and fragmentation, leading to the formation of various dicarboxylic acids, primarily oxalic acid. All these reactions were promoted by hydroxyl radicals generated from water. Ultimately, decarbonylation and decarboxylation of carboxyl groups resulted in gasification, mainly producing H₂, CO, and CO₂. These results provide fundamental insights into lignin decomposition and demonstrate that aqueous solution plasma is a promising method for producing dicarboxylic acids from lignin under mild conditions without catalysts.

Alexander S. Metel, Marina A. Volosova, Enver S. Mustafaev et al.

The removal of defective surface layers can substantially improve the quality of various products. It can be carried out using beams of accelerated ions or fast argon atoms. However, it is difficult to process the inner surface of narrow channels. In the present work, a narrow beam of fast argon atoms is used to sputter and polish the inner surface of drawing dies with 5.7 mm wide working channels. Due to the high angle of incidence to the channel walls, sputtering with fast argon atoms decreased their roughness to Ra ~ 0.004 µm.

D. Endrizzi, J. Anderson, M. Brown et al.

The Wisconsin high-temperature superconductor axisymmetric mirror experiment (WHAM) will be a high-field platform for prototyping technologies, validating interchange stabilization techniques and benchmarking numerical code performance, enabling the next step up to reactor parameters. A detailed overview of the experimental apparatus and its various subsystems is presented. WHAM will use electron cyclotron heating to ionize and build a dense target plasma for neutral beam injection of fast ions, stabilized by edge-biased sheared flow. At 25 keV injection energies, charge exchange dominates over impact ionization and limits the effectiveness of neutral beam injection fuelling. This paper outlines an iterative technique for self-consistently predicting the neutral beam driven anisotropic ion distribution and its role in the finite beta equilibrium. Beginning with recent work by Egedal et al. (Nucl. Fusion, vol. 62, no. 12, 2022, p. 126053) on the WHAM geometry, we detail how the FIDASIM code is used to model the charge exchange sources and sinks in the distribution function, and both are combined with an anisotropic magnetohydrodynamic equilibrium solver method to self-consistently reach an equilibrium. We compare this with recent results using the CQL3D code adapted for the mirror geometry, which includes the high-harmonic fast wave heating of fast ions.

Valentin Boutrouche, Juan Pablo Trelles

The Atmospheric Pressure Glow Discharge (APGD) is a relatively simple and versatile plasma source used in a wide range of applications. Active cooling of the cathode can effectively mitigate instabilities, leading to glow-to-arc transitions. This study investigates the effect of varying the degree of cathode cooling in APGD with a planar cathode in helium. The plasma flow model incorporates mass conservation, chemical species transport, momentum conservation, conservation of thermal energy of heavy species and of electrons, and electrostatics. The model is applied to time-dependent simulations through a three-dimensional computational domain describing the whole discharge, without geometric symmetry or steady-state assumptions. Simulations of an experimentally characterized APGD explore the effects of electric current and cathode cooling—ranging from thermally insulated to extreme convective cooling. Results show the formation of an annular region with high electric field over the cathode surface under conditions of high current and low cooling.

Xiao Song, Brian Leard, Zibo Wang et al.

A free-boundary equilibrium solver for an axisymmetric tokamak geometry was developed based on the finite difference method and Picard iteration in a rectangular computational area. The solver can run either in forward mode, where external coil currents are prescribed until the converged magnetic flux function <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mi>ψ</mi><mo>(</mo><mi>R</mi><mo>,</mo><mi>Z</mi><mo>)</mo></mrow></semantics></math></inline-formula> map is achieved, or in inverse mode, where the desired plasma boundary, with or without an X-point, is prescribed to determine the required coil currents. The equilibrium solutions are made consistent with prescribed plasma parameters, such as the total plasma current, poloidal beta, or safety factor at a specified flux surface. To verify the mathematical correctness and accuracy of the solver, the solution obtained using this numerical solver was compared with that from an analytic fixed-boundary equilibrium solver based on the EAST geometry. Additionally, the proposed solver was benchmarked against another numerical solver based on the finite-element and Newton-iteration methods in a triangular-based mesh. Finally, the proposed solver was compared with equilibrium reconstruction results in DIII-D experiments.

Espedito Vassallo, Matteo Pedroni, Marco Aloisio et al.

Biodegradable polymers (poly(butylene succinate (PBS)), poly(butylene adipate terephthalate (PBAT)) and poly(lactic acid)/poly(butylene adipate terephthalate (PLA/PBAT)) blend) were treated in radiofrequency (13.56 MHz) low-pressure (10 Pa) oxygen with argon post-crosslinking plasma to enhance wettability and adhesion properties. Surface morphology and roughness modification caused by plasma exposure were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Surface chemical modifications of plasma-treated samples were evaluated by Fourier Transform infrared spectroscopy (FTIR). Due to the limited durability of plasma activation, the hydrophobic recovery was evaluated by water contact angle (WCA) measurements. The ageing effect was measured over 15 days in order to assess this kind of treatment as a potential industrial scalable method to increase biodegradable polymers <i>hydrophilic</i> properties for food packaging applications. The effects of polymer activation on its weight loss were also determined. Differential scanning calorimetry (DSC) analysis was used to study the effect of plasma treatment on the thermal properties of the polymers, while the crystallinity was investigated by X-ray diffraction (XRD).

Jordan Stone, Mira Khair, Steven Cavazos et al.

The advancement of nuclear energy technology necessitates the development of novel materials and synthesis methods to produce materials which enable new fuel cycles. Alongside the maturation of R&amp;D scale technologies to produce these materials, there is an ongoing effort to develop in situ monitoring capabilities to reduce the time to the discovery and development of these fuels. Monitoring data can be leveraged in artificial intelligence platforms to detect phenomena which lead to varied macro- and microstructural features which impact the application and performance of samples synthesized. The present study presents early-stage findings of the implementation of high-temperature, high-frame-rate infrared thermal imaging to monitor the arc-melt synthesis of novel fuels and compounds relevant to advanced nuclear reactors. The study illustrates both the challenges and opportunities of this methodology, highlighting the importance of internal standards while determining emissivity and transmission values as well as visualizing volatilization during melt synthesis.

Edgar Buck, Robin Taylor

Haydn C. Bryan, Katherine W. Jesse, Charles A. Miller et al.

The nuclear energy industry is looking to next-generation reactor designs to augment, diversify, and expand generation capacity in an increasingly complex and varied energy landscape. A key element in this objective is microreactors—small nuclear reactors which can provide flexible capacity at a reduced scale compared to traditional large-scale nuclear reactors. Specifically, microreactors could be used to provide clean, reliable combined heat and power to remote communities, worksites, or facilities. However, the construction and operations and maintenance costs to supply the required operator staffing and physical supporting assets, such as control rooms, could be a limiting factor for first adopters of the technology. Opportunities to reduce the cost of monitoring and control activities could enable early adoption, allowing economies of learning to take effect, spurring further adoption. A reduction in the number and cost intensity of control rooms and operators per deployed microreactor could significantly decrease the overall cost for a fleet of microreactors. To optimize microreactor economic competitiveness, one solution would be to establish an off-site operation facility for centralized monitoring and control (CM&amp;C) of a fleet of microreactors. Leveraging advances in digital instrumentation and control systems could bolster the safety, reliability, and security of the remote communication architecture inherently required to operate remotely. Digital twins (DTs) are virtual replicas of physical assets which can be used for a variety of applications, including analyzing I&amp;C signals against a validated model to perform several analysis and prediction functions. When implemented properly, DTs can potentially detect anomalies and component failures, and serve as a diagnostic tool for operators. These technologies can enhance operator understanding and awareness, reduce the management demand time on operators, and increase asset uptime by providing early alerts for failures alongside insights to aid in predictive maintenance. Furthermore, a DT system could enhance the secure and reliable communication architecture necessary for remote microreactor operation by verifying signals and suggesting or automating controls, thereby boosting their economic viability. This research examines the economic effects of various control strategies ranging from many individually and on-site controlled reactors to co-management of all microreactors in a system from a single, off-site control center. Results from the analysis are positive, revealing significant cost-reduction opportunities.

Hye-Ryun Cho, Hye-Ryun Cho, Sangki Cho et al.

PuO2(cr) dissolution in natural water was investigated at 25°C and 60°C under atmospheric conditions. The concentration of Pu in solutions [Pu], was monitored for 1 year of reaction time. PuO2(cr) dissolution in natural water reached a steady state within 2 months at 25°C. The [Pu] in groundwater and seawater at pH 8 were in the range of [Pu] = 0.9–34 and 3.4–27 nM, respectively. The [Pu] in concrete porewater (rainwater equilibrated with concrete) at pH 8.1–10.9 was in the range of 0.1–3.2 nM. The [Pu] and pH values of groundwater were similar to those of seawater samples having a high ionic strength. The measured [Pu] at equilibrium in all samples was higher than the calculated solubility curves for PuO2(am, hyd). Experimental evidence is insufficient to confirm the oxidation state of Pu in solution and solid phases. However, the results of geochemical modeling indicate that PuO2(am, hyd) and aqueous Pu(IV) species are dominant in natural water samples of this work. The dissolution behavior of PuO2(cr) in natural waters is comparable to the oxidative dissolution of PuO2(am, hyd) in the presence of PuO2(coll, hyd). The dissolution of PuO2 in groundwater decreased at higher temperatures, whereas the influence of temperature in seawater and porewater was not significant under these experimental conditions.

Gurbax Singh Lakhina, Satyavir Singh, Thekkeyil Sreeraj et al.

Large-amplitude electrostatic waves propagating parallel to the background magnetic field have been observed at the Earth’s magnetopause by the Magnetospheric Multiscale (MMS) spacecraft. These waves are observed in the region where there is an intermixing of magnetosheath and magnetospheric plasmas. The plasma in the intermixing region is modeled as a five-component plasma consisting of three types of electrons, namely, two counterstreaming hot electron beams and cold electrons, and two types of ions, namely, cold background protons and a hot proton beam. Sagdeev pseudo-potential technique is used to study the parallel propagating nonlinear electrostatic solitary structures. The model predicts four types of modes, namely, slow ion-acoustic mode, fast ion-acoustic mode, slow electron-acoustic mode and fast electron-acoustic modes. Except the fast ion-acoustic mode, all other modes support solitons. Whereas slow ion-acoustic solitons have positive potentials, both slow and fast electron-acoustic solitons have negative potentials. For the case of 4% cold electron density, the slow ion-acoustic solitons have electric field ∼(40–120) mV m<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><msup><mrow></mrow><mrow><mo>−</mo><mn>1</mn></mrow></msup></semantics></math></inline-formula>. The fast Fourier transforms (FFT) of slow ion-acoustic solitons produce broadband frequency spectra having peaks between ∼100 Hz to 1000 Hz. These theoretical predictions are in good agreement with the observations. The slow and fast electron-acoustic solitons could be relevant in explaining the low-intensity high (>1 kHz) frequency waves which are also observed at the same time.

Julia Sutter, Jascha Brettschneider, Sara Mamchur et al.

In Plasma Medicine studies, the effect of non-thermal plasma (NTP) on biological targets is typically correlated with the amount of stable reactive oxygen and nitrogen species produced in a liquid medium. The effect of NTP and the response of the biological target on cellular redox mechanisms is overlooked in these investigations. Additionally, the influence of electrical properties of cells on the physical properties of NTP is neglected. Therefore, we used a floating electrode dielectric barrier discharge plasma to explore the impact of cell structure, size, and viability of the biological target on the physical properties of NTP. Lissajous figures were used to determine circuit capacitance and energy per cycle during NTP exposure of different cell suspensions. We show that both, structural integrity and active enzymic processes of cells change the electrical properties of NTP. Correlations were also drawn between NTP-produced hydrogen peroxide and nitrite with measured capacitance. Our studies indicate that the observed changes between different cell suspensions may be due to a feedback loop between the biological target and the NTP source. In future studies, a more detailed analysis is needed to improve the control of clinical NTP devices.

Tiankai Yao, Mukesh Bachhav, Fidelma G. Di Lemma et al.

U-Zr metallic fuel is a promising fuel candidate for Gen Ⅳ fast spectrum reactors. Previous experimental irradiation campaigns showed that the sodium thermal bonded U-10Zr fuel design can achieve a burnup of 10% fissions per initial heavy metal atom (FIMA). Advanced metallic fuel designs are pushing the burnup limit to 20% or even 30% FIMA. To achieve the higher burnup and eliminate the pyrophoric sodium, a prototypical annular fuel has been designed, fabricated, clad with HT-9 in the Materials and Fuels Complex, and irradiated in the Advanced Test Reactors of Idaho National Laboratory (INL) to a peak burnup of 3.3% FIMA. During irradiation, the mechanical contact between fuel and cladding acts as a thermal bond. The irradiation lasted for 132 days in the reactor. Recently, the archived fresh and irradiated fuel samples were characterized using advanced characterization capabilities in the Irradiated Materials Characterization Laboratory (IMCL) of INL. This article summarizes the results of advanced characterization and computer vision-based materials informatics to reveal the irradiation effects on U-Zr metallic fuel. Future work will focus on further implementation of advanced characterization and statistical data mining to improve the fidelity of fuel performance modeling and support U-Zr metallic fuel qualification for fast spectrum reactors.

I. Senichenkov, E. Kaveeva, V. Rozhansky et al.

A possibility to operate with fully detached targets and highly radiating X‐point was recently demonstrated on ASDEX Upgrade, JET, and DIII‐D with intensive impurity seeding (N, Ne, Ar) and feedback control. Notable feature of such a regime is the radiated power fraction of up to 90% of discharge power inside the separatrix without a confinement degradation, or even with confinement improvement (in terms of H‐factor), which leads to a full detachment of both targets. Therefore, this regime might be attractive for the next generation reactor scale tokamaks like DEMO or CFETR, where most of the power should be radiated. In the present report, the recent achievements in the understanding of such regime are reviewed. The effectiveness of divertor target shielding by different impurity gases is discussed, paying attention to its first ionization potential. SOLPS‐ITER modelling results illustrating the impurity flow pattern are presented, and the importance of drift flows is demonstrated. The effect of the machine size on the effectiveness of the divertor shielding by impurity radiation is discussed. It is demonstrated that in bigger machines impurity radiation is better kept in the divertor and divertor asymmetry is less pronounced. As the seeding rate increases, both targets fully detach, and neutrals start to penetrate inside the separatrix above the X‐point, leading to the plasma cooling there and to the formation of an observable localized radiation spot in the X‐point vicinity. The cold zone above the X‐point thus behaves as an energy sink like a divertor in conventional regime, so that the perpendicular decay length of perpendicular turbulent energy flow appears to be of the order of λq of conventional divertor. During the formation of the radiating X‐point a potential hill/well (depending on the direction of B×∇B drift) is formed on perturbed closed flux surfaces, and the corresponding E×B drift vortex fluxes appear to give major contribution to the particle balance. SOLPS‐ITER simulations show that the radial electric field significantly deviates from neoclassical formula and may even change sign (become positive). Thus, the zone of maximal poloidal rotation shear may shift inwards, which might be responsible for the inward shift of the transport barrier and for the confinement improvement. This effect is different to the discussed extension of peeling‐ballooning stability boundary by intensive impurity injection, which might explain experimentally observed ELMs suppression or their frequency reduction.

Jean-Christophe Pain

The modelling of ionization potential depression in warm and hot dense plasmas constitutes a real theoretical challenge due to ionic coupling and electron degeneracy effects. In this work, we present a quantum statistical model based on a multi-configuration description of the electronic structure in the framework of Density Functional Theory. We discuss different conceptual issues inherent to the definition of ionization potential depression and compare our results with the famous and widely-used Ecker-Kröll and Stewart-Pyatt models.

J. Kim, I. Kaganovich, Hyo-Chang Lee

Ionization gas sensors are ubiquitous tools that can monitor desired gases or detect abnormalities in real time to protect the environment of living organisms or to maintain clean and/or safe environment in industries. The sensors’ working principle is based on the fingerprinting of the breakdown voltage of one or more target gases using nanostructured materials. Fundamentally, nanomaterial-based ionization-gas sensors operate within a large framework of gas breakdown physics; signifying that an overall understanding of the gas breakdown mechanism is a crucial factor in the technological development of ionization gas sensors. Moreover, many studies have revealed that physical properties of nanomaterials play decisive roles in the gas breakdown physics and the performance of plasma-based gas sensors. Based on this insight, this review provides a comprehensive description of the foundation of both the gas breakdown physics and the nanomaterial-based ionization-gas-sensor technology, as well as introduces research trends on nanomaterial-based ionization gas sensors. The gas breakdown is reviewed, including the classical Townsend discharge theory and modified Paschen curves; and nanomaterial-based-electrodes proposed to improve the performance of ionization gas sensors are introduced. The secondary electron emission at the electrode surface is the key plasma–surface process that affects the performance of ionization gas sensors. Finally, we present our perspectives on possible future directions.