Semantic Scholar Open Access 2019 357 sitasi

Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Zhijie Chen Sylvia L. Hanna Louis R. Redfern Dalal Alezi Timur Islamoglu +1 lainnya

Lihat Sumber DOI

Abstrak

Abstract In the past two decades, reticular chemistry has developed into a powerful tool for the design and synthesis of porous, crystalline framework materials. The discovery of the first hexanuclear, zirconium cluster-based MOF (i.e. UiO-66; fcu net) led to a vast library of functional Zr-MOFs with various properties. The versatile connectivity of zirconium hexanuclear clusters and the adaptable tunability of organic ligands have resulted in the rational synthesis of a large set of Zr-MOFs based on edge-transitive nets; these nets commonly exists in crystalline network structures as suggested by reticular chemistry. In this review, we summarize recent advances in the synthesis of zirconium cluster-based MOFs in the light of reticular chemistry design principles. Isoreticular tuning of MOF parent structures and post-synthetic modification of Zr-MOFs for targeted applications are also deliberated.

Topik & Kata Kunci

Chemistry

Penulis (6)

Zhijie Chen

Sylvia L. Hanna

Louis R. Redfern

Dalal Alezi

Timur Islamoglu

O. Farha

Format Sitasi

APA MLA BibTeX

Chen, Z., Hanna, S.L., Redfern, L.R., Alezi, D., Islamoglu, T., Farha, O. (2019). Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs. https://doi.org/10.1016/J.CCR.2019.01.017

Akses Cepat

Lihat di Sumber doi.org/10.1016/J.CCR.2019.01.017

Informasi Jurnal

Tahun Terbit: 2019
Bahasa: en
Total Sitasi: 357×
Sumber Database: Semantic Scholar
DOI: 10.1016/J.CCR.2019.01.017
Akses: Open Access ✓