Semantic Scholar Open Access 2020 405 sitasi

Deep eutectic solvents and their applications as green solvents

F. Perna P. Vitale V. Capriati

Abstrak

Several examples illustrate the effectiveness of using Deep Eutectic Solvents (DESs) as environmentally responsible reaction media in polar organometallic chemistry and in metal-catalysed and biocatalysed processes in place of conventional, often hazardous volatile organic compounds (VOCs). Apart from the standpoint of ‘greenness’, applications of DESs in the aforementioned fields also reveal novel aspects of reactivity of practical significance, which are worthy of an in-depth mechanistic understanding: (a) metal-mediated organic transformations can be run in DESs competitively with protonolysis, often at room temperature and under air, (b) metal-catalysed reactions proceed efficiently and under milder conditions in DESs than in VOCs, with the catalyst and DES being easily and successfully recycled and (c) biocatalysts often exhibit higher stability, selectivity and performances in DES mixtures than in aqueous solutions, as well as a somewhat intriguing stereoselectivity.

Topik & Kata Kunci

Chemistry

Penulis (3)

F. Perna

P. Vitale

V. Capriati

Format Sitasi

APA MLA BibTeX

Perna, F., Vitale, P., Capriati, V. (2020). Deep eutectic solvents and their applications as green solvents. https://doi.org/10.1016/j.cogsc.2019.09.004

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Informasi Jurnal

Tahun Terbit: 2020
Bahasa: en
Total Sitasi: 405×
Sumber Database: Semantic Scholar
DOI: 10.1016/j.cogsc.2019.09.004
Akses: Open Access ✓