Novel gadolinium garnet Gd3Te2Li3O12: magnetism and magnetocaloric performance for sub-kelvin cryogenic applications.
Abstrak
The global helium shortage and escalating costs in cryogenic engineering have intensified demands for helium-free refrigeration technologies. Adiabatic demagnetization refrigeration (ADR) based on the magnetocaloric effect (MCE) presents a viable solution, with its efficacy fundamentally dependent on advanced magnetocaloric materials. Here we present the successful synthesis of a novel gadolinium garnet Gd3Te2Li3O12 through solid-state reaction, which crystallizes in the cubic Ia3̄d space group. The integration of magnetic characterization results with density functional theory (DFT) calculations establishes Gd3Te2Li3O12 as an antiferromagnetic compound exhibiting ultra-low magnetic ordering below 0.4 K. A comprehensive evaluation of the sub-kelvin magnetocaloric parameters demonstrates advantageous characteristics compared to commercial gadolinium gallium garnet (GGG) benchmarks, featuring both reduced magnetic ordering temperature and optimized entropy variation in the sub-Kelvin regime. These metrics position Gd3Te2Li3O12 as a prime candidate for sub-Kelvin ADR systems, while the observed geometrically frustrated magnetic sublattice configuration suggests new design principles for next generation magnetocaloric materials.
Topik & Kata Kunci
Penulis (6)
Xuetong He
L. Tian
Jianjian Gong
Xinqiang Gao
Guodong Liu
Z. Mo
Akses Cepat
- Tahun Terbit
- 2025
- Bahasa
- en
- Total Sitasi
- 1×
- Sumber Database
- Semantic Scholar
- DOI
- 10.1039/d5dt00989h
- Akses
- Open Access ✓