Advances in Structure Manipulation of Cobalt-Based Oxides for Catalytic Oxidation of Exhaust Gas.

Catalytic oxidation technologies for industrial exhaust emissions (e.g., VOCs, CO, and NOx) have gained significant attention due to the severe environmental and public health impacts. Recent advances highlight cobalt-based oxides as superior catalytic materials owing to excellent physicochemical properties, but the diverse compositions of industrial exhaust gases present significant obstacles in their practical applications. To develop rational design strategies for efficient cobalt-based oxides, exploring the structure-activity relationship (SAR) provides guidance for engineering structural properties to enhance performance. In this context, this review delves into how SAR impacts catalytic performance in exhaust gas purification through geometric structure modulation (size effects, morphology, and surface defect structures) and electronic structure modulation (Co-O bond strengths, d-band centers, coordination environments, and constrained structures). Furthermore, special attention is given to mechanistic studies combining reaction kinetic modeling, in situ spectroscopic characterization, and the effects of water vapor and SO2 on catalytic oxidation processes. We further outline emerging synthetic strategies and ongoing challenges for the design of next-generation cobalt-based catalysts. This review provides guidance and inspiration for the development of high-performance cobalt-based oxides for exhaust gas purification.