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Semantic Scholar Open Access 2020 127 sitasi

Three-Dimensional Mesoporous Covalent Organic Frameworks through Steric Hindrance Engineering.

Yujie Wang Yaozu Liu Hui Li X. Guan Ming Xue +4 lainnya
Lihat Sumber DOI

Abstrak

The development of three-dimensional (3D) covalent organic frameworks (COFs) with large pores and high surface areas is of great importance for various applications. However, it remains a major challenge due to the frequent structural interpenetration and pore collapse after the removal of guest species situated in the pores. Herein, we report for the first time a series of 3D mesoporous COFs through a general method of steric hindrance engineering. By placing methoxy and methyl groups strategically on the monomers, we can obtain non-interpenetrated 3D COFs of diamondoid structures with permanent mesopores (up to 26.5 Å) and high surface areas (> 3000 m2 g-1), which are far superior to those of reported conventional COFs with the same topology. This work thus opens a new avenue to create 3D large-pore COFs for potential applications in adsorption and separation of large inorganic, organic, and biological molecules.

Topik & Kata Kunci

Medicine Chemistry

Penulis (9)

Y

Yujie Wang

Y

Yaozu Liu

H

Hui Li

X

X. Guan

M

Ming Xue

Y

Yushan Yan

V

V. Valtchev

S

S. Qiu

Q

Q. Fang

Format Sitasi

APA MLA BibTeX
Wang, Y., Liu, Y., Li, H., Guan, X., Xue, M., Yan, Y. et al. (2020). Three-Dimensional Mesoporous Covalent Organic Frameworks through Steric Hindrance Engineering.. https://doi.org/10.1021/jacs.0c00560

Akses Cepat

Lihat di Sumber doi.org/10.1021/jacs.0c00560
Informasi Jurnal
Tahun Terbit
2020
Bahasa
en
Total Sitasi
127×
Sumber Database
Semantic Scholar
DOI
10.1021/jacs.0c00560
Akses
Open Access ✓