Semantic Scholar Open Access 2017 1223 sitasi

Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes

A. Álvarez Atul Bansode A. Urakawa Anastasiya V. Bavykina T. Wezendonk +3 lainnya

Lihat Sumber DOI

Abstrak

The recent advances in the development of heterogeneous catalysts and processes for the direct hydrogenation of CO2 to formate/formic acid, methanol, and dimethyl ether are thoroughly reviewed, with special emphasis on thermodynamics and catalyst design considerations. After introducing the main motivation for the development of such processes, we first summarize the most important aspects of CO2 capture and green routes to produce H2. Once the scene in terms of feedstocks is introduced, we carefully summarize the state of the art in the development of heterogeneous catalysts for these important hydrogenation reactions. Finally, in an attempt to give an order of magnitude regarding CO2 valorization, we critically assess economical aspects of the production of methanol and DME and outline future research and development directions.

Topik & Kata Kunci

Chemistry Medicine

Penulis (8)

A. Álvarez

Atul Bansode

A. Urakawa

Anastasiya V. Bavykina

T. Wezendonk

M. Makkee

J. Gascón

F. Kapteijn

Format Sitasi

APA MLA BibTeX

Álvarez, A., Bansode, A., Urakawa, A., Bavykina, A.V., Wezendonk, T., Makkee, M. et al. (2017). Challenges in the Greener Production of Formates/Formic Acid, Methanol, and DME by Heterogeneously Catalyzed CO2 Hydrogenation Processes. https://doi.org/10.1021/acs.chemrev.6b00816

Akses Cepat

Lihat di Sumber doi.org/10.1021/acs.chemrev.6b00816

Informasi Jurnal

Tahun Terbit: 2017
Bahasa: en
Total Sitasi: 1223×
Sumber Database: Semantic Scholar
DOI: 10.1021/acs.chemrev.6b00816
Akses: Open Access ✓