Semantic Scholar Open Access 2016 509 sitasi

Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2/CO2.

Jingru Fu Saikat Das Guolong Xing T. Ben V. Valtchev +1 lainnya

Abstrak

The search for new types of membrane materials has been of continuous interest in both academia and industry, given their importance in a plethora of applications, particularly for energy-efficient separation technology. In this contribution, we demonstrate for the first time that a metal-organic framework (MOF) can be grown on the covalent-organic framework (COF) membrane to fabricate COF-MOF composite membranes. The resultant COF-MOF composite membranes demonstrate higher separation selectivity of H2/CO2 gas mixtures than the individual COF and MOF membranes. A sound proof for the synergy between two porous materials is the fact that the COF-MOF composite membranes surpass the Robeson upper bound of polymer membranes for mixture separation of a H2/CO2 gas pair and are among the best gas separation MOF membranes reported thus far.

Topik & Kata Kunci

Penulis (6)

J

Jingru Fu

S

Saikat Das

G

Guolong Xing

T

T. Ben

V

V. Valtchev

S

S. Qiu

Format Sitasi

Fu, J., Das, S., Xing, G., Ben, T., Valtchev, V., Qiu, S. (2016). Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2/CO2.. https://doi.org/10.1021/jacs.6b03348

Akses Cepat

Lihat di Sumber doi.org/10.1021/jacs.6b03348
Informasi Jurnal
Tahun Terbit
2016
Bahasa
en
Total Sitasi
509×
Sumber Database
Semantic Scholar
DOI
10.1021/jacs.6b03348
Akses
Open Access ✓