Mapping and Modeling Physicochemical Fields in Solid-State Batteries.
Abstrak
The safety and energy density of solid-state batteries can be, in principle, substantially increased compared with that of conventional lithium-ion batteries. However, the use of solid-state electrolytes instead of liquid electrolytes introduces pronounced complexities to the solid-state system because of the strong coupling between different physicochemical fields. Understanding the evolution of these fields is critical to unlocking the potential of solid-state batteries. This necessitates the development of experimental and theoretical methods to track electrochemical, stress, crack, and thermal fields upon battery cycling. In this Perspective, we survey existing characterization techniques and the current understanding of multiphysics coupling in solid-state batteries. We propose that the development of experimental tools that can map multiple fields concurrently and systematic consideration of material plasticity in theoretical modeling are important for the advancement of this emerging battery technology. This Perspective provides introductory material on solid-state batteries to scientists from a broad physical chemistry community, motivating innovative and interdisciplinary studies in the future.
Topik & Kata Kunci
Penulis (4)
Zhetao Sun
Jingying Zhou
Yifan Wu
Shou‐Hang Bo
Akses Cepat
PDF tidak tersedia langsung
Cek di sumber asli →- Tahun Terbit
- 2022
- Bahasa
- en
- Total Sitasi
- 11×
- Sumber Database
- Semantic Scholar
- DOI
- 10.1021/acs.jpclett.2c02800
- Akses
- Open Access ✓