DOAJ Open Access 2024

Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes

Fayet, Océane Yvonne Odette Crespi, Stefano Orthaber, Andreas

Abstrak

A series of solid-state structures of gold(I) complexes using the semi-rigid cis-1,2- bis(diphenylphosphino)ethene (= cis-bdppe) ligand are reported. The proximity of the phosphine donor atoms of the bidentate ligand framework greatly favors formation of mononuclear over di- nuclear complexes. Structural analysis and theoretical studies shed further light on counter intermolecular packing motifs in the solid state including interactions of solvent, ligand and counterion fragments.

Topik & Kata Kunci

Biochemistry Physical and theoretical chemistry Mathematics

Penulis (3)

Fayet, Océane Yvonne Odette

Crespi, Stefano

Orthaber, Andreas

Format Sitasi

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Odette, F.O.Y., Stefano, C., Andreas, O. (2024). Synthesis and characterization of cis-bisdiphenylphosphinoethene gold(I) complexes. https://doi.org/10.5802/crchim.328

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Informasi Jurnal

Tahun Terbit: 2024
Sumber Database: DOAJ
DOI: 10.5802/crchim.328
Akses: Open Access ✓