DOAJ Open Access 2026

One-Pot Electrooxidative Allylation of Carbamates in the Presence of HBF4 and H2O

Haruka HOMMA Aika MOCHIZUKI Kaori MIYAKOSHI Natsumi HONJO Misaki AKETO +2 lainnya

Abstrak

The one-pot electrooxidative allylation of carbamates was successfully demonstrated in the presence of HBF4 and H2O. Anodic oxidation of carbamates generated the corresponding α-hydroxylated intermediates in the presence of H2O. Without separating the intermediates after electrolysis, reacting them with allyltrimethylsilane in the presence of HBF4 yielded the corresponding α-allylated products in high yields. This method was found to be applicable to several carbamates, except those with an acid-labile Boc protecting group.

Topik & Kata Kunci

Technology Physical and theoretical chemistry

Penulis (7)

Haruka HOMMA

Aika MOCHIZUKI

Kaori MIYAKOSHI

Natsumi HONJO

Misaki AKETO

Kohei FUNATSU

Toshiki TAJIMA

Format Sitasi

APA MLA BibTeX

HOMMA, H., MOCHIZUKI, A., MIYAKOSHI, K., HONJO, N., AKETO, M., FUNATSU, K. et al. (2026). One-Pot Electrooxidative Allylation of Carbamates in the Presence of HBF4 and H2O. https://doi.org/10.5796/electrochemistry.25-00153

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Informasi Jurnal

Tahun Terbit: 2026
Sumber Database: DOAJ
DOI: 10.5796/electrochemistry.25-00153
Akses: Open Access ✓