DOAJ
Open Access
2024
Mg Electrodes Coiled with Cu Wires Promoted Formation of Diphenylacetylene from Tetrachloroethylene and Bromobenzene: One-step Electrochemical Synthesis without Pd Catalyst
Kengo HAMASAKI
Ryoichi TOMIYAMA
Shin YONEYAMA
Pengyu XU
Kouichi MATSUMOTO
Abstrak
It was found that diphenylacetylene was synthesized by using electrochemical reduction with Mg electrodes, coiled with Cu wires. The electrochemical reaction of tetrachloroethylene and bromobenzene in LiClO4/THF afforded diphenylacetylene in up to 38 % yield. The reaction took place in the absence of Pd catalyst. The scope and limitations, and investigation of reaction mechanism were also studied.
Topik & Kata Kunci
Penulis (5)
K
Kengo HAMASAKI
R
Ryoichi TOMIYAMA
S
Shin YONEYAMA
P
Pengyu XU
K
Kouichi MATSUMOTO
Format Sitasi
HAMASAKI, K., TOMIYAMA, R., YONEYAMA, S., XU, P., MATSUMOTO, K. (2024). Mg Electrodes Coiled with Cu Wires Promoted Formation of Diphenylacetylene from Tetrachloroethylene and Bromobenzene: One-step Electrochemical Synthesis without Pd Catalyst. https://doi.org/10.5796/electrochemistry.24-00079
Akses Cepat
PDF tidak tersedia langsung
Cek di sumber asli →Informasi Jurnal
- Tahun Terbit
- 2024
- Sumber Database
- DOAJ
- DOI
- 10.5796/electrochemistry.24-00079
- Akses
- Open Access ✓