DOAJ Open Access 2023

Potentiometric Titration Based on the Reference Electrode Equipped with Ionic Liquid Salt Bridge — 1. Precipitation Titration of Chloride with Silver Ions in Water

Takashi KAKIUCHI Ryunosuke TANIGO Atsushi TANI Takeshi YAMAZAKI Kohta KOMATSUBARA +2 lainnya

Abstrak

A reference electrode equipped with ionic liquid salt bridge consisting of tributyl(2-methoxyethyl)phosphonium bis(pentafluoroethanesulfonyl)amide has been employed for potentiometric precipitation titration of chloride with silver ions in water at 25 °C. A model for the titration curve was regressed to experimental curves, taking into account the change in the activity coefficients of relevant ionic species in the course of the titration, to obtain the least square estimates of two adjustable parameters in the model, the solubility product (Ksp) and the analyte concentration. The least-square estimate of Ksp, (1.840 ± 0.060) × 10−10, i.e., pKsp = 9.736 ± 0.014, is in good agreement with literature data, but with higher precision.

Topik & Kata Kunci

Technology Physical and theoretical chemistry

Penulis (7)

Takashi KAKIUCHI

Ryunosuke TANIGO

Atsushi TANI

Takeshi YAMAZAKI

Kohta KOMATSUBARA

Keiji NAKANO

Masahiro YAMAMOTO

Format Sitasi

APA MLA BibTeX

KAKIUCHI, T., TANIGO, R., TANI, A., YAMAZAKI, T., KOMATSUBARA, K., NAKANO, K. et al. (2023). Potentiometric Titration Based on the Reference Electrode Equipped with Ionic Liquid Salt Bridge — 1. Precipitation Titration of Chloride with Silver Ions in Water. https://doi.org/10.5796/electrochemistry.22-66119

Akses Cepat

PDF tidak tersedia langsung

Cek di sumber asli →

Lihat di Sumber doi.org/10.5796/electrochemistry.22-66119

Informasi Jurnal

Tahun Terbit: 2023
Sumber Database: DOAJ
DOI: 10.5796/electrochemistry.22-66119
Akses: Open Access ✓