Zirconium-bearing accessory minerals in UK Paleogene granites: textural, compositional, and paragenetic relationships

<p>The mineral occurrences, parageneses, textures, and compositions of Zr-bearing accessory minerals in a suite of UK Paleogene granites from Scotland and Northern Ireland are described. Baddeleyite, zirconolite, and zircon, in that sequence, formed in hornblende <span class="inline-formula">+</span> biotite granites (type 1) and hedenbergite–fayalite granites (type 2). The peralkaline microgranite (type 3) of Ailsa Craig contains zircon, dalyite, a eudialyte-group mineral, a fibrous phase which is possibly lemoynite, and Zr-bearing aegirine. Hydrothermal zircon is also present in all three granite types and documents the transition from a silicate-melt environment to an incompatible element-rich aqueous-dominated fluid. No textures indicative of inherited zircon were observed. The minerals crystallized in stages from magmatic through late-magmatic to hydrothermal. The zirconolite and eudialyte-group mineral are notably Y<span class="inline-formula">+</span>REE-rich (REE signifies rare earth element). The crystallization sequence of the minerals may have been related to the activities of Si and Ca, to melt peralkalinity, and to local disequilibrium.</p>