Aerosol Composition and Extinction of the 2022 Hunga Plume Using CALIOP

<p>We use the CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) instrument to determine the microphysical properties of the stratospheric aerosol plume after the Hunga eruption in 2022, the largest so far after the Pinatubo in 1991. In the early stages, low depolarization (<span class="inline-formula">&lt;2 <i>%</i></span>) is found everywhere except in patches of high depolarization (up to 35 %) detected within the plumes of sulfur compounds up to 3 d after the eruption. As standard CALIOP L2 products are not operational in the case of the Hunga aerosol plume, we implement an iterative method of successive approximations to retrieve extinction profiles, by estimating the aerosol optical depth (AOD) and then the lidar ratio (LR). The AOD of the plume at 532 nm is between 0.5 and 1.25 on the first four days, then decreases rapidly and stabilizes at <span class="inline-formula">0.047 ± 0.011</span> for March 2022. The LR is initially between 60 and 80 sr, consistent with the early growth of sulfate aerosol particles, and then decreases to <span class="inline-formula">48 ± 6 sr</span> between late January and late March 2022. Results are compared and validated with the solar occultation instrument SAGE III (Stratospheric Aerosol and Gas Experiment) on board the International Space Station (ISS) and Mie calculations. A comparison with limb-viewing instruments highlights significant quantitative disagreements in extinction and AOD estimates, which we attribute, in part, to the unusual size distribution of the aerosols within the Hunga plume.</p>