Version 8 IMK/IAA MIPAS measurements of CFC-11, CFC-12, and HCFC-22

<p>The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) on Envisat provided infrared limb emission spectra, which were used to infer global distributions of CFC-11, CFC-12, and HCFC-22. Spectra were analysed using constrained non-linear least-squares fitting. Changes with respect to earlier data versions refer to the use of version 8 spectra, the altitude range where the background continuum is considered, details of the regularization and microwindow selection, and the occasional joint fitting of interfering species, the use of new spectroscopic data, the joint fit of a tangent-height-dependent spectral offset, and the use of 2D temperature fields. In the lower stratosphere the error budget is dominated by uncertainties in spectroscopic data, while above this measurement noise is the leading error source. The vertical resolution of CFC-11 and CFC-12 is 2–3 <span class="inline-formula">km</span> near the tropopause, about 4 <span class="inline-formula">km</span> at 30 <span class="inline-formula">km</span> altitude, and 6–10 <span class="inline-formula">km</span> at 50 <span class="inline-formula">km</span>. The vertical resolution of HCFC-22 is somewhat coarser, 3–4 <span class="inline-formula">km</span> at the tropopause and 10–12 <span class="inline-formula">km</span> at 35 <span class="inline-formula">km</span> altitude. In the altitude range of interest, the horizontal resolution is typically limited by the horizontal sampling of the measurements, not by the smearing of the retrievals. Horizontal information displacement does not exceed 150 <span class="inline-formula">km</span>, which can become an issue only for comparisons with model simulations with high horizontal resolution or localized in situ observations. Along with the regular data product, an alternative representation of the data on a coarser vertical grid is offered. These data can be used without consideration of the averaging kernels. The new data version provides improvement with respect to reduction of biases and improved consistency between the full- and reduced-resolution mission period of MIPAS.</p>