Advances in Magnesia–Dolomite Refractory Materials: Properties, Emerging Technologies, and Industrial Applications: A Review

Magnesia-dolomite refractories have emerged as sustainable alternatives to traditional carbon- or chromium-containing linings in steelmaking and cement industries. Their outstanding thermochemical stability, high refractoriness, and strong basic slag compatibility make them suitable for converters, electric arc furnaces (EAF), and argon–oxygen decarburization (AOD) units. However, their practical application has long been constrained by hydration and thermal shock sensitivity associated with free CaO and open porosity. Recent advances, including optimized raw material purity, fused co-clinker synthesis, nano-additive incorporation (TiO₂, MgAl₂O₄ spinel, FeAl₂O₄), and improved sintering strategies, have significantly enhanced density, mechanical strength, and hydration resistance. Emerging technologies such as co-sintered magnesia–dolomite composites and additive-assisted microstructural tailoring have enabled superior corrosion resistance and extended service life. This review provides a comprehensive analysis of physicochemical mechanisms, processing routes, and industrial performance of magnesia–dolomite refractories, with special emphasis on their contribution to technological innovation, decarbonization, and circular economy strategies in high-temperature industries.