CO₂ Decomposition in Microwave Discharge Created in Liquid Hydrocarbon

The task of CO₂ decomposition is one of the components of the problem associated with global warming. One of the promising directions of its solution is the use of low-temperature plasma. For these purposes, different types of discharges are used. Microwave discharge in liquid hydrocarbons has not been studied before for this problem. This paper presents the results of a study of microwave discharge products in liquid Nefras C2 80/120 (petroleum solvent, a mixture of light hydrocarbons with a boiling point from 33 to 205 °C) when CO₂ is introduced into the discharge zone, as well as the results of a study of the discharge by optical emission spectroscopy and shadow photography methods. The main gas products are H₂, C₂H₂, C₂H₄, CH₄, CO₂, and CO. No oxygen was found in the products. The mechanisms of CO₂ decomposition in the discharge are considered. The formation of H₂ occurs simultaneously with the decomposition of CO₂ in the discharge, with a volumetric rate of up to 475 mL/min and energy consumption of up to 81.4 NL/kWh.