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DOAJ Open Access 2024

Asymmetric Synthesis of Three Alkenyl Epoxides: Crafting the Sex Pheromones of the Elm Spanworm and the Painted Apple Moth

Yun Zhou Jianan Wang Beijing Tian Yanwei Zhu Yujuan Zhang +3 lainnya
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Abstrak

A concise synthesis of the sex pheromones of elm spanworm as well as painted apple moth has been achieved. The key steps were the alkylation of acetylide ion, Sharpless asymmetric epoxidation and Brown’s P2-Ni reduction. This approach provided the sex pheromone of the elm spanworm (<b>1</b>) in 31% total yield and those of the painted apple moth (<b>2</b>, <b>3</b>) in 26% and 32% total yields. The ee values of three final products were up to 99%. The synthesized pheromones hold promising potential for use in the management and control of these pests.

Topik & Kata Kunci

Organic chemistry

Penulis (8)

Y

Yun Zhou

J

Jianan Wang

B

Beijing Tian

Y

Yanwei Zhu

Y

Yujuan Zhang

J

Jinlong Han

J

Jiangchun Zhong

C

Chenggang Shan

Format Sitasi

APA MLA BibTeX
Zhou, Y., Wang, J., Tian, B., Zhu, Y., Zhang, Y., Han, J. et al. (2024). Asymmetric Synthesis of Three Alkenyl Epoxides: Crafting the Sex Pheromones of the Elm Spanworm and the Painted Apple Moth. https://doi.org/10.3390/molecules29092136

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Informasi Jurnal
Tahun Terbit
2024
Sumber Database
DOAJ
DOI
10.3390/molecules29092136
Akses
Open Access ✓