Peroxymonosulfate Activation by Facile Fabrication of α-MnO₂ for Rhodamine B Degradation: Reaction Kinetics and Mechanism

The persulfate-based advanced oxidation process has been an effective method for refractory organic pollutants’ degradation in aqueous phase. Herein, α-MnO₂ with nanowire morphology was facially fabricated via a one-step hydrothermal method and successfully activated peroxymonosulfate (PMS) for Rhodamine B (RhB) degradation. Influencing factors, including the hydrothermal parameter, PMS concentration, α-MnO₂ dosage, RhB concentration, initial pH, and anions, were systematically investigated. The corresponding reaction kinetics were further fitted by the pseudo-first-order kinetic. The RhB degradation mechanism via α-MnO₂ activating PMS was proposed according to a series of quenching experiments and the UV-vis scanning spectrum. Results showed that α-MnO₂ could effectively activate PMS to degrade RhB and has good repeatability. The catalytic RhB degradation reaction was accelerated by increasing the catalyst dosage and the PMS concentration. The effective RhB degradation performance can be attributed to the high content of surface hydroxyl groups and the greater reducibility of α-MnO₂, and the contribution of different ROS (reactive oxygen species) was ¹O₂ > <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi mathvariant="normal">O</mi></mrow><mrow><mn>2</mn></mrow><mrow><mo>·</mo><mo>−</mo></mrow></msubsup></mrow></semantics></math></inline-formula> > <inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msubsup><mrow><mi>SO</mi></mrow><mrow><mn>4</mn></mrow><mrow><mo>·</mo><mo>−</mo></mrow></msubsup></mrow></semantics></math></inline-formula> > ·OH.