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DOAJ Open Access 2022

Construction of Benzenesulfonamide Derivatives via Copper and Visible Light-induced Azides and S(O)<sub>2</sub>–H Coupling

Zhipeng Liang Ya-Nan Wu Yang Wang
Lihat Sumber DOI

Abstrak

We here have developed an S(O)<sub>2</sub>–N coupling between phenylsulfinic acid derivatives and aryl azides by dual copper and visible light catalysis. In this efficient and mild pathway, the reaction produces sulfonamide compounds under redox-neutral condition, which is mechanistically different from the nitrogen nucleophilic substitution reactions. Significantly, this transformation intends to utilize the property of visible light-induced azides to generate triplet nitrene and followed coupling with sulfonyl radicals in situ to achieve structurally diverse benzenesulfinamides in good yields.

Topik & Kata Kunci

Organic chemistry

Penulis (3)

Z

Zhipeng Liang

Y

Ya-Nan Wu

Y

Yang Wang

Format Sitasi

APA MLA BibTeX
Liang, Z., Wu, Y., Wang, Y. (2022). Construction of Benzenesulfonamide Derivatives via Copper and Visible Light-induced Azides and S(O)<sub>2</sub>–H Coupling. https://doi.org/10.3390/molecules27175539

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Informasi Jurnal
Tahun Terbit
2022
Sumber Database
DOAJ
DOI
10.3390/molecules27175539
Akses
Open Access ✓