DOAJ Open Access 2014

A Novel Extended N-Methyl Monopyrrolotetrathiafulvalene Based on 2-Methylene-4,5-Bis(Methylthio)-1,3-Dithiole

Ruibin Hou Xiaohong Shang Yan Xia Bao Li Dongfeng Li

Lihat Sumber DOI

Abstrak

The title compound was prepared via a cross-coupling reaction and its crystal structure has been determined. It crystallized in the triclinic space group P-1 with cell parameters: a = 8.552(2) Å, b = 11.310(2) Å, c = 16.150(3) Å, α = 109.55(3)°, β = 91.45(3)°, γ = 91.28(3)°, V = 1470.6(5) Å3, Z = 2 at 296 K. There is one molecule in the asymmetric unit. In the crystal structure, the neighboring molecules from dimers by weak intermolecular π···π interactions between the pyrrole and tetrathiafulvalene units. The dimers are further linked through C-H···π interactions to generate one-dimensional chains along the [100] direction. The arrangement of the molecules corresponds to an overlap between the HOMO and LUMO.

Topik & Kata Kunci

Organic chemistry

Penulis (5)

Ruibin Hou

Xiaohong Shang

Yan Xia

Bao Li

Dongfeng Li

Format Sitasi

APA MLA BibTeX

Hou, R., Shang, X., Xia, Y., Li, B., Li, D. (2014). A Novel Extended N-Methyl Monopyrrolotetrathiafulvalene Based on 2-Methylene-4,5-Bis(Methylthio)-1,3-Dithiole. https://doi.org/10.3390/molecules191220314

Akses Cepat

Lihat di Sumber doi.org/10.3390/molecules191220314

Informasi Jurnal

Tahun Terbit: 2014
Sumber Database: DOAJ
DOI: 10.3390/molecules191220314
Akses: Open Access ✓