Effect of Si Doping on Microstructure and Mechanical and Electrochemical Properties of (AlCrFeNi)_100-xSi_x (x = 2, 4, 6) Dual-Phase Eutectic High-Entropy Alloys

The effects of silicon (Si) doping on the microstructure, mechanical properties, and electrochemical corrosion behavior of dual-phase eutectic high-entropy alloys (AlCrFeNi)_100-xSi_x (x = 2, 4, 6 at.%) were systematically investigated. The results reveal that with increasing Si content, all three alloys maintain a sunflower-like eutectic microstructure composed of A2 and B2 phases, characterized by an expanding central region and a densification and refinement of the lamellar two-phase structure in the petal regions; the volume of phase B2 gradually increases, accompanied by the precipitation of nanoscale B2 particles. The test results of mechanical properties show that Si doping enhances the compressive strength and Vickers hardness but significantly reduces ductility, exhibiting a typical inverse strength–ductility relationship. Electrochemical corrosion tests demonstrate that higher Si content deteriorates corrosion resistance, with corrosion predominantly occurring in the B2 phase. Among the studied alloys, the Si₂ variant exhibits the most balanced overall performance. This work provides valuable insights into the role of Si in tuning the microstructure and properties of eutectic high-entropy alloys and methodology for their compositional design and engineering applications.