Thermo-Responsive Wax Millicapsules as Lubricating Agents Carriers

Encapsulation of lubricating agents has many advantages, as it helps to protect them from external factors, oxidation and degradation, can support their controlled and prolonged release, and also preserves the environment from accidental contamination with these substances. In our experiments various types of thermo-responsive, paraffin wax capsules capable of safely transporting liquid and semi-solid lubricants were designed, fabricated and tested. Lubricating oils were primarily encapsulated inside hemispherical wax shells closed with special caps, but also in wax spherocylinders and two-compartment structures. Greases were protected with wax coatings with the thickness ranging from 0.187 to 0.774 mm. The payload release from our core–shell capsules occurred not only due to the exerted mechanical force but also in a controlled manner upon prolonged contact with a heated surface. The wax shells of the capsules lying on the plate, whose temperature was increased at a rate of 0.025°C/s, began to melt gradually, starting from ≈55.5 °C. This temperature-triggered lubricant liberation can be useful when, for example, a machine element becomes excessively hot due to friction. The wax itself also has lubricating properties, so the crushed or melted coating cannot be treated as waste, but only as an additional factor supporting lubrication. The practical applications of our wax capsules were demonstrated with five examples.