Impact of TiC/TiB2 Inoculation on the Electrochemical Performance of an Arc-Directed Energy-Deposited PH 13-8Mo Martensitic Stainless Steel

This study investigates the impact of incorporating TiC and TiB₂ inoculants on the microstructure and corrosion performance of an arc-directed energy-deposited PH 13-8Mo martensitic stainless steel. The microstructural characterizations revealed partial dissolution of the incorporated ceramic-based nanoparticles, resulting in the formation of in situ TiC phase in the TiC-inoculated sample, while TiC and chromium-enriched M₃B₂ phases were formed in the TiB₂-inoculated sample. Further investigations into the electrochemical response of the fabricated samples confirmed that the applied inoculation strategy slightly enhanced the corrosion resistance of the alloy, offering a valuable advantage for in-service performance for applications in harsher environments. The slight improvement in the corrosion resistance of the inoculated samples was found to be attributed to the formation of a higher fraction of low-angle grain boundaries and enhanced retained austenite content in the microstructure. However, it is essential to note that the formation of chromium-enriched M₃B₂ phases in the TiB₂-inoculated sample led to a slight deterioration in its corrosion resistance compared to the TiC-inoculated counterpart.