DOAJ Open Access 2024

On the Elimination of Fast Variables from the Langevin Equation

Dick Bedeaux

Abstrak

In a multivariable system, there are usually a number of relaxation times. When some of the relaxation times are shorter than others, the corresponding variables will decay to their equilibrium value faster than the others. After the fast variables have decayed, the system can be described with a smaller number of variables. From the theory of nonequilibrium thermodynamics, as formulated by Onsager, we know that the coefficients in the linear flux–force relations satisfy the so-called Onsager symmetry relations. The question we will address in this paper is how to eliminate the fast variables in such a way that the coefficients in the reduced description for the slow variables still satisfy the Onsager relations. As the proof that Onsager gave of the symmetry relations does not depend on the choice of the variables, it is equally valid for the subset of slow variables. Elimination procedures that lead to symmetry breaking are possible, but do not consider systems that satisfy the laws of nonequilibrium thermodynamics.

Penulis (1)

D

Dick Bedeaux

Format Sitasi

Bedeaux, D. (2024). On the Elimination of Fast Variables from the Langevin Equation. https://doi.org/10.3390/e26100821

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Informasi Jurnal
Tahun Terbit
2024
Sumber Database
DOAJ
DOI
10.3390/e26100821
Akses
Open Access ✓