Impact of Environmental Weathering on the Chemical Composition of Spilled Oils in a Real Case in Brazil

Brazil suffered the largest oil spill disaster in its history, beginning on August 2019, affecting the Northeast coast. This study proposes a chemical investigation of oils from the 2019 spill in Brazil, which had naturally undergone different weathering processes in terrestrial and aquatic environments after an extended period of exposure. Three samples were collected at different times and under distinct environmental conditions, coded as spilled oil (SO), oil recovered from the aquatic environment (SA), and oil collected from the terrestrial environment (ST), the latter two having spent more time naturally exposed to aquatic and terrestrial environments. The analyses were performed by gas chromatography–mass spectrometry (GC-MS) and electrospray ionization coupled with Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). The results of the GC-MS analysis indicated that, although the samples share a common geochemical origin, the SA and ST samples showed a decrease in the intensity of <i>n</i>-alkane distribution compared to the SO sample, mainly attributed to evaporation and biodegradation processes. FT-ICR MS analysis identified dozens of classes of ESI(+) and ESI(–) compounds, most of them rich in sulfur and oxygen, with the highest intensities and quantities of molecular formulas in the SA and ST samples. Diagnostic ratios for heteroatom classes concluded that the SA and ST samples had undergone a higher level of weathering, mainly associated with photooxidation and biodegradation processes. Thus, the combined use of GC-MS and FT-ICR MS proved to be a robust approach for the detailed characterization of spilled oils, contributing to a clearer understanding of the extent and type of weathering in samples from the 2019 Brazilian spill.