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DOAJ Open Access 2025

Synthesis and Structural Characterization of Manganese(I) Complexes Ligated by 2-Azabutadienes (ArS)<sub>2</sub>C=C(H)-N=CPh<sub>2</sub>

Rodolphe Kinghat Abderrahim Khatyr Michael Knorr Yoann Rousselin Marek M. Kubicki
Lihat Sumber DOI

Abstrak

The thioether-functionalized 2-azabutadienes (ArS)<sub>2</sub>C=C(H)-N=CPh<sub>2</sub> (<b>L1</b> Ar = Ph, <b>L2</b> Ar = <i>p</i>-Tol) ligate to [Mn(CO)<sub>5</sub>Br] to form the octahedral five-membered <i>S</i>, <i>N</i>-chelate complexes <i>fac</i>-[MnBr(CO)<sub>3</sub>{(ArS)<sub>2</sub>C=C(H)-N=CPh<sub>2</sub>] (<b>1</b> Ar = Ph; <b>2</b> Ar = <i>p</i>-Tol), whose crystal structures have been solved by X-ray diffraction. Complex <b>1</b> crystallizes in the non-centrosymmetric orthorhombic space group <i>P</i>2<sub>1</sub>2<sub>1</sub>2<sub>1</sub>, whereas <b>2</b> crystallizes in the triclinic space group <i>P</i><inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><mover accent="false"><mrow><mn>1</mn></mrow><mo>¯</mo></mover></mrow></semantics></math></inline-formula>. The secondary interactions occurring in the packing have also been assessed by an Atoms in Molecules (AIM) topological analysis.

Topik & Kata Kunci

Inorganic chemistry

Penulis (5)

R

Rodolphe Kinghat

A

Abderrahim Khatyr

M

Michael Knorr

Y

Yoann Rousselin

M

Marek M. Kubicki

Format Sitasi

APA MLA BibTeX
Kinghat, R., Khatyr, A., Knorr, M., Rousselin, Y., Kubicki, M.M. (2025). Synthesis and Structural Characterization of Manganese(I) Complexes Ligated by 2-Azabutadienes (ArS)<sub>2</sub>C=C(H)-N=CPh<sub>2</sub>. https://doi.org/10.3390/M2042

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Informasi Jurnal
Tahun Terbit
2025
Sumber Database
DOAJ
DOI
10.3390/M2042
Akses
Open Access ✓