Synthesis of (<i>Z</i>)-3-Allyl-5-(4-nitrobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one and Determination of Its Crystal Structure
Abstrak
To extend the existing library of arylidenerhodanines which display a potential biological activity, 3-<i>N</i>-allylrhodanine <b>1</b> was condensed under Knoevenagel conditions with <i>p</i>-nitrobenzaldehyde in acetic acid to afford the π-conjugated heterocyclic compound 3-allyl-5-(4-nitrobenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one <b>2</b>. Compound <b>2</b> was characterized by IR and NMR spectroscopy, and its UV-vis spectrum was compared with that of compound 3-allyl-5-(4-methoxybenzylidene)-2-sulfanylidene-1,3-thiazolidin-4-one <b>3.</b> The molecular structure is ascertained by a single-crystal X-ray diffraction study performed at 100 K.
Topik & Kata Kunci
Penulis (6)
Bastien Moreno
Isabelle Jourdain
Michael Knorr
Sarra Boudriga
Carsten Strohmann
Tobias Schrimpf
Akses Cepat
- Tahun Terbit
- 2024
- Sumber Database
- DOAJ
- DOI
- 10.3390/M1783
- Akses
- Open Access ✓