DOAJ Open Access 2025

Reactive self-consumption strategy to suppress SiO2 phase transition-induced cracking

Lin Chen Shu-Wen Li Chang-Jiu Li Qiang Zhang Guan-Jun Yang

Abstrak

The lifetime of Si bond coats in environmental barrier coatings (EBCs) is constrained by phase transition-induced cracking at the SiO₂ scale. In this study, reactive self-consumption and lattice solid solution strategies are employed to address this limitation via Si–Yb₄Al₂O₉ composite coatings. The formation of an Yb₂Si₂O₇ layer, through the consumption of the thermally grown SiO₂ scale and Yb₄Al₂O₉, reduces the SiO₂ thickness and significantly lowers the cracking driving force. Furthermore, the incorporation of Al into the SiO₂ lattice stabilizes high-temperature β-SiO₂, preventing phase transition-induced cracking. The proposed coating demonstrated an oxidation lifetime 20 times longer than that of pure Si at 1370 °C, highlighting its potential as an EBC bond coating.

Penulis (5)

L

Lin Chen

S

Shu-Wen Li

C

Chang-Jiu Li

Q

Qiang Zhang

G

Guan-Jun Yang

Format Sitasi

Chen, L., Li, S., Li, C., Zhang, Q., Yang, G. (2025). Reactive self-consumption strategy to suppress SiO2 phase transition-induced cracking. https://doi.org/10.26599/JAC.2025.9221042

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Informasi Jurnal
Tahun Terbit
2025
Sumber Database
DOAJ
DOI
10.26599/JAC.2025.9221042
Akses
Open Access ✓