DOAJ Open Access 2021

Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes

Manel Khiat Fatima-Zohra Zradni Souad Kasmi-Mir Alejandro Baeza

Abstrak

An electrochemical study using the cyclic voltammetry method was carried out on some previously prepared merocyanines salts, namely thiazolideniumsulfonate salts 5a-b, and thiazolidenium chloride salts 6a-b, and merocarbocyanines salts, namely alkylidenthiazolidenium sulfonate salt 5c, and alkylidenthiazolidenium chloride salt 6c. These salts are transformed by dimerization in situ in a voltammetric cell into tetrathiatetraazafulvalenes (TTTAFs) 7a-b, 7’a-b, 8c, and 8'c supposed to be π-electron donor molecules due to the existing conjugation in their structure. The structure of all new chemically synthesized molecules was confirmed by IR, 1H-NMR, 13C-NMR, and MS. The transformation of salts into TTTAF was confirmed by a reversible voltammogram curve and the variation of observed potentials.

Topik & Kata Kunci

Chemistry

Penulis (4)

Manel Khiat

Fatima-Zohra Zradni

Souad Kasmi-Mir

Alejandro Baeza

Format Sitasi

APA MLA BibTeX

Khiat, M., Zradni, F., Kasmi-Mir, S., Baeza, A. (2021). Study of the Electrochemical Behavior of Merocyanine and Merocarbocyanine Salts and Their Transformation into Π-Electron Donor Molecules, Namely Tetrathiatetraazafulvalenes. https://doi.org/10.22146/ijc.58132

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Informasi Jurnal

Tahun Terbit: 2021
Sumber Database: DOAJ
DOI: 10.22146/ijc.58132
Akses: Open Access ✓