Pitting and Crevice Corrosion Behavior of the Duplex Stainless Steel UNS S32205 Welded by Using the GTAW Process

Abstract This study investigated the pitting and crevice corrosion behavior of the gas tungsten arc welding (GTAW) process in the UNS S32205 according to industrial parameters. Results revealed that the welding process presented a weld metal chemical composition similar to the base metal and an adequate balance of the austenite and ferrite phases. No relevant variation in the hardness was observed and XRD spectra did not identify the presence of deleterious phases in the weld bead. Cyclic polarization tests revealed similarities between welded and base metal samples (20±2°C, NaCl 3.5% wt.). When comparing the behavior obtained in the crevice, and pitting tests, a decrease in the corrosion resistance was observed in the presence of a crevice former. The SEM-EDS proved that the attack occurred mainly in secondary austenites. Profilometry measurements revealed that the crevice corrosion in the weld region was deeper than in the base metal. However, considering the welded samples as a unit, making no difference between regions: weld metal, HAZ, and base metal, the average crevice corrosion depth was comparable to that of the base metal samples. Finally, it was concluded that the welding process used for the UNS S32205 steel did not harm its corrosion resistance.