A Quantitative Study of Photocatalytic Reduction of Cr(Ⅵ) by Operando Low-Field NMR Relaxometry
Abstrak
In this work, operando low-field nuclear magnetic resonance (LF-NMR) technology was used to quantitatively study the photocatalytic reduction of Cr(Ⅵ) in a real solid-liquid reaction environment. The performance of Ag/g-C3N4 photocatalysts with different loadings of Ag for the photocatalytic reduction of aqueous Cr(Ⅵ) to Cr(Ⅲ) under visible-light irradiation was systematically investigated. The results showed that the addition of Ag cocatalysts (Ag loading amount: 1 wt.%, 2 wt.%, 5 wt.%, and 10 wt.%) significantly enhanced the photocatalytic performance of g-C3N4 photocatalysts, while the optimal content of Ag loading was 5 wt.%, which was greater than that of pristine g-C3N4 by a factor of 4.0. Furthermore, we carried out a quantitative analysis on the concentration of paramagnetic Cr(Ⅲ) ions in solution by using the transverse relaxation time (T2) values, and proved the viability of employing operando LF-NMR relaxometry for monitoring the photocatalytic Cr(Ⅵ) reduction performance.
Topik & Kata Kunci
Penulis (6)
Xing-xing NIU
Zhi-jie BAI
Yi YANG
Yang-wen GAO
Xue-lu WANG
Ye-feng YAO
Akses Cepat
- Tahun Terbit
- 2021
- Sumber Database
- DOAJ
- DOI
- 10.11938/cjmr20202815
- Akses
- Open Access ✓