Properties of aniline or O-phenylenediamine/YBCO hybrid materials

YBa₂Cu₃O_7-δ(YBCO) bulk material prepared by high temperature solid state reaction was milled and dispersed through ultrasonic process in ethanol to prepare nanoscale YBCO/ethanol sol. Then it was mixed with aniline or O-phenylenediamine and the organic/YBCO hybrid materials were obtained after concentration and being dried in vacuum. The influence of the organic on YBCO’s chemical composition, phase, elemental valence and magnetic properties was studied by Fourier transform infrared spectroscopy(FT-IR), X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS) and vibrating sample magnetometer(VSM). The results show that the infrared absorption of YBCO is not affected by the aniline or O-phenylenediamine within 0.05%-5%(mass fraction, the same below), however the intensity of the XRD peaks is significantly increased. The interaction between the N atom in aniline or O-phenylenediamine and the Y atom in YBCO is stronger compared with N-Ba or N-Cu. The superconducting transition temperature <i>T</i>_c and magnetization <i>M</i> of YBCO are significantly affected by the content of N element in the hybrid materials. When the content of N element exceeds 1%, <i>T</i>_c is significantly decreased and <i>M</i>_min is increased accordingly.