Multi-technique analysis of pigments on sandstone sculptures: Renaissance re-painting of a Roman relief

Abstract The Antonine Wall was commissioned by the Roman Emperor Antoninus Pius around 142 CE and stretches for c. 60 km across the central belt of Scotland, marking the Empire’s most north-western frontier. This vanguard research reports on the materials referred to by Antiquarian sources as having been applied during the sixteenth century for the redecoration of an iconic Distance Sculpture that was once embedded into the mural barrier. Portable non-invasive technologies, including pXRF and in-situ microphotography were deployed. These techniques were further supplemented by micro-sampling for SEM/EDS, FTIR–ATR and microscopy of embedded cross-sections. The validity of applying these complementary techniques has been confirmed. They provide a comprehensive account of the polychromy present, including pigments that could have been applied during the Roman period and others that were only available from the fifteenth or sixteenth Centuries. The work has confirmed stratigraphic sequencing of the pigments which will, in due course, permit the digital reconstruction of how this Classical relief sculpture would have been adorned during the Renaissance.