DOAJ Open Access 2019

Temperature dependences of electric properties of tetramethylammonium mono- and pentaiodide

Irina D. Yushina Fedor V. Podgornov Maxim Gavrilyak Victor Boronin Ekaterina V. Bartashevich

Abstrak

The dielectric properties of tetramethylammonium monoiodide and pentaiodide were investigated in broad temperature range (−150∘C till +50∘C). It was demonstrated that the structural organization of the polyiodide chain containing I…I charge-assisted halogen bonds influenced the parameters and the mechanism of electric conductivity of considered compound. The impedance spectroscopic measurements revealed that the direct current electric conductivity of pentaiodide salt is around four orders of magnitude higher than that of corresponding monoiodide. Moreover, pentaiodide demonstrates the hopping mechanism of conductivity.

Topik & Kata Kunci

Penulis (5)

I

Irina D. Yushina

F

Fedor V. Podgornov

M

Maxim Gavrilyak

V

Victor Boronin

E

Ekaterina V. Bartashevich

Format Sitasi

Yushina, I.D., Podgornov, F.V., Gavrilyak, M., Boronin, V., Bartashevich, E.V. (2019). Temperature dependences of electric properties of tetramethylammonium mono- and pentaiodide. https://doi.org/10.1142/S2010135X19500528

Akses Cepat

Lihat di Sumber doi.org/10.1142/S2010135X19500528
Informasi Jurnal
Tahun Terbit
2019
Sumber Database
DOAJ
DOI
10.1142/S2010135X19500528
Akses
Open Access ✓